841 research outputs found
Photochemistry and kinetics of gas phase reactions involving HO and Cl radicals
The kinetics of the reaction of the HO radical with HNO/sub 3/ and H/sub 2/O/sub 2/, the kinetics of Cl atom reactions with ClNO and ClNO/sub 2/, and the photochemistry of ClNO/sub 2/ and ClONO/sub 2/ were examined. The ultraviolet absorption cross sections of HNO/sub 3/ and ClNO/sub 2/ were also determined as part of the kinetics work. The rate constant for the reaction of HO with HNO/sub 3/ at room temperature was measured to be (8.2 +- 1.8) x 10/sup -14/ cm/sup 3/ molecule/sup -1/ s/sup -1/, where the uncertainty reported here and in all cases reflects twice the experimental standard deviation plus an estimate of systematic errors. The rate constant for the reaction HO + H/sub 2/O/sub 2/ was measured as (1.57 +- 0.23) x 10/sup -12/ cm/sup 3/ molecule/sup -1/ s/sup -1/. This agrees well with the two latest determinations and serves as a calibration of the experimental apparatus used. The Cl + ClNO reaction rate constant was determined to be (1.65 +- 0.32) x 10/sup -11/ cm/sup 3/ molecule/sup -1/ s/sup -1/. The rate constant for the reaction of Cl + ClNO/sub 2/ was found to be (5.05 +- 0.75) x 10/sup -12/ cm/sup 3/ molecule/sup -1/ s/sup -1/. This is the first direct measurement of this rate constant. The photodissociation of ClNO/sub 2/ was studied in great detail. The absorption cross sections were measured in the ultraviolet and found to be substantially lower than the literature values in the Cl/sub 2/ absorption region (300 to 360 nm). Two product channels were investigated; products representative of the two channels were Cl and O atoms. Absolute calibration for the product detection systems was provided by Cl/sub 2/ and NO/sub 2/ photolysis respectively. The quantum uields measured for photolysis at 350 nm, calcualted using the absorption spectrum measured in this work, are: 0.93 +- 0.1 for Cl and less than or equal to 0.025 for O. An upper limit of 0.1 was measured for the O atom channel in ClOHO/sub 2/ photolysis
Reducing αENaC expression in the kidney connecting tubule induces pseudohypoaldosteronism type 1 symptoms during K+ loading.
Genetic inactivation of the epithelial Na(+) channel α-subunit (αENaC) in the renal collecting duct (CD) does not interfere with Na(+) and K(+) homeostasis in mice. However, inactivation in the CD and a part of the connecting tubule (CNT) induces autosomal recessive pseudohypoaldosteronism type 1 (PHA-1) symptoms in subjects already on a standard diet. In the present study, we further examined the importance of αENaC in the CNT. Knockout mice with αENaC deleted primarily in a part of the CNT (CNT-KO) were generated using Scnn1a(lox/lox) mice and Atp6v1b1::Cre mice. With a standard diet, plasma Na(+) concentration ([Na(+)]) and [K(+)], and urine Na(+) and K(+) output were unaffected. Seven days of Na(+) restriction (0.01% Na(+)) led to a higher urine Na(+) output only on days 3-5, and after 7 days plasma [Na(+)] and [K(+)] were unaffected. In contrast, the CNT-KO mice were highly susceptible to a 2-day 5% K(+) diet and showed lower food intake and relative body weight, lower plasma [Na(+)], higher fractional excretion (FE) of Na(+), higher plasma [K(+)], and lower FE of K(+). The higher FE of Na(+) coincided with lower abundance and phosphorylation of the Na(+)-Cl(-) cotransporter. In conclusion, reducing ENaC expression in the CNT induces clear PHA-1 symptoms during high dietary K(+) loading
Plasma S-adenosylmethionine, DNMT polymorphisms, and peripheral blood LINE-1 methylation among healthy Chinese adults in Singapore
10.1186/1471-2407-13-389BMC Cancer13-BCMA
Equivalence of the (generalised) Hadamard and microlocal spectrum condition for (generalised) free fields in curved spacetime
We prove that the singularity structure of all n-point distributions of a
state of a generalised real free scalar field in curved spacetime can be
estimated if the two-point distribution is of Hadamard form. In particular this
applies to the real free scalar field and the result has applications in
perturbative quantum field theory, showing that the class of all Hadamard
states is the state space of interest. In our proof we assume that the field is
a generalised free field, i.e. that it satisies scalar (c-number) commutation
relations, but it need not satisfy an equation of motion. The same argument
also works for anti-commutation relations and it can be generalised to
vector-valued fields. To indicate the strengths and limitations of our
assumption we also prove the analogues of a theorem by Borchers and Zimmermann
on the self-adjointness of field operators and of a very weak form of the
Jost-Schroer theorem. The original proofs of these results in the Wightman
framework make use of analytic continuation arguments. In our case no
analyticity is assumed, but to some extent the scalar commutation relations can
take its place.Comment: 18 page
Isospin Effects on Strangeness in Heavy-Ion Collisions
Kaon properties are studied within the framework of a fully covariant
transport approach. The kaon-nucleon potential is evaluated in two schemes, a
chiral perturbative approach and an effective One-Boson-Exchange model. Isospin
effects are explicitly accounted for in both models. The transport calculations
indicate a significant sensitivity of momentum distributions and total yields
of isospin states on the choice of the kaon-nucleon interaction.
Furthermore, isospin effects are rather moderate on absolute kaon yields, but
appear on strangeness ratios. This is an important issue in determining the
high density symmetry energy from studies of strangeness production in
heavy-ion collisions.Comment: 15 papes, 5 figures. Accepted for publication in Nuclear Physic
Quantum-fluctuation-induced collisions and subsequent excitation gap of an elastic string between walls
An elastic string embedded between rigid walls is simulated by means of the
density-matrix renormalization group. The string collides against the walls
owing to the quantum-mechanical zero-point fluctuations. Such ``quantum
entropic'' interaction has come under thorough theoretical investigation in the
context of the stripe phase observed experimentally in doped cuprates. We found
that the excitation gap opens in the form of exponential singularity DeltaE ~
exp(-Ad^sigma) (d: wall spacing) with the exponent sigma =0.6(3), which is
substantially smaller than the meanfield value sigma=2. That is, the excitation
gap is much larger than that anticipated from meanfield, suggesting that the
string is subjected to robust pinning potential due to the quantum collisions.
This feature supports Zaanen's ``order out of disorder'' mechanism which would
be responsible to the stabilization of the stripe phase
Flux-lattice melting in two-dimensional disordered superconductors
The flux line lattice melting transition in two-dimensional pure and
disordered superconductors is studied by a Monte Carlo simulation using the
lowest Landau level approximation and quasi-periodic boundary condition on a
plane. The position of the melting line was determined from the diffraction
pattern of the superconducting order parameter. In the clean case we confirmed
the results from earlier studies which show the existence of a quasi-long range
ordered vortex lattice at low temperatures. Adding frozen disorder to the
system the melting transition line is shifted to slightly lower fields. The
correlations of the order parameter for translational long range order of the
vortex positions seem to decay slightly faster than a power law (in agreement
with the theory of Carpentier and Le Doussal) although a simple power law decay
cannot be excluded. The corresponding positional glass correlation function
decays as a power law establishing the existence of a quasi-long range ordered
positional glass formed by the vortices. The correlation function
characterizing a phase coherent vortex glass decays however exponentially
ruling out the possible existence of a phase coherent vortex glass phase.Comment: 12 pages, 21 figures, final version to appear in Phys. Rev.
Possible implications of the channeling effect in NaI(Tl) crystals
The channeling effect of low energy ions along the crystallographic axes and
planes of NaI(Tl) crystals is discussed in the framework of corollary
investigations on WIMP Dark Matter candidates. In fact, the modeling of this
existing effect implies a more complex evaluation of the luminosity yield for
low energy recoiling Na and I ions. In the present paper related
phenomenological arguments are developed and possible implications are
discussed at some extent.Comment: 16 pages, 10 figures, preprint ROM2F/2007/15, submitted for
publicatio
Recent developments in planet migration theory
Planetary migration is the process by which a forming planet undergoes a
drift of its semi-major axis caused by the tidal interaction with its parent
protoplanetary disc. One of the key quantities to assess the migration of
embedded planets is the tidal torque between the disc and planet, which has two
components: the Lindblad torque and the corotation torque. We review the latest
results on both torque components for planets on circular orbits, with a
special emphasis on the various processes that give rise to additional, large
components of the corotation torque, and those contributing to the saturation
of this torque. These additional components of the corotation torque could help
address the shortcomings that have recently been exposed by models of planet
population syntheses. We also review recent results concerning the migration of
giant planets that carve gaps in the disc (type II migration) and the migration
of sub-giant planets that open partial gaps in massive discs (type III
migration).Comment: 52 pages, 18 figures. Review article to be published in "Tidal
effects in Astronomy and Astrophysics", Lecture Notes in Physic
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