98 research outputs found
Cavity nonlinear optics with few photons and ultracold quantum particles
The light force on particles trapped in the field of a high-Q cavity mode
depends on the quantum state of field and particle. Different photon numbers
generate different optical potentials anddifferent motional states induce
different field evolution. Even for weak saturation and linear polarizability
the induced particle motion leads to nonlinear field dynamics. We derive a
corresponding effective field Hamiltonian containing all the powers of the
photon number operator, which predicts nonlinear phase shifts and squeezing
even at the few-photon level. Wave-function simulations of the full
particle-field dynamics confirm this and show significant particle-field
entanglement in addition.Comment: 5 pages, 5 figure
The second law and beyond in microscopic quantum setups
The Clausius inequality (CI) is one of the most versatile forms of the second
law. Although it was originally conceived for macroscopic steam engines, it is
also applicable to quantum single particle machines. Moreover, the CI is the
main connecting thread between classical microscopic thermodynamics and
nanoscopic quantum thermodynamics. In this chapter, we study three different
approaches for obtaining the CI. Each approach shows different aspects of the
CI. The goals of this chapter are: (i) To show the exact assumptions made in
various derivations of the CI. (ii) To elucidate the structure of the second
law and its origin. (iii) To discuss the possibilities each approach offers for
finding additional second-law like inequalities. (iv) To pose challenges
related to the second law in nanoscopic setups. In particular, we introduce and
briefly discuss the notions of exotic heat machines (X machines), and "lazy
demons".Comment: As a chapter of: F. Binder, L. A. Correa, C. Gogolin, J. Anders, and
G. Adesso (eds.), "Thermodynamics in the quantum regime - Recent Progress and
Outlook", (Springer International Publishing). v1 does not include references
to other book chapter
Thermodynamic principles and implementations of quantum machines
The efficiency of cyclic heat engines is limited by the Carnot bound. This
bound follows from the second law of thermodynamics and is attained by engines
that operate between two thermal baths under the reversibility condition
whereby the total entropy does not increase. By contrast, the efficiency of
engines powered by quantum non-thermal baths has been claimed to surpass the
thermodynamic Carnot bound. The key to understanding the performance of such
engines is a proper division of the energy supplied by the bath to the system
into heat and work, depending on the associated change in the system entropy
and ergotropy. Due to their hybrid character, the efficiency bound for quantum
engines powered by a non-thermal bath does not solely follow from the laws of
thermodynamics. Hence, the thermodynamic Carnot bound is inapplicable to such
hybrid engines. Yet, they do not violate the principles of thermodynamics.
An alternative means of boosting machine performance is the concept of
heat-to-work conversion catalysis by quantum non-linear (squeezed) pumping of
the piston mode. This enhancement is due to the increased ability of the
squeezed piston to store ergotropy. Since the catalyzed machine is fueled by
thermal baths, it adheres to the Carnot bound.
We conclude by arguing that it is not quantumness per se that improves the
machine performance, but rather the properties of the baths, the working fluid
and the piston that boost the ergotropy and minimize the wasted heat in both
the input and the output.Comment: As a chapter of: F. Binder, L. A. Correa, C. Gogolin, J. Anders, and
G. Adesso (eds.), "Thermodynamics in the quantum regime - Recent Progress and
Outlook", (Springer International Publishing
Elatinaceae are Sister to Malpighiaceae; Peridiscaceae Belong to Saxifragales
Phylogenetic data from plastid (ndhF and rbcL) and nuclear (PHYC) genes indicate that, within the order Malpighiales, Elatinaceae are strongly supported as sister to Malpighiaceae. There are several putative morphological synapomorphies for this clade; most notably, they both have a base chromosome number of X = 6 (or some multiple of three or six), opposite or whorled leaves with stipules, unicellular hairs (also uniseriate in some Elatinaceae), multicellular glands on the leaves, and resin (Elatinacae) or latex (Malpighiaceae). Further study is needed to determine if these features are synapomorphic within the order. Malpighiaceae have previously been inferred as sister to Peridiscaceae based on rbcL sequence data, but the rbcL sequence of Whittonia is a chimera of two sequences, neither of which appears to be Whittonia. Our data from plastid (atpB, rbcL) and nuclear (18S rDNA) genes instead place Peridiscaeace as a member of the Saxifragales.Organismic and Evolutionary Biolog
Energetic instability of passive states in thermodynamics
Passivity is a fundamental concept in thermodynamics that demands a quantum system’s energy cannot be lowered by any reversible, unitary process acting on the system. In the limit of many such systems, passivity leads in turn to the concept of complete passivity, thermal states and the emergence of a thermodynamic temperature. Here we only consider a single system and show that every passive state except the thermal state is unstable under a weaker form of reversibility. Indeed, we show that given a single copy of any athermal quantum state, an optimal amount of energy can be extracted from it when we utilise a machine that operates in a reversible cycle. This means that for individual systems, the only form of passivity that is stable under general reversible processes is complete passivity, and thus provides a physically motivated identification of thermal states when we are not operating in the thermodynamic limit
Nucleic Acids Res.
In the known monoclinic crystals the 3-dimensional structure of the hexameric, replicative helicase RepA encoded by plasmid RSF1010 shows 6-fold rotational symmetry. In contrast, in the cubic crystal form at 2.55 Å resolution described here RepA has 3-fold symmetry and consists of a trimer of dimers. To study structure–function relationships, a series of repA deletion mutants and mutations yielding single amino acid exchanges were constructed and the respective gene products were analyzed in vivo and in vitro. Hexamerization of RepA occurs via the N-terminus and is required for NTP hydrolysis. The C-terminus is essential both for the interaction with the replication machinery and for the helicase activity. Functional analyses of RepA variants with single amino acid exchanges confirmed most of the predictions that were based on the published 3-dimensional structure. Of the five motifs conserved in family 4 helicases, all residues conserved in RepA and T7 gp4 helicases participate in DNA unwinding. Residues K42, E76, D77, D139 and H178, proposed to play key roles in catalyzing the hydrolysis of NTPs, are essential for RepA activity. Residue H178 of motif H3 couples nucleotide consumption to DNA strand separation
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