320 research outputs found
Quantum bath refrigeration towards absolute zero: unattainability principle challenged
A minimal model of a quantum refrigerator (QR), i.e. a periodically
phase-flipped two-level system permanently coupled to a finite-capacity bath
(cold bath) and an infinite heat dump (hot bath), is introduced and used to
investigate the cooling of the cold bath towards the absolute zero (T=0).
Remarkably, the temperature scaling of the cold-bath cooling rate reveals that
it does not vanish as T->0 for certain realistic quantized baths, e.g. phonons
in strongly disordered media (fractons) or quantized spin-waves in ferromagnets
(magnons). This result challenges Nernst's third-law formulation known as the
unattainability principle
Transient energy excitation in shortcuts to adiabaticity for the time dependent harmonic oscillator
There is recently a surge of interest to cut down the time it takes to change
the state of a quantum system adiabatically. We study for the time-dependent
harmonic oscillator the transient energy excitation in speed-up processes
designed to reproduce the initial populations at some predetermined final
frequency and time, providing lower bounds and examples. Implications for the
limits imposed to the process times and for the principle of unattainability of
the absolute zero, in a single expansion or in quantum refrigerator cycles, are
drawn.Comment: 7 pages, 6 figure
Universal restrictions to the conversion of heat into work derived from the analysis of the Nernst theorem as a uniform limit
We revisit the relationship between the Nernst theorem and the Kelvin-Planck
statement of the second law. We propose that the exchange of entropy uniformly
vanishes as the temperature goes to zero. The analysis of this assumption shows
that is equivalent to the fact that the compensation of a Carnot engine scales
with the absorbed heat so that the Nernst theorem should be embedded in the
statement of the second law.
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Se analiza la relaci{\'o}n entre el teorema de Nernst y el enunciado de
Kelvin-Planck del segundo principio de la termodin{\'a}mica. Se{\~n}alamos el
hecho de que el cambio de entrop{\'\i}a tiende uniformemente a cero cuando la
temperatura tiende a cero. El an{\'a}lisis de esta hip{\'o}tesis muestra que es
equivalente al hecho de que la compensaci{\'o}n de una m{\'a}quina de Carnot
escala con el calor absorbido del foco caliente, de forma que el teorema de
Nernst puede derivarse del enunciado del segundo principio.Comment: 8pp, 4 ff. Original in english. Also available translation into
spanish. Twocolumn format. RevTe
The Quantum Refrigerator: The quest for absolute zero
The scaling of the optimal cooling power of a reciprocating quantum
refrigerator is sought as a function of the cold bath temperature as . The working medium consists of noninteracting particles in a harmonic
potential. Two closed-form solutions of the refrigeration cycle are analyzed,
and compared to a numerical optimization scheme, focusing on cooling toward
zero temperature. The optimal cycle is characterized by linear relations
between the heat extracted from the cold bath, the energy level spacing of the
working medium and the temperature. The scaling of the optimal cooling rate is
found to be proportional to giving a dynamical interpretation to
the third law of thermodynamics
Low temperature Thermodynamics in the Context of Dissipative Diamagnetism
We revisit here the effect of quantum dissipation on the much - studied
problem of Landau diamagnetism, and analyze the results in the light of the
third law of thermodynamics. The case of an additional parabolic potential is
separately assessed. We find that dissipation arising from strong coupling of
the system to its environment qualitatively alters the low-temperature
thermodynamic attributes such as the entropy and the specific heat
Diffuse-Charge Dynamics in Electrochemical Systems
The response of a model micro-electrochemical system to a time-dependent
applied voltage is analyzed. The article begins with a fresh historical review
including electrochemistry, colloidal science, and microfluidics. The model
problem consists of a symmetric binary electrolyte between parallel-plate,
blocking electrodes which suddenly apply a voltage. Compact Stern layers on the
electrodes are also taken into account. The Nernst-Planck-Poisson equations are
first linearized and solved by Laplace transforms for small voltages, and
numerical solutions are obtained for large voltages. The ``weakly nonlinear''
limit of thin double layers is then analyzed by matched asymptotic expansions
in the small parameter , where is the
screening length and the electrode separation. At leading order, the system
initially behaves like an RC circuit with a response time of
(not ), where is the ionic diffusivity, but nonlinearity
violates this common picture and introduce multiple time scales. The charging
process slows down, and neutral-salt adsorption by the diffuse part of the
double layer couples to bulk diffusion at the time scale, . In the
``strongly nonlinear'' regime (controlled by a dimensionless parameter
resembling the Dukhin number), this effect produces bulk concentration
gradients, and, at very large voltages, transient space charge. The article
concludes with an overview of more general situations involving surface
conduction, multi-component electrolytes, and Faradaic processes.Comment: 10 figs, 26 pages (double-column), 141 reference
Notes on the Third Law of Thermodynamics.I
We analyze some aspects of the third law of thermodynamics. We first review
both the entropic version (N) and the unattainability version (U) and the
relation occurring between them. Then, we heuristically interpret (N) as a
continuity boundary condition for thermodynamics at the boundary T=0 of the
thermodynamic domain. On a rigorous mathematical footing, we discuss the third
law both in Carath\'eodory's approach and in Gibbs' one. Carath\'eodory's
approach is fundamental in order to understand the nature of the surface T=0.
In fact, in this approach, under suitable mathematical conditions, T=0 appears
as a leaf of the foliation of the thermodynamic manifold associated with the
non-singular integrable Pfaffian form . Being a leaf, it cannot
intersect any other leaf const. of the foliation. We show that (N) is
equivalent to the requirement that T=0 is a leaf. In Gibbs' approach, the
peculiar nature of T=0 appears to be less evident because the existence of the
entropy is a postulate; nevertheless, it is still possible to conclude that the
lowest value of the entropy has to belong to the boundary of the convex set
where the function is defined.Comment: 29 pages, 2 figures; RevTex fil
Cosmological Dark Energy: Prospects for a Dynamical Theory
We present an approach to the problem of vacuum energy in cosmology, based on
dynamical screening of Lambda on the horizon scale. We review first the
physical basis of vacuum energy as a phenomenon connected with macroscopic
boundary conditions, and the origin of the idea of its screening by particle
creation and vacuum polarization effects. We discuss next the relevance of the
quantum trace anomaly to this issue. The trace anomaly implies additional terms
in the low energy effective theory of gravity, which amounts to a non-trivial
modification of the classical Einstein theory, fully consistent with the
Equivalence Principle. We show that the new dynamical degrees of freedom the
anomaly contains provide a natural mechanism for relaxing Lambda to zero on
cosmological scales. We consider possible signatures of the restoration of
conformal invariance predicted by the fluctuations of these new scalar degrees
of freedom on the spectrum and statistics of the CMB, in light of the latest
bounds from WMAP. Finally we assess the prospects for a new cosmological model
in which the dark energy adjusts itself dynamically to the cosmological horizon
boundary, and therefore remains naturally of order H^2 at all times without
fine tuning.Comment: 50 pages, Invited Contribution to New Journal of Physics Focus Issue
on Dark Energ
Movement and Fluctuations of the Vacuum
Quantum fields possess zero-point or vacuum fluctuations which induce
mechanical effects, namely generalised Casimir forces, on any scatterer.
Symmetries of vacuum therefore raise fundamental questions when confronted
with the principle of relativity of motion in vacuum. The specific case of
uniformly accelerated motion is particularly interesting, in connection with
the much debated question of the appearance of vacuum in accelerated frames.
The choice of Rindler representation, commonly used in General Relativity,
transforms vacuum fluctuations into thermal fluctuations, raising difficulties
of interpretation. In contrast, the conformal representation of uniformly
accelerated frames fits the symmetry properties of field propagation and
quantum vacuum and thus leads to extend the principle of relativity of motion
to uniform accelerations.
Mirrors moving in vacuum with a non uniform acceleration are known to
radiate. The associated radiation reaction force is directly connected to
fluctuating forces felt by motionless mirrors through fluctuation-dissipation
relations. Scatterers in vacuum undergo a quantum Brownian motion which
describes irreducible quantum fluctuations. Vacuum fluctuations impose ultimate
limitations on measurements of position in space-time, and thus challenge the
very concept of space-time localisation within a quantum framework.
For test masses greater than Planck mass, the ultimate limit in localisation
is determined by gravitational vacuum fluctuations. Not only positions in
space-time, but also geodesic distances, behave as quantum variables,
reflecting the necessary quantum nature of an underlying geometry.Comment: 17 pages, to appear in Reports on Progress in Physic
Prediction of Antibacterial Activity from Physicochemical Properties of Antimicrobial Peptides
Consensus is gathering that antimicrobial peptides that exert their antibacterial action at the membrane level must reach a local concentration threshold to become active. Studies of peptide interaction with model membranes do identify such disruptive thresholds but demonstrations of the possible correlation of these with the in vivo onset of activity have only recently been proposed. In addition, such thresholds observed in model membranes occur at local peptide concentrations close to full membrane coverage. In this work we fully develop an interaction model of antimicrobial peptides with biological membranes; by exploring the consequences of the underlying partition formalism we arrive at a relationship that provides antibacterial activity prediction from two biophysical parameters: the affinity of the peptide to the membrane and the critical bound peptide to lipid ratio. A straightforward and robust method to implement this relationship, with potential application to high-throughput screening approaches, is presented and tested. In addition, disruptive thresholds in model membranes and the onset of antibacterial peptide activity are shown to occur over the same range of locally bound peptide concentrations (10 to 100 mM), which conciliates the two types of observations
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