Image states in metal clusters

The existence of image states in small clusters is shown, using a quantum-mechanical many-body approach. We present image state energies and wave functions for spherical jellium clusters up to 186 atoms, calculated in the GW approximation, where G is the Green's function and W is the dynamically screened Coulomb interaction, which by construction contains the dynamic long-range correlation effects that give rise to image effects. In addition, we find that image states are also subject to quantum confinement. To extrapolate our investigations to clusters in the mesoscopic size range, we propose a semiclassical model potential, which we test against our full GW results

Quenched Dislocation Enhanced Supersolid Ordering

I show using Landau theory that quenched dislocations can facilitate the supersolid (SS) to normal solid (NS) transition, making it possible for the transition to occur even if it does not in a dislocation-free crystal. I make detailed predictions for the dependence of the SS to NS transition temperature T_c(L), superfluid density %\rho_S(T, L), and specific heat C(T,L) on temperature T and dislocation spacing L, all of which can be tested against experiments. The results should also be applicable to an enormous variety of other systems, including, e.g., ferromagnets.Comment: 5 pages, 2 figure

Relaxation of superflow in a network: an application to the dislocation model of supersolidity of helium crystals

We have considered the dislocation network model for the supersolid state in He-4 crystals. In difference with uniform 2D and 3D systems, the temperature of superfluid transition T_c in the network is much smaller than the degeneracy temperature T_d. It is shown that a crossover into a quasi superfluid state occurs in the temperature interval between T_c and T_d. Below the crossover temperature the time of decay of the flow increases exponentially under decrease of the temperature. The crossover has a continuous character and the crossover temperature does not depend on the density of dislocations.Comment: Corrected typo

Dislocation-induced superfluidity in a model supersolid

Motivated by recent experiments on the supersolid behavior of $^4$He, we study the effect of an edge dislocation in promoting superfluidity in a Bose crystal. Using Landau theory, we couple the elastic strain field of the dislocation to the superfluid density, and use a linear analysis to show that superfluidity nucleates on the dislocation before occurring in the bulk of the solid. Moving beyond the linear analysis, we develop a systematic perturbation theory in the weakly nonlinear regime, and use this method to integrate out transverse degrees of freedom and derive a one-dimensional Landau equation for the superfluid order parameter. We then extend our analysis to a network of dislocation lines, and derive an XY model for the dislocation network by integrating over fluctuations in the order parameter. Our results show that the ordering temperature for the network has a sensitive dependence on the dislocation density, consistent with numerous experiments that find a clear connection between the sample quality and the supersolid response.Comment: 10 pages, 6 figure

Helical, Angular and Radial Ordering in Narrow Capillaries

To enlighten the nature of the order-disorder and order-order transitions in block copolymer melts confined in narrow capillaries we analyze peculiarities of the conventional Landau weak crystallization theory of systems confined to cylindrical geometry. This phenomenological approach provides a quantitative classification of the cylindrical ordered morphologies by expansion of the order parameter spatial distribution into the eigenfunctions of the Laplace operator. The symmetry of the resulting ordered morphologies is shown to strongly depend both on the boundary conditions (wall preference) and the ratio of the cylinder radius and the wave length of the critical order parameter fluctuations, which determine the bulk ordering of the system under consideration. In particular, occurrence of the helical morphologies is a rather general consequence of the imposed cylindrical symmetry for narrow enough capillaries. We discuss also the ODT and OOT involving some other simplest morphologies. The presented results are relevant also to other ordering systems as charge-density waves appearing under addition of an ionic solute to a solvent in its critical region, weakly charged polyelectrolyte solutions in poor solvent, microemulsions etc.Comment: 6 pages, 3 figure

Dynamics of Binary Mixtures with Ions: Dynamic Structure Factor and Mesophase Formation

Dynamic equations are presented for polar binary mixtures containing ions in the presence of the preferential solvation. In one-phase states, we calculate the dynamic structure factor of the composition accounting for the ion motions. Microphase separation can take place for sufficiently large solvation asymmetry of the cations and the anions. We show two-dimensional simulation results of the mesophase formation with an antagonistic salt, where the cations are hydrophilic and the anions are hydrophobic. The structure factor S(q) in the resultant mesophase has a sharp peak at an intermediate wave number on the order of the Debye-Huckel wave number. As the quench depth is increased, the surface tension nearly vanishes in mesophases due to an electric double layer.Comment: 24 pages, 10 figures, to appear in Journal of Physics: Condensed Matte

Retarded Casimir-Polder force on an atom near reflecting microstructures

We derive the fully retarded energy shift of a neutral atom in two different geometries useful for modelling etched microstructures. First we calculate the energy shift due to a reflecting cylindrical wire, and then we work out the energy shift due to a semi-infinite reflecting half-plane. We analyze the results for the wire in various limits of the wire radius and the distance of the atom from the wire, and obtain simple asymptotic expressions useful for estimates. For the half-plane we find an exact representation of the Casimir-Polder interaction in terms of a single, fast converging integral, which is easy to evaluate numerically.Comment: 12 pages, 8 figure

Peculiar behavior of the electrical resistivity of MnSi at the ferromagnetic phase transition

The electrical resistivity of a single crystal of MnSi was measured across its ferromagnetic phase transition line at ambient and high pressures. Sharp peaks of the temperature coefficient of resistivity characterize the transition line. Analysis of these data shows that at pressures to ~0.35 GPa these peaks have fine structure, revealing a shoulder at ~ 0.5 K above the peak. It is symptomatic that this structure disappears at pressures higher than ~0.35 GPa, which was identified earlier as a tricritical poin

Bound states of edge dislocations: The quantum dipole problem in two dimensions

We investigate bound state solutions of the 2D Schr\"odinger equation with a dipole potential originating from the elastic effects of a single edge dislocation. The knowledge of these states could be useful for understanding a wide variety of physical systems, including superfluid behavior along dislocations in solid $^4$He. We present a review of the results obtained by previous workers together with an improved variational estimate of the ground state energy. We then numerically solve the eigenvalue problem and calculate the energy spectrum. In our dimensionless units, we find a ground state energy of -0.139, which is lower than any previous estimate. We also make successful contact with the behavior of the energy spectrum as derived from semiclassical considerations.Comment: 6 pages, 3 figures, submitted to PR

Superfluid density near the critical temperature in the presence of random planar defects

The superfluid density near the superconducting transition is investigated in the presence of spatial inhomogeneity in the critical temperature. Disorder is accounted for by means of a random $T_c$ term in the conventional Ginzburg-Landau action for the superconducting order parameter. Focusing on the case where a low-density of randomly distributed planar defects are responsible for the variation of $T_c$, we derive the lowest order correction to the superfluid density in powers of the defect concentration. The correction is calculated assuming a broad Gaussian distribution for the strengths of the defect potentials. Our results are in a qualitative agreement with the superfluid density measurements in the underdoped regime of high-quality YBCO crystals by Broun and co-workers.Comment: 14 pages, 7 figures; Accepted to Phys. Rev.