High pressure cosmochemistry applied to major planetary interiors: Experimental studies

The measurement of equilibria in binary fluid-solid systems in diamond anvil cells, represents a major advance of the art of high-pressure experimentation. Vibrational spectroscopy, direct visual observations, and X-ray diffraction crystallography of materials confined in externally heated cells are the primary experimental probes being used. Adiabats in these systems are being measured in order to constrain models of heat flow in these bodies and to detect phase transitions by thermal anomalies. Other studies are directed toward interpreting high pressure reactions in these systems that are suggested by shockwave measurements, and developing methods for reaching high temperatures and high pressures of planetary interest in diamond cells. The overall objective of this project is to determine the properties of the H2-He-H2O-HN3-CH4 system and related small-molecule systems that are needed to constrain theoretical models of the interiors of the major planets

High pressure cosmochemistry applied to major planetary interiors: Experimental studies

Progress is reported on a project to determine the properties and boundaries of high pressure phases of the H2-He-H2O-NH3-CH4 system that are needed to constrain theoretical models of the interiors of the major planets. This project is one of the first attempts to measure phase equilibria in binary fluid-solid systems in diamond anvil cells. Vibrational spectroscopy, direct visual observations, and X-ray diffraction crystallography of materials confined in externally heated cells are the primary experimental probes. Adiabats of these materials are also measured in order to constrain models of heat flow in these bodies and to detect phase transitions by thermal anomalies. Initial efforts involve the NH3-H2O binary. This system is especially relevant to models for surface reconstruction of the icy satellites of Jupiter and Saturn. Thermal analysis experiments were completed for the P-X space, p4GPa:0 or = 0.50, near room temperature. The cryostat, sample handling equipment, and optics needed to extend the optical P-T-X work below room temperature was completed

High pressure cosmochemistry applied to major planetary interiors: Experimental studies

The overall goal of this project is to determine properties of the H-He-C-N-O system, as represented by small molecules composed of these elements, that are needed to constrain theoretical models of the interiors of the major planets. Much of our work now concerns the H2O-NH3 system. This project is the first major effort to measure phase equilibria in binary fluid-solid systems in diamond anvil cells. Vibrational spectroscopy, direct visual observations, and X-ray crystallography of materials confined in externally heated cells are our primary experimental probes. We also are collaborating with the shockwave physics group at Lawrence Livermore Laboratory in studies of the equation of state of a synthetic Uranus fluid and molecular composition of this and other H-C-N-O materials under planetary conditions

Polynomial loss of memory for maps of the interval with a neutral fixed point

We give an example of a sequential dynamical system consisting of intermittent-type maps which exhibits loss of memory with a polynomial rate of decay. A uniform bound holds for the upper rate of memory loss. The maps may be chosen in any sequence, and the bound holds for all compositions.Comment: 16 page

The anodic behaviour of chalcopyrite in chloride solutions: Potentiostatic measurements

This paper summarises the results of the first part of an electrochemical study of the anodic characteristics of chalcopyrite in the potential region relevant to ambient temperature heap leaching in chloride solutions during which both iron(II) and copper(II) act as oxidants for the mineral. Mixed potential (Em) measurements in concentrated chloride solutions in the presence of iron(II) or copper(II) have enabled the potential region of 0.65 V to 0.8 V to be defined as important in the leaching process. The systematic variations in Em with pH and oxidant concentrations suggest that increases in both should result in increased rates of dissolution. This conclusion is also supported by simultaneous decreasing solution potentials due to reduction of the oxidants on the dissolving mineral surface. Slower rates of dissolution can be expected for iron(II) than copper(II) as the oxidant. Potentiostatic measurements at various potentials in the above range at different pH values have confirmed that chalcopyrite undergoes a slow “passivation” that is not complete even after 24 h. The current densities after prolonged oxidation vary exponentially with potential and increase with increasing pH but are not affected by the concentration of chloride in the range 1–5 M. Measurements with chalcopyrite samples from 3 different locations showed only minor variations in anodic reactivity. Analysis of both the current-time transients and the re-activation of the mineral surface under zero current conditions after potentiostatic oxidation have been interpreted in terms of a growing copper-rich sulphide layer under anodic polarization. Solid-state diffusion through this layer is suggested as being responsible for the “passivation” process by analogy with the well known de-alloying and back-alloying processes in some binary alloys

Intra-assessor consistency in question answering

In this paper we investigate the consistency of answer assessment in a complex question answering task examining features of assessor consistency, types of answers and question type

Graph Kernels

We present a unified framework to study graph kernels, special cases of which include the random walk (Gärtner et al., 2003; Borgwardt et al., 2005) and marginalized (Kashima et al., 2003, 2004; Mahé et al., 2004) graph kernels. Through reduction to a Sylvester equation we improve the time complexity of kernel computation between unlabeled graphs with n vertices from O(n^6) to O(n^3). We find a spectral decomposition approach even more efficient when computing entire kernel matrices. For labeled graphs we develop conjugate gradient and fixed-point methods that take O(dn^3) time per iteration, where d is the size of the label set. By extending the necessary linear algebra to Reproducing Kernel Hilbert Spaces (RKHS) we obtain the same result for d-dimensional edge kernels, and O(n^4) in the infinite-dimensional case; on sparse graphs these algorithms only take O(n^2) time per iteration in all cases. Experiments on graphs from bioinformatics and other application domains show that these techniques can speed up computation of the kernel by an order of magnitude or more. We also show that certain rational kernels (Cortes et al., 2002, 2003, 2004) when specialized to graphs reduce to our random walk graph kernel. Finally, we relate our framework to R-convolution kernels (Haussler, 1999) and provide a kernel that is close to the optimal assignment kernel of Fröhlich et al. (2006) yet provably positive semi-definite

Lithium hydroxide dihydrate: A new type of icy material at elevated pressure

We show that, in addition to the known monohydrate, LiOH forms a dihydrate at elevated pressure. The dihydrate involves a large number of H-bonds establishing chains along the direction. In addition, the energy surface exhibits a saddle point for proton locations along certain O interatomic distances, a feature characteristic for superprotonic conductors. However, MD simulations indicate that LiOH·2H_2O is not a superprotonic conductor and suggest the relevant interpolyhedral O–O distances being too large to allow for proton transfer between neighboring Li-coordinated polyhedra at least on the time scale of the MD-simulations