Substituted phenylarsonic acids; structures and spectroscopy

Full NMR and ESI-MS spectra, and differential scanning calorimeter data are presented for 15 substituted phenylarsonic acids, including two new fluoro-substituted examples. X-ray crystal structure determinations of five examples (phenylarsonic acid and the 4-fluoro-, 4-fluoro-3-nitro-, 3-amino-4-hydroxy- and 3-amino-4-methoxy-substituted derivatives) were determined and the H-bonding crystal-packing patterns analysed

Livestock, Land Use Change, and Environmental Outcomes in the Developing World

No Abstrac

Darwin\u27s Bee-Trap: The Kinetics of Catasetum, a New World Orchid

The orchid genera Catasetum employs a hair-trigger activated, pollen release mechanism, which forcibly attaches pollen sacs onto foraging insects in the New World tropics. This remarkable adaptation was studied extensively by Charles Darwin and he termed this rapid response sensitiveness. Using high speed video cameras with a frame speed of 1000 fps, this rapid release was filmed and from the subsequent footage, velocity, speed, acceleration, force and kinetic energy were computed

Revealing the role of electrons and phonons in the ultrafast recovery of charge density wave correlations in 1TT-TiSe2_2

Using time- and angle-resolved photoemission spectroscopy with selective near- and mid-infrared photon excitations, we investigate the femtosecond dynamics of the charge density wave (CDW) phase in 1$T$-TiSe$_2$, as well as the dynamics of CDW fluctuations at 240 K. In the CDW phase, we observe the coherent oscillation of the CDW amplitude mode. At 240 K, we single out an ultrafast component in the recovery of the CDW correlations, which we explain as the manifestation of electron-hole correlations. Our momentum-resolved study of femtosecond electron dynamics supports a mechanism for the CDW phase resulting from the cooperation between the interband Coulomb interaction, the mechanism of excitonic insulator phase formation, and electron-phonon coupling.Comment: 9 pages, 6 figure

Chaotic saddles in nonlinear modulational interactions in a plasma

A nonlinear model of modulational processes in the subsonic regime involving a linearly unstable wave and two linearly damped waves with different damping rates in a plasma is studied numerically. We compute the maximum Lyapunov exponent as a function of the damping rates in a two-parameter space, and identify shrimp-shaped self-similar structures in the parameter space. By varying the damping rate of the low-frequency wave, we construct bifurcation diagrams and focus on a saddle-node bifurcation and an interior crisis associated with a periodic window. We detect chaotic saddles and their stable and unstable manifolds, and demonstrate how the connection between two chaotic saddles via coupling unstable periodic orbits can result in a crisis-induced intermittency. The relevance of this work for the understanding of modulational processes observed in plasmas and fluids is discussed.Comment: Physics of Plasmas, in pres

Amplitude dependent frequency, desynchronization, and stabilization in noisy metapopulation dynamics

The enigmatic stability of population oscillations within ecological systems is analyzed. The underlying mechanism is presented in the framework of two interacting species free to migrate between two spatial patches. It is shown that that the combined effects of migration and noise cannot account for the stabilization. The missing ingredient is the dependence of the oscillations' frequency upon their amplitude; with that, noise-induced differences between patches are amplified due to the frequency gradient. Migration among desynchronized regions then stabilizes a "soft" limit cycle in the vicinity of the homogenous manifold. A simple model of diffusively coupled oscillators allows the derivation of quantitative results, like the functional dependence of the desynchronization upon diffusion strength and frequency differences. The oscillations' amplitude is shown to be (almost) noise independent. The results are compared with a numerical integration of the marginally stable Lotka-Volterra equations. An unstable system is extinction-prone for small noise, but stabilizes at larger noise intensity