Structural and vibrational properties of two-dimensional MnxOy\rm Mn_xO_y nanolayers on Pd(100)

Using different experimental techniques combined with density functional based theoretical methods we have explored the formation of interface-stabilized manganese oxide structures grown on Pd(100) at (sub)monolayer coverage. Amongst the multitude of phases experimentally observed we focus our attention on four structures which can be classified into two distinct regimes, characterized by different building blocks. Two oxygen-rich phases are described in terms of MnO(111)-like O-Mn-O trilayers, whereas the other two have a lower oxygen content and are based on a MnO(100)-like monolayer structure. The excellent agreement between calculated and experimental scanning tunneling microscopy images and vibrational electron energy loss spectra allows for a detailed atomic description of the explored models.Comment: 14 pages, 11 figure

High-ionization mid-infrared lines as black hole mass and bolometric luminosity indicators in active galactic nuclei

We present relations of the black hole mass and the optical luminosity with the velocity dispersion and the luminosity of the [Ne V] and the [O IV] high-ionization lines in the mid-infrared (MIR) for 28 reverberation-mapped active galactic nuclei. We used high-resolution Spitzer Infrared Spectrograph and Infrared Space Observatory Short Wavelength Spectrometer data to fit the profiles of these MIR emission lines that originate from the narrow-line region of the nucleus. We find that the lines are often resolved and that the velocity dispersion of [Ne V] and [O IV] follows a relation similar to that between the black hole mass and the bulge stellar velocity dispersion found for local galaxies. The luminosity of the [Ne V] and the [O IV] lines in these sources is correlated with that of the optical 5100A continuum and with the black hole mass. Our results provide a means to derive black hole properties in various types of active galactic nuclei, including highly obscured systems.Comment: accepted for publication in ApJ

The Nature of Associated Absorption and the UV-X-ray Connection in 3C 288.1

We discuss new Hubble Space Telescope spectroscopy of the radio-loud quasar, 3C 288.1. The data cover ~590 A to ~1610 A in the quasar rest frame. They reveal a wealth of associated absorption lines (AALs) with no accompanying Lyman-limit absorption. The metallic AALs range in ionization from C III and N III to Ne VIII and Mg X. We use these data and photoionization models to derive the following properties of the AAL gas: 1) There are multiple ionization zones within the AAL region, spanning a factor of at least ~50 in ionization parameter. 2) The overall ionization is consistent with the ``warm'' X-ray continuum absorbers measured in Seyfert 1 nuclei and other QSOs. However, 3) the column densities implied by the AALs in 3C 288.1 are too low to produce significant bound-free absorption at any UV-X-ray wavelengths. Substantial X-ray absorption would require yet another zone, having a much higher ionization or a much lower velocity dispersion than the main AAL region. 4) The total hydrogen column density in the AAL gas is log N_H (cm-2)= 20.2. 5) The metallicity is roughly half solar. 6) The AALs have deconvolved widths of ~900 km/s and their centroids are consistent with no shift from the quasar systemic velocity (conservatively within +/-1000 km/s). 7) There are no direct indicators of the absorber's location in our data, but the high ionization and high metallicity both suggest a close physical relationship to the quasar/host galaxy environment. Finally, the UV continuum shape gives no indication of a ``blue bump'' at higher energies. There is a distinct break of unknown origin at ~1030 A, and the decline toward higher energies (with spectral index alpha = -1.73, for f_nu ~ nu^alpha) is even steeper than a single power-law interpolation from 1030 A to soft X-rays.Comment: 27 pages with figures and tables, in press with Ap

Fast-Growing SMBHs in Fast-Growing Galaxies, at High Redshifts: The Role of Major Mergers As Revealed by ALMA

We present a long-term, multi-wavelength project to understand the epoch of fastest growth of the most massive black holes by using a sample of 40 luminous quasars at z~4.8. These quasars have rather uniform properties, with typical accretion rates and black hole masses of L/L_Edd~0.7 and M_BH~10^9 M_sol. The sample consists of "FIR-bright" sources with a previous Herschel/SPIRE detection, suggesting SFR > 1000 M_sol/yr, as well as of "FIR-faint" sources for which Herschel stacking analysis implies a typical SFR of ~400 M_sol/yr. Six of the quasars have been observed by ALMA in [CII]{\lambda}157.74 micron line emission and adjacent rest-frame 150 micron continuum, to study the dusty cold ISM. ALMA detected companion, spectroscopically confirmed sub-mm galaxies (SMGs) for three sources - one FIR-bright and two FIR-faint. The companions are separated by ~14-45 kpc from the quasar hosts, and we interpret them as major galaxy interactions. Our ALMA data therefore clearly support the idea that major mergers may be important drivers for rapid, early SMBH growth. However, the fact that not all high-SFR quasar hosts are accompanied by interacting SMGs, and their ordered gas kinematics observed by ALMA, suggest that other processes may be fueling these systems. Our analysis thus demonstrates the diversity of host galaxy properties and gas accretion mechanisms associated with early and rapid SMBH growth

Probing the Ionizing Continuum of Narrow-Line Seyfert 1 Galaxies. I.Observational Results

We present optical spectra and emission-line ratios of 12 Narrow-Line Seyfert 1 (NLS1) galaxies that we observed to study the ionizing EUV continuum. A common feature in the EUV continuum of active galactic nuclei is the big blue bump (BBB), generally associated with thermal accretion disk emission. While Galactic absorption prevents direct access to the EUV range, it can be mapped by measuring the strength of a variety of forbidden optical emission lines that respond to different EUV continuum regions. We find that narrow emission-line ratios involving [OII]3727, Hbeta, [OIII]5007, [OI]6300, Halpha,[NII]6583, and [SII]6716,6731 indicate no significant difference between NLS1s and Broad-Line Seyfert 1 (BLS1) galaxies, which suggests that the spectral energy distributions of their ionizing EUV - soft X-ray continua are similar. The relative strength of important forbidden high ionization lines like [NeV]3426 compared to HeII4686 and the relative strength of [FeX]6374 appear to show the same range as in BLS1 galaxies. However, a trend of weaker F([OI]6300)/F(Halpha) emission-line ratios is indicated for NLS1s compared to BLS1s. To recover the broad emission-line profiles we used Gaussian components. This approach indicates that the broad Hbeta profile can be well described with a broad component (FWHM = 3275 +- 800 km/s) and an intermediate broad component (FWHM = 1200 +- 300 km/s). The width of the broad component is in the typical range of normal BLS1s. The emission-line flux that is associated with the broad component in these NLS1s amounts to at least 60% of the total flux. Thus it dominates the total line flux, similar to BLS1 galaxies.Comment: 34 pages, 9 figures. accepted for publication in the Astrophys.Journa

ALMA Observations of Quasar Host Galaxies at z ≃ 4.8

We present ALMA band-7 data of the [C ii] 157:74 m emission line and underlying far-infrared (FIR) continuum for twelve luminous quasars at z ' 4:8 powered by fast-growing supermassive black holes (SMBHs). Our total sample consists of eighteen quasars, twelve of which are presented here for the rst time. The new sources consists of six Herschel/SPIRE detected systems, which we de ne as "FIR-bright" sources, and six Herschel/SPIRE undetected systems, which we de ne as "FIR-faint" sources. We determine dust masses for the quasars hosts of Mdust 0:225:0 108M , implying ISM gas masses comparable to the dynamical masses derived from the [C ii] kinematics. It is found that on average the Mgii line is blueshifted by 500kms1 with respect to the [C ii] emission line, which is also observed when complementing our observations with data from the literature. We nd that all of our "FIR-bright" subsample and most of the "FIR-faint" objects lie above the main sequence of star forming galaxies at z 5. We detect companion sub-millimeter galaxies (SMGs) for two sources, both FIR-faint, with a range of projected distances of 20 60 kpc and with typical velocity shifts of j vj < 200kms1 from the quasar hosts. Of our total sample of eighteen quasars, 5/18 are found to have dust obscured starforming companions.ERC; STF

Interplay between magnetic, electronic and vibrational effects in monolayer Mn_3O_4 grown on Pd(100)

The surface stabilized MnO(100)-like monolayer, characterised by a regular c(4x2) distribution of Mn vacancies, is studied by hybrid functionals and discussed in the light of available scanning tunneling microscopy and high-resolution electron energy loss spectroscopy data. We show that the use of hybrid functionals is crucial to account for the intermingled nature of magnetic ineractions, electron localization, structural distortions and surface phonons. The proposed Pd(100) supported Mn3O4 structure is excellently compatible with the experiments previously reported in literature.Comment: 16 pages, 5 figure

A New H I Survey of Active Galaxies

We have conducted a new Arecibo survey for H I emission for 113 galaxies with broad-line (type 1) active galactic nuclei (AGNs) out to recession velocities as high as 35,000 km/s. The primary aim of the study is to obtain sensitive H I spectra for a well-defined, uniformly selected sample of active galaxies that have estimates of their black hole masses in order to investigate correlations between H I properties and the characteristics of the AGNs. H I emission was detected in 66 out of the 101 (65%) objects with spectra uncorrupted by radio frequency interference, among which 45 (68%) have line profiles with adequate signal-to-noise ratio and sufficiently reliable inclination corrections to yield robust deprojected rotational velocities. This paper presents the basic survey products, including an atlas of H I spectra, measurements of H I flux, line width, profile asymmetry, optical images, optical spectroscopic parameters, as well as a summary of a number of derived properties pertaining to the host galaxies. To enlarge our primary sample, we also assemble all previously published H I measurements of type 1 AGNs for which can can estimate black hole masses, which total an additional 53 objects. The final comprehensive compilation of 154 broad-line active galaxies, by far the largest sample ever studied, forms the basis of our companion paper, which uses the H I database to explore a number of properties of the AGN host galaxies.Comment: To appear in ApJS; 31 pages. Preprint will full-resolution figures can be downloaded from http://www.ociw.edu/~lho/preprints/ms1.pd

Magnetic Confinement, MHD Waves, and Smooth Line Profiles in AGN

In this paper, we show that if the broad line region clouds are in approximate energy equipartition between the magnetic field and gravity, as hypothesized by Rees, there will be a significant effect on the shape and smoothness of broad emission line profiles in active galactic nuclei. Line widths of contributing clouds or flow elements are much wider than their thermal widths, due to the presence of non-dissipative MHD waves, and their collective contribution produce emission line profiles broader and smoother than would be expected if a magnetic field were not present. As an illustration, a simple model of isotropically emitting clouds, normally distributed in velocity, is used to show that smoothness can be achieved for less than 80,000 clouds and may even be as low as a few hundred. We conclude that magnetic confinement has far reaching consequences for observing and modeling active galactic nuclei.Comment: to appear in MNRA