440 research outputs found
Spectral and Photophysical Studies of Poly[2,6-(1,5-dioctylnaphthalene)]thiophenes
A complete spectroscopic and photophysical study of three alternating naphthalene-α-thiophene copolymers was undertaken in solution (room and low temperature) and in the solid state (thin films in a Zeonex matrix). The study comprises absorption, emission, and tripletâtriplet spectra together with quantitative measurements of quantum yield (fluorescence, intersystem-crossing, internal conversion, and singlet oxygen formation) lifetimes and singlet and triplet energies. The overall data allow the determination of the rate constants for all the decay processes. Comparison between the behavior of analogous 1-naphthyl(oligo)thiophenes and the 2,6-naphthalene(oligo)thiophene copolymers allows several important observations. First, the polymers display higher fluorescence quantum yields and lower S1âT1 intersystem-crossing yields than the oligomers. This can be attributed to the presence of the 1,5-dioctyloxynaphthalene groups in the copolymers leading to a more rigid polymer backbone, which decreases radiationless deactivation and increases the radiative efficiency. Second, the singlet and triplet energies are significantly lower in the polymers than with the corresponding oligomers. This implies a lower HOMOâLUMO energy difference in the polymers due to an extended Ï-delocalization. Third, the singlet-to-triplet (S1âT1) energy splitting is higher in the oligomers than with the polymers, even though the former display higher intersystem-crossing yields. It is suggested that this may result from intersystem-crossing in the oligomers involving significant charge-transfer (CT) character (spin-orbit coupling is mediated by CT mixing involving the singlet and triplet states in matrix elements of the type 1ΚCT |Hâ|3Κ1) of the relevant excited states but that is less important with the polymers. We believe that this may be relevant to understanding the nature of CT states in conjugated copolymers
The diet of red-throated divers (Gavia stellata) overwintering in the German Bight (North Sea) analysed using molecular diagnostics
In Europe, the German Bight is one of the most important non-breeding areas for protected red-throated divers (Gavia stellata). It is unclear what attracts the birds to this area, especially as the food composition of seabirds outside the breeding season is notoriously difficult to study. To obtain information on prey species composition of red-throated divers in this area, faecal samples from 34 birds caught alive were analysed using DNA metabarcoding. Prey DNA was detected in 85% of the samples with a mean number of 4.2â±â0.7 taxa per sample (nâ=â29). Altogether, we found a broad prey spectrum with 19 fish taxa from 13 families dominated by five groups: clupeids, mackerel, gadoids, flatfish and sand lances with clupeids being the most frequently detected prey. Our results indicate that red-throated divers are generalist opportunistic feeders in the German Bight, but pelagic schooling fish that aggregate at frontal zones and have a high energetic value might be favoured. Atlantic mackerel appears to be a more important prey for red-throated divers in this area than previously thought. The precision achievable using metabarcoding has revealed a number of prey species that are consumed by red-throated divers in the German Bight, which helps to explain the selection of this area by divers in winter and spring
Radio Emission in Atmospheric Air Showers: First Measurements with LOPES-30
When Ultra High Energy Cosmic Rays interact with particles in the Earth's
atmosphere, they produce a shower of secondary particles propagating toward the
ground. LOPES-30 is an absolutely calibrated array of 30 dipole antennas
investigating the radio emission from these showers in detail and clarifying if
the technique is useful for largescale applications. LOPES-30 is co-located and
measures in coincidence with the air shower experiment KASCADE-Grande. Status
of LOPES-30 and first measurements are presented.Comment: Proceedings of ARENA 06, June 2006, University of Northumbria, U
Results from the KASCADE, KASCADE-Grande, and LOPES experiments
The origin of high-energy cosmic rays in the energy range from 10^14 to 10^18
eV is explored with the KASCADE and KASCADE-Grande experiments. Radio signals
from air showers are measured with the LOPES experiment. An overview on results
is given.Comment: Talk at The ninth International Conference on Topics in Astroparticle
and Underground Physics, TAUP 2005, Zaragoza, September 10-14, 200
Air Shower Measurements with the LOPES Radio Antenna Array
LOPES is set up at the location of the KASCADE-Grande extensive air shower
experiment in Karlsruhe, Germany and aims to measure and investigate radio
pulses from Extensive Air Showers. Since radio waves suffer very little
attenuation, radio measurements allow the detection of very distant or highly
inclined showers. These waves can be recorded day and night, and provide a
bolometric measure of the leptonic shower component. LOPES is designed as a
digital radio interferometer using high bandwidths and fast data processing and
profits from the reconstructed air shower observables of KASCADE-Grande. The
LOPES antennas are absolutely amplitude calibrated allowing to reconstruct the
electric field strength which can be compared with predictions from detailed
Monte Carlo simulations. We report about the analysis of correlations present
in the radio signals measured by the LOPES 30 antenna array. Additionally,
LOPES operates antennas of a different type (LOPES-STAR) which are optimized
for an application at the Pierre Auger Observatory. Status, recent results of
the data analysis and further perspectives of LOPES and the possible large
scale application of this new detection technique are discussed.Comment: 8 pages, 10 figures, Contribution to the Arena 2008 conference, Rome,
June 200
Radio detection of cosmic ray air showers with LOPES
In the last few years, radio detection of cosmic ray air showers has
experienced a true renaissance, becoming manifest in a number of new
experiments and simulation efforts. In particular, the LOPES project has
successfully implemented modern interferometric methods to measure the radio
emission from extensive air showers. LOPES has confirmed that the emission is
coherent and of geomagnetic origin, as expected by the geosynchrotron
mechanism, and has demonstrated that a large scale application of the radio
technique has great potential to complement current measurements of ultra-high
energy cosmic rays. We describe the current status, most recent results and
open questions regarding radio detection of cosmic rays and give an overview of
ongoing research and development for an application of the radio technique in
the framework of the Pierre Auger Observatory.Comment: 8 pages; Proceedings of the CRIS2006 conference, Catania, Italy; to
be published in Nuclear Physics B, Proceedings Supplement
Radio emission of highly inclined cosmic ray air showers measured with LOPES
LOPES-10 (the first phase of LOPES, consisting of 10 antennas) detected a
significant number of cosmic ray air showers with a zenith angle larger than
50, and many of these have very high radio field strengths. The most
inclined event that has been detected with LOPES-10 has a zenith angle of
almost 80. This is proof that the new technique is also applicable
for cosmic ray air showers with high inclinations, which in the case that they
are initiated close to the ground, can be a signature of neutrino events.Our
results indicate that arrays of simple radio antennas can be used for the
detection of highly inclined air showers, which might be triggered by
neutrinos. In addition, we found that the radio pulse height (normalized with
the muon number) for highly inclined events increases with the geomagnetic
angle, which confirms the geomagnetic origin of radio emission in cosmic ray
air showers.Comment: A&A accepte
Energy Spectra of Elemental Groups of Cosmic Rays: Update on the KASCADE Unfolding Analysis
The KASCADE experiment measures extensive air showers induced by cosmic rays
in the energy range around the so-called knee. The data of KASCADE have been
used in a composition analysis showing the knee at 3-5 PeV to be caused by a
steepening in the light-element spectra. Since the applied unfolding analysis
depends crucially on simulations of air showers, different high energy hadronic
interaction models (QGSJet and SIBYLL) were used. The results have shown a
strong dependence of the relative abundance of the individual mass groups on
the underlying model. In this update of the analysis we apply the unfolding
method with a different low energy interaction model (FLUKA instead of GHEISHA)
in the simulations. While the resulting individual mass group spectra do not
change significantly, the overall description of the measured data improves by
using the FLUKA model. In addition data in a larger range of zenith angle are
analysed. The new results are completely consistent, i.e. there is no hint to
any severe problem in applying the unfolding analysis method to KASCADE data.Comment: accepted for publication in Astroparticle Physic
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