Suppressed Coherence due to Orbital Correlations in the Ferromagnetically Ordered Metallic Phase of Mn Compounds

Small Drude weight $D$ together with small specific heat coefficient $\gamma$ observed in the ferromagnetic phase of R$_{1-x}$A$_x$MnO$_3$ (R=La, Pr, Nd, Sm; A=Ca, Sr, Ba) are analyzed in terms of a proximity effect of the Mott insulator. The scaling theory for the metal-insulator transition with the critical enhancement of orbital correlations toward the staggered ordering of two $e_g$ orbitals such as $3x^2-r^2$ and $3y^2-r^2$ symmetries may lead to the critical exponents of $D \propto \delta^{u}$ and $\gamma \propto \delta^v$ with $u=3/2$ and $v=0$. The result agrees with the experimental indications.Comment: 4 pages LaTeX using jpsj.sty. To appear in J. Phys. Soc. Jpn. 67(1998)No.

Dynamic Kerr Effect and Spectral Weight Transfer in the Manganites

We perform pump-probe Kerr spectroscopy in the colossally magnetoresistive manganite Pr0.67Ca0.33MnO3. Kerr effects uncover surface magnetic dynamics undetected by established methods based on reflectivity and optical spectral weight transfer. Our findings indicate the connection between spin and charge dynamics in the manganites may be weaker than previously thought. Additionally, important differences between this system and conventional ferromagnetic metals manifest as long-lived, magneto-optical coupling transients, which may be generic to all manganites.Comment: 12 text pages, 4 figure

Magnetic Field resulting from non-linear electrical transport in single crystals of charge-ordered Pr0.63_{0.63} Ca0.37_{0.37} MnO3_{3}}

In this letter we report that the current induced destabilization of the charge ordered (CO) state in a rare-earth manganite gives rise to regions with ferromagnetic correlation. We did this experiment by measurement of the I-V curves in single crystal of the CO system Pr$_{0.63}$Ca$_{0.37}$MnO$_{3}$ and simultanously measuring the magnetization of the current carrying conductor using a high T$_c$ SQUID working at T = 77K. We have found that the current induced destabilization of the CO state leads to a regime of negative differential resistance which leads to a small enhancement of the magnetization of the sample, indicating ferromagnetically aligned moments.Comment: 4 pages LateX, 4 eps figure

Spin Excitation Spectrum of La1−xAx_{1-x}A_xMnO3_3

As an effective model to describe perovskite-type manganates (La,$A$)MnO$_3$, the double-exchange model on a cubic lattice is investigated. Spin excitation spectrum of the model in the ground state is studied using the spin wave approximation. Spin wave dispersion relation observed in the inelastic neutron scattering experiment of La$_{0.7}$Pb$_{0.3}$MnO$_3$ is reproduced. Effective values for the electron bandwidth as well as Hund's coupling is estimated from the data.Comment: 10 pages LaTeX including 4 PS figure

Static and Dynamical Properties of the Ferromagnetic Kondo Model with Direct Antiferromagnetic Coupling Between the localized t2gt_{2g} Electrons

The phase diagram of the Kondo lattice Hamiltonian with ferromagnetic Hund's coupling in the limit where the spin of the localized $t_{2g}$ electrons is classical is analyzed in one dimension as a function of temperature, electronic density, and a direct antiferromagnetic coupling $J'$ between the localized spins. Studying static and dynamical properties, a behavior that qualitatively resembles experimental results for manganites occurs for $J'$ smaller than 0.11 in units of the $e_g$ hopping amplitude. In particular a coexistence of ferromagnetic and antiferromagnetic excitations is observed at low-hole density in agreement with neutron scattering experiments on $\rm{La_{2-2x}Sr_{1+2x}Mn_2O_7}$ with$x=0.4$. This effect is caused by the recently reported tendency to phase separation between hole-rich ferromagnetic and hole-undoped antiferromagnetic domains in electronic models for manganites. As $J'$ increases metal-insulator transitions are detected by monitoring the optical conductivity and the density of states. The magnetic correlations reveal the existence of spiral phases without long-range order but with fairly large correlation lengths. Indications of charge ordering effects appear in the analysis of charge correlations.Comment: 14 pages with 25 eps figures embeded in the tex

Oxygen isotope effect and phase separation in the optical conductivity of (La0.5_{0.5}Pr0.5_{0.5})0.7_{0.7}Ca0.3_{0.3}MnO3_3 thin films

The optical conductivities of films of (La$_{0.5}$Pr$_{0.5}$)$_{0.7}$Ca$_{0.3}$MnO$_3$ with different oxygen isotopes ($^{16}$O and $^{18}$O) have been determined in the spectral range from 0.3 to 4.3 eV using a combination of transmission in the mid-infrared and ellipsometry from the near-infrared to ultra-violet regions. We have found that the isotope exchange strongly affects the optical response in the ferromagnetic phase in a broad frequency range, in contrast to the almost isotope-independent optical conductivity above $T_C$. The substitution by $^{18}$O strongly suppresses the Drude response and a mid-infrared peak while enhancing the conductivity peak at 1.5 eV. A qualitative explanation can be given in terms of the phase separation present in these materials. Moreover, the optical response is similar to the one extracted from measurements in polished samples and other thin films, which signals to the importance of internal strain.Comment: 11 pages, 11 figures, to appear in PR

Incoherent Charge Dynamics in Perovskite Manganese Oxides

A minimal model is proposed for the perovskite manganese oxides showing the strongly incoherent charge dynamics with a suppressed Drude weight in the ferromagnetic and metallic phase near the insulator. We investigate a generalized double-exchange model including three elements; the orbital degeneracy of $e_g$ conduction bands, the Coulomb interaction and fluctuating Jahn-Teller distortions. We demonstrate that Lancz$\ddot{\rm o}$s diagonalization calculations combined with Monte Carlo sampling of the largely fluctuating lattice distortions result in the optical conductivity which quantitatively accounts for the experimental indications. It is found that all the three elements are indispensable to understand the charge dynamics in these compounds.Comment: 4 pages with 1 page of figures. To appear in J. Phys. Soc. Jp

Effects of Orbital Degeneracy and Electron Correlation on Charge Dynamics in Perovskite Manganese Oxides

Taking the orbital degeneracy of $e_g$ conduction bands and the Coulomb interaction into account in a double-exchange model, we investigate charge dynamics of perovskite Mn oxides by the Lancz$\ddot{\rm o}$s diagonalization method. In the metallic phase near the Mott insulator, it is found that the optical conductivity for a spin-polarized two-dimensional system exhibits a weight transfer to a broad and incoherent structure within the lower-Hubbard band together with a suppressed Drude weight. It reproduces qualitative feature of the experimental results. As an orbital effect, we find that an anomalous charge correlation at quarter filling suppresses the coherent charge dynamics and signals precursor to the charge ordering.Comment: 4 pages LaTeX including 3 PS figures, to appear in J. Phys. Soc. Jp

Spin-polarized tunneling of La0.67Sr0.33MnO3/YBa2Cu3O7-d junctions

The transport properties between ferromagnets and high-Tc superconductors are investigated in La0.67Sr0.33MnO3/YBa2Cu3O7-d (LSMO/YBCO)junctions in the geometry of cross-strip lines. The conductance spectra show zero-bias conductance peaks (ZBCP), reflecting the charge transport in the ab-plane. When an external magnetic field is applied to the junctions, the conductance spectra show two notable features, i.e., an increase of background conductance and an asymmetric ZBCP splitting whose amplitude responds nonlinearly to the applied field. It is shown that the magnetic field response are consistent with a theoretical prediction of tunneling spectroscopy when the presence of a ferromagnetic barrier between a spin-polarized ferromagnet and a d-wave superconductor is assumed.Comment: 10 Pages, 7 EPS figures, Submitted to Phys. Rev.

Optical spectral weights and the ferromagnetic transition temperature of CMR manganites: relevance of double-exchange to real materials

We present a thorough and quantitative comparison of double-exchange models to experimental data on the colossal magnetoresistance manganese perovskites. Our results settle a controversy by showing that physics beyond double-exchange is important even in La$_{0.7}$Sr$_{0.3}$MnO$_3$, which has been regarded as a conventional double-exchange system. We show that the crucial quantity for comparisons of different calculations to each other and to data is the conduction band kinetic energy $K$, which is insensitive to the details of the band structure and can be experimentally determined from optical conductivity measurements. The seemingly complicated dependence of $T_c$ on the Hund's coupling $J$ and carrier concentration $n$ is shown to reflect the variation of $K$ with $J$, $n$ and temperature. We present results for the optical conductivity which allow interpretation of experiments and show that a feature previously interpreted in terms of the Hund's coupling was misidentified. We also correct minor errors in the phase diagram presented in previous work.Comment: 13 pages, 7 eps figure