7,698 research outputs found
Na atomic order, Co charge disproportionation and magnetism in NaCoO for large Na contents
We have synthesized and characterized four different stable phases of Na
ordered NaCoO, for . Above 100 K they display similar
Curie-Weiss susceptibilities as well as ferromagnetic spin fluctuations
in the CoO planes revealed by Na NMR data. In all phases from
Co NMR data we display evidences that the Co disproportionate already
above 300 K into non magnetic Co and magnetic Co
sites on which holes delocalize. This allows us to understand that metallic
magnetism is favored for these large Na contents. Below 100 K the phases
differentiate, and a magnetic order sets in only for at
22 K. We suggest that the charge order also governs the low energy
scales and transverse couplings
Watershed Vulnerability To Herbicide Transport in Northern Missouri and Southern Iowa Streams
Herbicide contamination of streams has been well documented, but little is currently known about the specific factors affecting watershed vulnerability to herbicide transport. The primary objectives of this study were (1) to document herbicide occurrence and transport from watersheds in the northern Missouri/ southern Iowa region; (2) to quantify watershed vulnerability to herbicide transport and relate vulnerability to soil properties; and (3) to compute the contribution of this region to the herbicide load of the Missouri and Mississippi Rivers. Grab samples were collected under baseflow and runoff conditions at 21 hydrologic monitoring stations between April 15 and July 15 from 1996 to 1999. Samples were analyzed for commonly used soil-applied herbicides (atrazine, cyanazine, acetochlor, alachlor, metolachlor, and metribuzin) and four triazine metabolites (deisopropylatrazine, deethylatrazine, hydroxyatrazine, and cyanazine amide). Estimates of herbicide load and relative losses were computed for each watershed. Median parent herbicide losses, as a percentage of applied, ranged from 0.33 to 3.9%; loss rates that were considerably higher than other areas of the United States. Watershed vulnerability to herbicide transport, measured as herbicide load per treated area, showed that the runoff potential of soils was a critical factor affecting herbicide transport. Herbicide transport from these watersheds contributed a disproportionately high amount of the herbicide load to both the Missouri and Mississippi Rivers. Based on these results, this region of the Corn Belt is highly vulnerable to transport of herbicides from fields to streams, and it should be targeted for implementation of management practices designed to reduce herbicide losses in surface runoff
Evidence for the contribution of sulfur–bromine intramolecular interactions to the self-rigidification of thiophene-based π-conjugated systems
Bithiophene associating 3,4-ethylenedioxythiophene and 3-bromothiophene, and the corresponding polymer exhibit self-rigidified structures of the conjugated backbones resulting from the association of S–Br and S–O non-bonded intramolecular interactions
Intrinsic susceptibility and bond defects in the novel 2D frustrated antiferromagnet BaSnZnCrGaO
We present microscopic and macroscopic magnetic properties of the highly
frustrated antiferromagnet BaSnZnCrGaO,
respectively probed with NMR and SQUID experiments. The -variation of the
intrinsic susceptibility of the Cr frustrated kagom\'{e} bilayer,
, displays a maximum around 45 K. The dilution of the magnetic
lattice has been studied in detail for . Novel dilution
independent defects, likely related with magnetic bond disorder, are evidenced
and discussed. We compare our results to SrCrGaO. Both
bond defects and spin vacancies do not affect the average susceptibility of the
kagom\'{e} bilayers.Comment: Published in Phys. Rev. Lett. 92, 217202 (2004). Only minor changes
as compared to previous version. 4 pages, 4 figure
On Quantum Jumps, Events and Spontaneous Localization Models
We propose a definite meaning to the concepts of "experiment", "measurement"
and "event" in the event-enhanced formalism of quantum theory. A minimal
piecewise deterministic process is given that can be used for a computer
simulation of real time series of experiments on single quantum objects. As an
example a generalized cloud chamber is described, including multiparticle case.
Relation to the GRW spontaneous localization model is discussed. The second
revised version of the paper contains references to papers by other authors
that are are aiming in the same direction: to enhance quantum theory in such a
way that it will provide stochastic description of events triggered by
individual quantum systems.Comment: 20 page
Numerical analysis of a spontaneous collapse model for a two-level system
We study a spontaneous collapse model for a two-level (spin) system, in which
the Hamiltonian and the stochastic terms do not commute. The numerical solution
of the equations of motions allows to give precise estimates on the regime at
which the collapse of the state vector occurs, the reduction and delocalization
times, and the reduction probabilities; it also allows to quantify the effect
that an Hamiltonian which does not commute with the reducing terms has on the
collapse mechanism. We also give a clear picture of the transition from the
"microscopic" regime (when the noise terms are weak and the Hamiltonian
prevents the state vector to collapse) to the "macroscopic" regime (when the
noise terms are dominant and the collapse becomes effective for very long
times). Finally, we clarify the distinction between decoherence and collapse.Comment: 7 pages, RevTeX. Significative improvements made. To appear on Phys.
Rev.
Normal State Magnetic Properties of Ni and Zn Substituted in YBa_{2}Cu_{3} O_{6+x}: Hole-Doping Dependence
We present SQUID susceptibility data on Zn and Ni substituted
YBa_{2}Cu_{3}O_{6+x}. Cross-checks with NMR yield an unprecedented accuracy in
the estimate of the magnetic susceptibility associated with the substituants,
from the underdoped to the lightly overdoped case. This allows us to determine
the Weiss temperature \theta for YBCO: its value is very small for all hole
dopings n_h. Since in conventional metals, the Kondo temperature,
, magnetic screening effects would not be expected for ; in contrast, increasing n_h produces a reduction of the small moment
induced by Zn^{2+} and a nearly constant effective moment for Ni^{2+}
corresponding to a spin 1/2 rather than to a spin 1.Comment: 4 pages, 5 figures, to be published in Europhysics Letter
Lyapunov exponents and transport in the Zhang model of Self-Organized Criticality
We discuss the role played by the Lyapunov exponents in the dynamics of
Zhang's model of Self-Organized Criticality. We show that a large part of the
spectrum (slowest modes) is associated with the energy transpor in the lattice.
In particular, we give bounds on the first negative Lyapunov exponent in terms
of the energy flux dissipated at the boundaries per unit of time. We then
establish an explicit formula for the transport modes that appear as diffusion
modes in a landscape where the metric is given by the density of active sites.
We use a finite size scaling ansatz for the Lyapunov spectrum and relate the
scaling exponent to the scaling of quantities like avalanche size, duration,
density of active sites, etc ...Comment: 33 pages, 6 figures, 1 table (to appear
On Uniqueness of the Jump Process in Quantum Measurement Theory
We prove that, contrary to the standard quantum theory of continuous
observation, in the formalism of Event Enhanced Quantum Theory the stochastic
process generating individual sample histories of pairs (observed quantum
system, observing classical apparatus) is unique. This result gives a rigorous
basis to the previous heuristic argument of Blanchard and Jadczyk. Possible
implications of this result are discussed.Comment: 31 pages, LaTeX, article; e-mail contact [email protected]
Relationship of Decan volcanism to global K-T biotic extinctions: a case of unfounded assumptions?
This article does not have an abstract
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