5,573 research outputs found
Thermodynamic theory of epitaxial ferroelectric thin films with dense domain structures
A Landau-Ginsburg-Devonshire-type nonlinear phenomenological theory is
presented, which enables the thermodynamic description of dense laminar
polydomain states in epitaxial ferroelectric thin films. The theory explicitly
takes into account the mechanical substrate effect on the polarizations and
lattice strains in dissimilar elastic domains (twins). Numerical calculations
are performed for PbTiO3 and BaTiO3 films grown on (001)-oriented cubic
substrates. The "misfit strain-temperature" phase diagrams are developed for
these films, showing stability ranges of various possible polydomain and
single-domain states. Three types of polarization instabilities are revealed
for polydomain epitaxial ferroelectric films, which may lead to the formation
of new polydomain states forbidden in bulk crystals. The total dielectric and
piezoelectric small-signal responses of polydomain films are calculated,
resulting from both the volume and domain-wall contributions. For BaTiO3 films,
strong dielectric anomalies are predicted at room temperature near special
values of the misfit strain.Comment: 19 pages, 8 figure
Soft modes of collective domain-wall vibrations in epitaxial ferroelectric thin films
Mechanical restoring forces acting on ferroelastic domain walls displaced
from the equilibrium positions in epitaxial films are calculated for various
modes of their cooperative translational oscillations. For vibrations of the
domain-wall superlattice with the wave vectors corresponding to the center and
boundaries of the first Brillouin zone, the soft modes are singled out that are
distinguished by a minimum magnitude of the restoring force. It is shown that,
in polydomain ferroelectric thin films, the soft modes of wall vibrations may
create enormously large contribution to the film permittivity.Comment: 6 pages, 3 figure
Spin-density-wave transition of (TMTSF)PF at high magnetic fields
The transverse magnetoresistance of the Bechgaard salt (TMTSF)PF has
been measured for various pressures, with the field up to 24 T parallel to the
lowest conductivity direction c. A quadratic behavior is observed in
the magnetic field dependence of the spin-density-wave (SDW) transition
temperature . With increasing pressure,
decreases and the coefficient of the quadratic term increases. These results
are consistent with the prediction of the mean-field theory based on the
nesting of the quasi one-dimensional Fermi surface. Using a mean field theory,
for the perfect nesting case is estimated as about 16 K. This
means that even at ambient pressure where is 12 K, the SDW
phase of (TMTSF)PF is substantially suppressed by the
two-dimensionality of the system.Comment: 11pages,6figures(EPS), accepted for publication in PR
Analysis of hadronic transitions in Υ(3S) decays
This is the publisher's version, also available electronically from http://journals.aps.org/prd/abstract/10.1103/PhysRevD.49.40.Using the CLEO II detector, we have measured the branching fractions for Υ(3S)→ππΥ(1S), Υ(3S)→ππΥ(2S), and the cascade Υ(3S)→Υ(2S)+X, Υ(2S)→π+π−Υ(1S), analyzing the exclusive mode where the daughter Υ state decays to a e(+)e(−) or μ(+)μ(−) pair, as well as the inclusive π(+)π(−) transitions where the final Υ state decays into hadrons. Properties of the ππ system are analyzed. Searches for the cascade decay Υ(3S)→π+π−h(b), h(b)→γη(b) and Υ(3S)→π0h(b) were also performed
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A RISC-V Vector Processor With Simultaneous-Switching Switched-Capacitor DC-DC Converters in 28 nm FDSOI
This work demonstrates a RISC-V vector microprocessor implemented in 28 nm FDSOI with fully integrated simultaneous-switching switched-capacitor DC-DC (SC DC-DC) converters and adaptive clocking that generates four on-chip voltages between 0.45 and 1 V using only 1.0 V core and 1.8 V IO voltage inputs. The converters achieve high efficiency at the system level by switching simultaneously to avoid charge-sharing losses and by using an adaptive clock to maximize performance for the resulting voltage ripple. Details about the implementation of the DC-DC switches, DC-DC controller, and adaptive clock are provided, and the sources of conversion loss are analyzed based on measured results. This system pushes the capabilities of dynamic voltage scaling by enabling fast transitions (20 ns), simple packaging (no off-chip passives), low area overhead (16%), high conversion efficiency (80%-86%), and high energy efficiency (26.2 DP GFLOPS/W) for mobile devices
Higher-order Galilean-invariant lattice Boltzmann model for microflows: Single-component gas
We introduce a scheme which gives rise to additional degree of freedom for the same number of discrete velocities in the context of the lattice Boltzmann model. We show that an off-lattice D3Q27 model exists with correct equilibrium to recover Galilean-invariant form of Navier-Stokes equation (without any cubic error). In the first part of this work, we show that the present model can capture two important features of the microflow in a single component gas: Knudsen boundary layer and Knudsen Paradox. Finally, we present numerical results corresponding to Couette flow for two representative Knudsen numbers. We show that the off-lattice D3Q27 model exhibits better accuracy as compared to more widely used on-lattice D3Q19 or D3Q27 model. Finally, our construction of discrete velocity model shows that there is no contradiction between entropic construction and quadrature-based procedure for the construction of the lattice Boltzmann model.open252
Detecting early myocardial ischemia in rat heart by MALDI imaging mass spectrometry.
Diagnostics of myocardial infarction in human post-mortem hearts can be achieved only if ischemia persisted for at least 6-12 h when certain morphological changes appear in myocardium. The initial 4 h of ischemia is difficult to diagnose due to lack of a standardized method. Developing a panel of molecular tissue markers is a promising approach and can be accelerated by characterization of molecular changes. This study is the first untargeted metabolomic profiling of ischemic myocardium during the initial 4 h directly from tissue section. Ischemic hearts from an ex-vivo Langendorff model were analysed using matrix assisted laser desorption/ionization imaging mass spectrometry (MALDI IMS) at 15 min, 30 min, 1 h, 2 h, and 4 h. Region-specific molecular changes were identified even in absence of evident histological lesions and were segregated by unsupervised cluster analysis. Significantly differentially expressed features were detected by multivariate analysis starting at 15 min while their number increased with prolonged ischemia. The biggest significant increase at 15 min was observed for m/z 682.1294 (likely corresponding to S-NADHX-a damage product of nicotinamide adenine dinucleotide (NADH)). Based on the previously reported role of NAD <sup>+</sup> /NADH ratio in regulating localization of the sodium channel (Na <sub>v</sub> 1.5) at the plasma membrane, Na <sub>v</sub> 1.5 was evaluated by immunofluorescence. As expected, a fainter signal was observed at the plasma membrane in the predicted ischemic region starting 30 min of ischemia and the change became the most pronounced by 4 h. Metabolomic changes occur early during ischemia, can assist in identifying markers for post-mortem diagnostics and improve understanding of molecular mechanisms
Spatiotemporal correlations of handset-based service usages
We study spatiotemporal correlations and temporal diversities of
handset-based service usages by analyzing a dataset that includes detailed
information about locations and service usages of 124 users over 16 months. By
constructing the spatiotemporal trajectories of the users we detect several
meaningful places or contexts for each one of them and show how the context
affects the service usage patterns. We find that temporal patterns of service
usages are bound to the typical weekly cycles of humans, yet they show maximal
activities at different times. We first discuss their temporal correlations and
then investigate the time-ordering behavior of communication services like
calls being followed by the non-communication services like applications. We
also find that the behavioral overlap network based on the clustering of
temporal patterns is comparable to the communication network of users. Our
approach provides a useful framework for handset-based data analysis and helps
us to understand the complexities of information and communications technology
enabled human behavior.Comment: 11 pages, 15 figure
Two-Dimensional Electronic Spectroscopy of Chlorophyll a: Solvent Dependent Spectral Evolution
The interaction of the monomeric chlorophyll Q-band electronic transition with solvents of differing physical-chemical properties is investigated through two-dimensional electronic spectroscopy (2DES). Chlorophyll constitutes the key chromophore molecule in light harvesting complexes. It is well-known that the surrounding protein in the light harvesting complex fine-tunes chlorophyll electronic transitions to optimize energy transfer. Therefore, an understanding of the influence of the environment on the monomeric chlorophyll electronic transitions is important. The Q-band 2DES is inhomogeneous at early times, particularly in hydrogen bonding polar solvents, but also in nonpolar solvents like cyclohexane. Interestingly this inhomogeneity persists for long times, even up to the nanosecond time scale in some solvents. The reshaping of the 2DES occurs over multiple time scales and was assigned mainly to spectral diffusion. At early times the reshaping is Gaussian-like, hinting at a strong solvent reorganization effect. The temporal evolution of the 2DES response was analyzed in terms of a Brownian oscillator model. The spectral densities underpinning the Brownian oscillator fitting were recovered for the different solvents. The absorption spectra and Stokes shift were also properly described by this model. The extent and nature of inhomogeneous broadening was a strong function of solvent, being larger in H-bonding and viscous media and smaller in nonpolar solvents. The fastest spectral reshaping components were assigned to solvent dynamics, modified by interactions with the solute
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