Preparation and characterization of Bi26–2xMn2xMo10O69-d and Bi26.4Mn0.6Mo10–2yMe2yO69-d(Me = V, Fe) solid solutions

Received: 06.06.2017; accepted: 23.06.2017; published: 14.07.2017.Single phase samples of bismuth molybdate, Bi26Mo10O69, doped with Mn on the bismuth sublattice and V, Fe on the molybdenum sublattice were found to crystallize in the triclinic Bi26Mo10O69 structure at low doping levels and in the monoclinic Bi26Mo10O69 structure - at higher dopant concentration. The assumption that all Mn ions have an oxidation state of +2 was confirmed by means of magnetic measurement results analysis using Curie-Weiss law. Conductivity was investigated using impedance spectroscopy. The conductivity of Bi26.4Mn0.6Mo9.6Fe0.4O69-d was 1.2*10-2 S*cm-1 at 973 K and 2.2*10-4 S*cm-1 at 623 K, and the conductivity of Bi26.4Mn0.6Mo9.2V0.8O69-d was 2.2*10-3 S*cm-1 at 973 K and 2.2*10-5 S*cm-1 at 623 K

Overhauser effect in individual InP/GaInP dots

Sizable nuclear spin polarization is pumped in individual InP/GaInP dots in a wide range of external magnetic fields B_ext=0-5T by circularly polarized optical excitation. We observe nuclear polarization of up to ~40% at Bext=1.5T and corresponding to an Overhauser field of ~1.2T. We find a strong feedback of the nuclear spin on the spin pumping efficiency. This feedback, produced by the Overhauser field, leads to nuclear spin bi-stability at low magnetic fields of Bext=0.5-1.5T. We find that the exciton Zeeman energy increases markedly, when the Overhauser field cancels the external field. This counter-intuitive result is shown to arise from the opposite contribution of the electron and hole Zeeman splittings to the total exciton Zeeman energy

Overhauser effect in individual InP/GaInP dots

Sizable nuclear spin polarization is pumped in individual InP/GaInP dots in a wide range of external magnetic fields B_ext=0-5T by circularly polarized optical excitation. We observe nuclear polarization of up to ~40% at Bext=1.5T and corresponding to an Overhauser field of ~1.2T. We find a strong feedback of the nuclear spin on the spin pumping efficiency. This feedback, produced by the Overhauser field, leads to nuclear spin bi-stability at low magnetic fields of Bext=0.5-1.5T. We find that the exciton Zeeman energy increases markedly, when the Overhauser field cancels the external field. This counter-intuitive result is shown to arise from the opposite contribution of the electron and hole Zeeman splittings to the total exciton Zeeman energy

Theory of grain mixture particle motion during aspiration separation

The practice of separating grain mixtures with the use of the difference in the aerodynamic properties of their components has proved that the process of separating mixtures in the aspiration separator is the most promising one with regard to the improvement of quality and intensification of production. The authors have developed a new improved design of aspiration seed separators, in which the work process of separating seed material is performed with the use of vibration processes. In this seed material separator, the constant force air flow that acts on the sail members on the central pipe of the separator, when seeds are fed for processing, generates self-excited oscillations in the pipe, which produces centrifugal forces of inertia in the seed feeding system. As a result of the mentioned effect, the propelling force in the process under study substantially increases, accelerating the seeds of different fractions, which differ in their masses, to different velocities. The motion paths of the seed particles change accordingly, heavier particles moving closer to the vertical axis of the aspiration channel, which provides for increasing the efficiency of separation of the seeds of different fractions from each other. In this paper, a new mathematical model is developed for the motion of a seed mixture material particle in the operating space of the separator’s aspiration channel. The mathematical modelling of the process of vibration and aspiration separation has indicated that the separation of the motion paths of the medium and heavy fractions takes place within the range of 20–40 mm; the flying speed of the particles is equal to 3.2–8.0 m s–1, respectively; and their acceleration is equal to 1.8– 3.3 m s–2, which provides the necessary conditions for the accurate and high quality separation into the required fractions. In view of the found differences between the kinematic characteristics of the separated fractions of the grain mixture, the diameter of the pipeline for the medium fraction is to be within the range of 90–100 mm, for the heavy fraction – 50–70 mm

Mathematical model of cleaning potatoes on surface of spiral separator

ArticleCleaning potato tubers from soil impurities and plant debris after digging them out of soil is a topical problem in the work process of potato production. Therefore, the engineer ing of new designs of potato heap separators necessitates the further studying of them and the optimisation of their kinematic and design parameters, which must not only ensure the high quality of cleaning, but also rule out the possibility of damaging the tubers. The aim of this study is to determine the design and kinematic parameters of the improved design of the spiral potato separator, which will ensure the high quality of cleaning and rule out the possibility of damaging the tubers, on the basis of th e development of the new theory of potato tuber’s motion on the surface of the separator. An analytical study has been carried out resulting in the construction of the equivalent schematic model of the interaction between the potato tuber and separator, th e tuber being approximated by a material point on the surface formed by the two cantilevered spirals, which are the separator’s tools. The separator’s spirals are driven to rotate and at the same time they can perform oscillations in the vertical and axial plane under the action of the varying load generated by the continuous feeding of the potato heap for separation. In the model, the forces acting on the potato tuber’s body are applied to it, the coordinate axes that have been selected and appropriately o riented are shown. A system of equations has been set up for the constructed equivalent schematic model, comprising three differential equations of the potato tuber body’s motion on the surface of the trough formed by the two cantilevered spirals. The dete rmined kinematic and design parameters will allow to raise the quality of cleaning potato tubers from soil impurities and plant debris.

Interaction between the Arctic and Non-Arctic States in Scientific Research and Practical Development of the Geopolitical Potential of the Arctic

Aim. Reveal the methodological role of ideas about the geopolitical potential of the state in making managerial decisions in the development of the space of the Russian Arctic. The article presents an overview of fundamental research and articles by foreign authors that addresses the problem of realizing the geopolitical potential of the Arctic.Tasks. Development of the principles of geopolitical forecasting based on mathematical modeling of the geopolitical potential of the state and systematization of developments on the spatial development of the Russian Arctic as part of Greater Eurasia.Methods. Mathematical modeling of geopolitical processes, medium-term forecasting of the spatial development of the Russian Arctic in the face of challenges from foreign states claiming its natural resources and territorial waters.Results. It confirms the need to include scientific developments in the methodological apparatus of geopolitical research to identify qualitative and quantitative definitions of the geopolitical potential of the state, which contributes to ensuring the national security of Russia and improving its spatial development.Conclusions. The transition to the sixth technological mode is not limited to a radical transformation of the country’s production complex, but also implies the need to create a unified infrastructure architecture for the Greater Eurasia (“smart” Eurasia), into which the Russian Arctic organically fits

Correction: Synthesis and crystal structure of a new hexagonal perovskite 7H-Ba7Li1.75Mn3.5O15.75 with Mn4+/Mn5+ charge distribution.

The authors regret a spelling mistake in the surname of one of authors. The surname given as ‘Vasilev’ should be ‘Vasiliev’. Furthermore a second affiliation for the author A. D. Vasiliev was inadvertently omitted. The correct spelling and affiliations of all the authors for this paper is as shown above. The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers

Synthesis, Structure, and Investigation of Bismuth Niobate Doped by Alkaline-Earth Elements

Polycrystalline samples with general formula Bi3