63 research outputs found
Assessing the operating temperature of multi-junction solar cells with novel rear side layer stack and local electrical contacts
Sub-bandgap sunlight provides a source of heat generation in solar cells that is detrimental to performance, especially in space applications where heat dissipation is limited. In this work we assess the impact that an advanced rear-side contact scheme for multi-junction solar cells has on the cell temperature. Our results show that this scheme reduces the optical power absorption below the bandgap of germanium by 81% compared to a standard, full metallization design. Measurements of the electrical and thermal power fluxes performed in vacuum demonstrate that this lower near-infrared light absorption results in 8% less heat dissipated in the cell with the novel rear-side contact scheme when operating at 25 ºC. Modelling of the operating temperature for both cells when fully encapsulated with glass indicates that this effect will also result in a reduction of the operating temperature of 9 ºC for the novel design
Systematic solar pvt testing in steady-state and dynamic outdoor conditions
In order to predict accurately the performance of solar-thermal
or hybrid PVT systems, it is necessary that the steady-state
and dynamic performance of the collectors is understood. This
work focuses on the testing and detailed characterization of nonconcentrating
PVT collectors based on the testing procedure
specified in the European standard EN 12975-2. Three different
types of PVT collectors were tested in Cyprus under outdoor
conditions similar to those specified in the standard. Amongst
other results, we show that that poor thermal contact between
the laminate and the copper absorber can lead to a significant
deterioration in thermal performance and that a glass cover improves
the thermal performance by reducing losses as expected,
but causes electrical losses that vary with the glass transmittance
and the incident angle. It is found that the reduction in electrical
efficiency at large solar incidence angles is more significant than
that due to elevated temperatures representative of water heating
applications. Dynamic tests are performed by imposing a
step change in incident irradiance in order to quantify the collector
time constant and effective heat capacity. A time constant of
8 min is found for a commercial PVT module, which compares
to <2 min for a flat plate solar collector. The PVT collector time
constant is found to be very sensitive to the thermal contact between
the PV layer and the absorber, which may vary according
to the quality of construction, and also to the operating flow rate.Papers presented at the 13th International Conference on Heat Transfer, Fluid Mechanics and Thermodynamics, Portoroz, Slovenia on 17-19 July 2017 .International centre for heat and mass transfer.American society of thermal and fluids engineers
Off-grid solar photovoltaic systems for rural electrification and emissions mitigation in India
Over one billion people lack access to electricity and many of them in rural areas far from existing infrastructure. Off-grid systems can provide an alternative to extending the grid network and using renewable energy, for example solar photovoltaics (PV) and battery storage, can mitigate greenhouse gas emissions from electricity that would otherwise come from fossil fuel sources. This paper presents a model capable of comparing several mature and emerging PV technologies for rural electrification with diesel generation and grid extension for locations in India in terms of both the levelised cost and lifecycle emissions intensity of electricity. The levelised cost of used electricity, ranging from $0.46–1.20/kWh, and greenhouse gas emissions are highly dependent on the PV technology chosen, with battery storage contributing significantly to both metrics. The conditions under which PV and storage becomes more favourable than grid extension are calculated and hybrid systems of PV, storage and diesel generation are evaluated. Analysis of expected price evolutions suggest that the most cost-effective hybrid systems will be dominated by PV generation around 2018
Improving the light-harvesting of amorphous silicon solar cells with photochemical upconversion
Single-threshold solar cells are fundamentally limited by their ability to
harvest only those photons above a certain energy. Harvesting below-threshold
photons and re-radiating this energy at a shorter wavelength would thus boost
the efficiency of such devices. We report an increase in light harvesting
efficiency of a hydrogenated amorphous silicon (a-Si:H) thin-film solar cell
due to a rear upconvertor based on sensitized triplet–triplet-annihilation in
organic molecules. Low energy light in the range 600–750 nm is converted to
550–600 nm light due to the incoherent photochemical process. A peak
efficiency enhancement of (1.0 ± 0.2)% at 720 nm is measured under irradiation
equivalent to (48 ± 3) suns (AM1.5). We discuss the pathways to be explored in
adapting photochemical UC for application in various single threshold devices
Improving the light-harvesting of second generation solar cells with photochemical upconversion
Photovoltaics (PV) offer a solution for the development of sustainable energy
sources, relying on the sheer abundance of sunlight: More sunlight falls on
the Earth’s surface in one hour than is required by its inhabitants in a year.
However, it is imperative to manage the wide distribution of photon energies
available in order to generate more cost efficient PV devices because single
threshold PV devices are fundamentally limited to a maximum conversion
efficiency, the Shockley-Queisser (SQ) limit. Recent progress has enabled the
production of c-Si cells with efficiencies as high as 25%,1 close to the
limiting efficiency of ∼30%. But these cells are rather expensive, and
ultimately the cost of energy is determined by the ratio of system cost and
efficiency of the PV device. A strategy to radically decrease this ratio is to
circumvent the SQ limit in cheaper, second generation PV devices. One
promising approach is the use of hydrogenated amorphous silicon (a-Si:H),
where film thicknesses on the order of several 100nm are sufficient.
Unfortunately, the optical threshold of a-Si:H is rather high (1.7-1.8 eV) and
the material suffers from light-induced degradation. Thinner absorber layers
in a-Si:H devices are generally more stable than thicker films due to the
better charge carrier extraction, but at the expense of reduced conversion
efficiencies, especially in the red part of the solar spectrum (absorption
losses). Hence for higher bandgap materials, which includes a-Si as well as
organic and dye-sensitized cells, the major loss mechanism is the inability to
harvest low energy photons
Effect of a back reflector
Photochemical upconversion is applied to a hydrogenated amorphous silicon
solar cell in the presence of a back-scattering layer. A custom-synthesized
porphyrin was utilized as the sensitizer species, with rubrene as the emitter.
Under a bias of 24 suns, a peak external quantum efficiency (EQE) enhancement
of ~2 % was observed at a wavelength of 720 nm. Without the scattering layer,
the EQE enhancement was half this value, indicating that the effect of the
back-scatterer is to double the efficacy of the upconverting device. The
results represent an upconversion figure of merit of 3.5 × 10–4 mA cm–2 sun–2,
which is the highest reported to date
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