Numerical Study of Wave Overtopping Based on Local Method of Approximate Particular Solution Method

In order to study the wave overtopping process, this paper establishes a two-dimensional numerical wave flume based on a meshless algorithm, local method of approximate particular solution (the LMAPS method), and the technology of momentum source wave. It calculates the climbing and overtopping process under regular waves on a typical slope, results of which are more consistent with the physical model test results. Finally, wave action simulation is carried out on six different structural forms of wave walls (vertical wave wall, 1/4 arc wave wall, reversed-arc wave wall, smooth surface wave wall with 1: 3 slope ratio, smooth surface wave wall with 1: 1.5 slope ratio and stepped surface wave wall with 1: 1.5 slope ratio). Numerical results of the simulation accurately describe the wave morphological changes in the interaction of waves and different structural forms of wave walls, in which, average error of wave overtopping is roughly 6.2% compared with the experimental values

Transport-Induced Inversion of Screening Ionic Charges in Nanochannels

This work reveals a counterintuitive but basic process of ionic screening in nanofluidic channels. Steady-state numerical simulations and mathematical analysis show that, under significant longitudinal ionic transport, the screening ionic charges can be locally inverted in the channels: their charge sign becomes the same as that of the channel surface charges. The process is identified to originate from the coupling of ionic electro-diffusion transport and junction two-dimensional electrostatics. This finding may expand our understanding of ionic screening and electrical double layers in nanochannels. Furthermore, the charge inversion process results in a body-force torque on channel fluids, which is a possible mechanism for vortex generation in the channels and their nonlinear current–voltage characteristics

Design of B/N Co-doped micro/meso porous carbon electrodes from CNF/BNNS/ZIF-8 nanocomposites for advanced supercapacitors

Boron (B) and nitrogen (N) co-doped 3D hierarchical micro/meso porous carbon (BNPC) were successfully fabricated from cellulose nanofiber (CNF)/ boron nitride nanosheets (BNNS)/ zinc-methylimidazolate framework-8 (ZIF-8) nanocomposites prepared by 2D BNNS, ZIF-8 nanoparticles, and wheat straw based CNFs. Herein, CNF/ZIF-8 acts as versatile skeleton and imparts partial N dopant into porous carbon structure, while the introduced BNNS can help strengthen the hierarchical porous superstructure and endow abundant B/N co-dopants within BNPC matrix. The obtained BNPC electrode possesses a high specific surface area of 505.4 m2/g, high B/N co-doping content, and desirable hydrophilicity. Supercapacitors assembled with BNPC-2 (B/N co-doped porous carbon with a CNF/BNNS mass ratio of 1꞉2) electrodes exhibited exceptional electrochemical performance, demonstrating high capacitance stability even after 5 000 charge-discharge cycles. The devices exhibited outstanding energy density and power density, as well as the highest specific capacitance of 433.4 F/g at 1.0 A/g, when compared with other similar reports. This study proposes a facile and sustainable strategy for efficiently fabrication of rich B/N co-doped hierarchical micro/meso porous carbon electrodes from agricultural waste biomass for advanced supercapacitor performance

Robust Guar Gum/Cellulose Nanofibrils Multilayer Films with Good Barrier Properties

The pursuit of sustainable functional materials requires development of materials based on renewable resources and efficient fabrication methods. Hereby, we fabricated all-polysaccharides multilayer films using cationic guar gum (CGG) and anionic cellulose nanofibrils (i.e., TEMPO-oxidized cellulose nanofibrils, TOCNs) through a layer-by-layer casting method. This technique is based on alternate depositions of oppositely charged water-based CGG and TOCNs onto laminated films. The resultant polyelectrolyte multilayer films were transparent, ductile, and strong. More importantly, the self-standing films exhibited excellent gas (water vapor and oxygen) and oil barrier performances. Another outstanding feature of these resultant films was their resistance to various organic solvents including methanol, acetone, <i>N</i>,<i>N</i>-dimethylacetamide (DMAc) and tetrahydrofuran (THF). The proposed film fabrication process is environmentally benign, cost-effective, and easy to scale-up. The developed CGG/TOCNs multilayer films can be used as a renewable material for industrial applications such as packaging