2,034 research outputs found
Distortion and orientation of fulleride ions in A(4)C(60)
A(4)C(60) compounds (A = K, Rb, Cs) are good candidates to exhibit the Mott-Jahn-Teller insulating
state. We present near-IR and neutron scattering data to reflect molecular and crystal stucture
changes with temperature. We show how the size of the cation affects the structural and electronic
properties of these compounds
Mean-Field Approximation to the Master Equation for Sympathetic Cooling of Trapped Bosons
We use the mean-field approximation to simplify the master equation for
sympathetic cooling of Bosons. For the mean single-particle occupation numbers,
this approach yields the same equations as the factorization assumption
introduced in an erlier paper. The stationary or equilibrium solution of the
resulting master equation for the one-body density matrix shows that the
mean-field approximation breaks down whenever the fraction of condensate Bosons
exceeds ten percent or so of the total. Using group-theoretical methods, we
also solve the time-dependent master equation for the one-body density matrix.
Given the time dependence of the mean single-particle occupation numbers, this
solution is obtained by quadratures. It tends asymptotically towards the
equilibrium solution.Comment: submitted to PR
Electronic and structural properties of alkali doped SWNT
Comprehensive experiments on structural and transport properties of alkali intercalated
single walled carbon nanotubes (SWNT) are presented. The increasing electron density was
measured as a shift of the Drude-edge in optical reflectivity in-situ with progressive doping. In
saturation-doped samples the Drude-edge shifts into the visible (to 25,000 - 30,000 cm— 1 for potassium
and rubidium doped samples) and the samples have a golden-brown color, similar to stage I
graphite. X-ray diffraction reveals a crystalline rope structure with expanded lattice constant, similar
to results of Duclaux et al. The change in the low temperature divergence of the resistivity after
degassing at high temperature and high vacuum and after K-doping is studied in-situ
Charge transfer and Fermi level shift in p-doped single-walled carbon nanotubes
The electronic properties of p-doped single-walled carbon nanotube (SWNT) bulk samples were studied by temperature-dependent resistivity and thermopower, optical reflectivity, and Raman spectroscopy. These all give consistent results for the Fermi level downshift (Delta E(F)) induced by doping. We find Delta E(F) approximate to 0.35 eV and 0.50 eV for concentrated nitric and sulfuric acid doping respectively. With these values, the evolution of Raman spectra can be explained by variations in the resonance condition as E(F) moves down into the valence band. Furthermore, we find no evidence for diameter-selective doping, nor any distinction between doping responses of metallic and semiconducting tubes
Ordered low-temperature structure in K4C60 detected by infrared spectroscopy
Infrared spectra of a K4C60 single-phase thin film have been measured between
room temperature and 20 K. At low temperatures, the two high-frequency T1u
modes appear as triplets, indicating a static D2h crystal-field stabilized
Jahn-Teller distortion of the (C60)4- anions. The T1u(4) mode changes into the
known doublet above 250 K, a pattern which could have three origins: a dynamic
Jahn-Teller effect, static disorder between "staggered" anions, or a phase
transition from an orientationally-ordered phase to one where molecular motion
is significant.Comment: 4 pages, 2 figures submitted to Phys. Rev.
The Casimir Effect for Parallel Plates Revisited
The Casimir effect for a massless scalar field with Dirichlet and periodic
boundary conditions (b.c.) on infinite parallel plates is revisited in the
local quantum field theory (lqft) framework introduced by B.Kay. The model
displays a number of more realistic features than the ones he treated. In
addition to local observables, as the energy density, we propose to consider
intensive variables, such as the energy per unit area , as
fundamental observables. Adopting this view, lqft rejects Dirichlet (the same
result may be proved for Neumann or mixed) b.c., and accepts periodic b.c.: in
the former case diverges, in the latter it is finite, as is shown by
an expression for the local energy density obtained from lqft through the use
of the Poisson summation formula. Another way to see this uses methods from the
Euler summation formula: in the proof of regularization independence of the
energy per unit area, a regularization-dependent surface term arises upon use
of Dirichlet b.c. but not periodic b.c.. For the conformally invariant scalar
quantum field, this surface term is absent, due to the condition of zero trace
of the energy momentum tensor, as remarked by B.De Witt. The latter property
does not hold in tha application to the dark energy problem in Cosmology, in
which we argue that periodic b.c. might play a distinguished role.Comment: 25 pages, no figures, late
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