1,847 research outputs found

    3,5-Bis(4-chloro­benzyl­idene)-1-methyl­piperidin-4-one

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    In the title mol­ecule, C20H17Cl2NO, the central heterocyclic ring adopts a flattened boat conformation. The dihedral angles between the planar part of this central heterocyclic ring [maximum deviation = 0.004 (1) Å] and the two almost planar side-chain fragments [maximum deviations = 0.015 (1) and 0.019 (1) Å], that include the aromatic ring and bridging atoms, are 18.1 (1) and 18.0 (1)°. In the crystal, pairs of weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules into inversion dimers that form stacks along the a axis. The structure is further stabilized by weak inter­molecular C—H⋯π inter­actions involving the benzene rings

    1-Benzyl-3,5-bis­(4-chloro­benzyl­idene)piperidin-4-one

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    The title compound, C26H21Cl2NO, crystallizes with two symmetry-independent mol­ecules (A and B) in the asymmetric unit. In both mol­ecules, the central heterocyclic ring adopts a sofa conformation. The dihedral angles between the planar part of this central heterocyclic ring [maximum deviations of 0.011 (1) and 0.036 (1) Å in mol­ecules A and B, respectively] and the two almost planar [maximum deviations of 0.020 (1) and 0.008 (1) Å in A and 0.007 (1) and 0.011 (1) in B] side-chain fragments that include the aromatic ring and bridging atoms are 20.1 (1) and 31.2 (1)° in mol­ecule A, and 26.4 (1) and 19.6 (1)° in mol­ecule B. The dihedral angles between the planar part of the heterocyclic ring and the benzyl substituent are 79.7 (1) and 53.2 (1)° in mol­ecules A and B, respectively. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the two independent mol­ecules into dimers

    Use of computers to exclude the influence of radiometer instability upon measurement results

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    A radiometer, practically insensitive to great fluctuations in the equipment amplification coefficient, was developed by dividing the useful signal by a reference signal and modulating the two signals at different frequencies. The signals are simultaneously separated by corresponding synchronous detectors and recorded over two channels. The operation is simplified by replacing the continuous signals by a sampling of discrete values, and using a digital computer. The four steps involved in the process are described and a block diagram is included. This technique not only directly connects the radiometer with the computer, but also records all data provided by the control and signal channels

    Study of High Energy Gamma-Quanta Beyond the Atmosphere

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    Measurements of primary cosmic radiation gamma quanta from Proton I and II satellite

    Smooth Loops and Fiber Bundles: Theory of Principal Q-bundles

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    A nonassociative generalization of the principal fiber bundles with a smooth loop mapping on the fiber is presented. Our approach allows us to construct a new kind of gauge theories that involve higher ''nonassociative'' symmetries.Comment: 20 page

    Algebraic Model for scattering of three-s-cluster systems; 2, Resonances in the three-cluster continuum of 6He and 6Be

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    The resonance states embedded in the three-cluster continuum of 6He and 6Be are obtained in the Algebraic Version of the Resonating Group Method. The model accounts for a correct treatment of the Pauli principle. It also provides the correct three-cluster continuum boundary conditions by using a Hyperspherical Harmonics basis. The model reproduces the observed resonances well and achieves good agreement with other models. A better understanding for the process of formation and decay of the resonance states in six-nucleon systems is obtained

    Topological bands in two-dimensional networks of metamaterial elements

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    We show that topological frequency band structures emerge in two-dimensional electromagnetic lattices of metamaterial components without the application of an external magnetic field. The topological nature of the band structure manifests itself by the occurrence of exceptional points in the band structure or by the emergence of one-way guided modes. Based on an EM network with nearly flat frequency bands of nontrivial topology, we propose a coupled-cavity lattice made of superconducting transmission lines and cavity QED components which is described by the Janes-Cummings-Hubbard model and can serve as simulator of the fractional quantum Hall effect

    Structural and Functional Organization of Photosynthetic Apparatus in Wild Halophites

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    The structural and molecular parameters of photosynthetic apparatus in plants with different strategies for the accumulation of salts were investigated. The objects of the study were euhalophytes (Salicornia perennans, Suaeda salsa, Halocnemum strobilaceum), a crynohalophyte (Limonium gmelinii) and a glycohalophyte (Artemisia santonica). The euhalophytes S. perennans and S. salsa belong to plants of the halosucculent type, while the other three species represent the xerophilic type. Larger cells with a great number of chloroplasts, a high content of membrane glycerolipids and unsaturated C18:3 fatty acid and smaller pigment and light-harvesting complexes characterize the features of euhalophytes with a succulent leaf type. Therefore, thefeatures of the halophyte photosynthetic apparatus structure are closely related to its functional indicators and are defined by a strategy in both the accumulation of salts and the method of water regime regulation. Keywords: chlorophyll, lipids and fatty acids, photosynthetic apparatus, ultrastructure of chloroplast
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