Getting simultaneous red and near infrared bands from a single digital camera for plant monitoring applications

International audienceLes images multispectrales incluant une bande rouge et une bande infrarouge ont prouvé leur efficacité pour la discrimination entre sol et végétation et le suivi cultural en télédétection. Mais elles restent rarement utilisées pour l'imagerie au sol ou par drone, du fait de la non disponibilité de capteurs adaptés. Nous proposons ici une solution originale pour obtenir simultanément les bandes rouge et infrarouge à partir d'un appareil photographique couleur ordinaire, après avoir retiré le filtre interne bloquant l'infrarouge. Nous décrivons d'abord l'approche théorique, ainsi que des résultats simulés sur un jeu de données spectrales, pour deux types d'appareils. Des exemples d'acquisition sur le terrain en conditions réelles sont ensuite présentés, et comparés à une acquisition couleur standard pour la discrimination sol/plantes. Dans la plupart des cas notre approche apporte une amélioration significative, ouvrant de nouvelles opportunités pour les applications de suivi de culture. / Multispectral images including red and near-infrared bands have proved their efficiency for vegetation-soil discrimination and agricultural monitoring in remote sensing applications. But they remain rarely used in ground and UAV imagery, due to a limited availability of adequate 2D imaging devices. In this paper, we propose and evaluate an original solution to obtain simultaneously the near-infrared and red bands from a standard RGB camera, after having removed the near-infrared blocking filter inside. First, the theoretical approach is described, as well as simulated results on a set of soil and vegetation luminance spectra with two different still cameras (Canon 500D and Sigma SD14). Then examples of images obtained in real field conditions are given, and compared with standard colour image acquisition for pixel-based plant/soil discrimination, using an automatic thresholding method. It appears that in most cases our new acquisition procedure brings a significative improvement, opening new opportunities for crop monitoring applications

The evolution of the specific star formation rate of massive galaxies to z ~ 1.8 in the E-CDFS

We study the evolution of the star formation rate (SFR) of mid-infrared (IR) selected galaxies in the extended Chandra Deep Field South (E-CDFS). We use a combination of U-K GaBoDS and MUSYC data, deep IRAC observations from SIMPLE, and deep MIPS data from FIDEL. This unique multi-wavelength data set allows us to investigate the SFR history of massive galaxies out to redshift z ~ 1.8. We determine star formation rates using both the rest-frame ultraviolet luminosity from young, hot stars and the total IR luminosity of obscured star formation obtained from the MIPS 24 um flux. We find that at all redshifts the galaxies with higher masses have substantially lower specific star formation rates than lower mass galaxies. The average specific star formation rates increase with redshift, and the rate of incline is similar for all galaxies (roughly (1+z)^{n}, n = 5.0 +/- 0.4). It does not seem to be a strong function of galaxy mass. Using a subsample of galaxies with masses M_*> 10^11 M_sun, we measured the fraction of galaxies whose star formation is quenched. We consider a galaxy to be in quiescent mode when its specific star formation rate does not exceed 1/(3 x t_H), where t_H is the Hubble time. The fraction of quiescent galaxies defined as such decreases with redshift out to z ~ 1.8. We find that, at that redshift, 19 +/-9 % of the M_* > 10^11 M_sun sources would be considered quiescent according to our criterion.Comment: 7 pages, 6 figures, accepted for publication in Ap

Theoretical Model for the Semimetal Yb_4As_3

We present a model which can explain semiquantitatively a number of the unusual properties of \mbox{Yb$_4$As$_3$}. The structural phase transition at T_{\text{c}}\simeq300\,\mbox{K} is described by a band Jahn-Teller effect of correlated electrons and is interpreted as a charge ordering of the Yb ions. The low carrier concentration in the low-temperature phase follows from the strong electron correlations of the 4f-holes on the Yb sites and can be viewed as self-doping of charge-ordered chains. The observed heavy-fermion behaviour is on a scale of T^\ast\simeq50\,\mbox{K} and is due to spinon-like excitations in the Yb$^{3+}$-chains. The appearance of a second low-energy scale around 0.2\,K is due to the Fermi energy of the low-density carriers.Comment: 7 pages, REVTeX, 1 Postscript-figure separatel

Scalable and Tunable Carbide-Phosphide Composite Catalyst System for the Thermochemical Conversion of Biomass

© 2017 American Chemical Society. We have prepared composite materials of hexagonal nickel phosphide and molybdenum carbide (Mo2C) utilizing a simple and scalable two-stage synthesis method composed of carbothermic reduction followed by hydrothermal incubation. We observe the monophasic hexagonal phosphide Ni2P in the composite at low phosphide-to-carbide (P:C) ratios. Upon an increase in the proportion of P:C, the carbide surface becomes saturated, and we detect the emergence of a second hexagonal nickel phosphide phase (Ni5P4) upon annealing. We demonstrate that vapor-phase upgrading (VPU) of whole biomass via catalytic fast pyrolysis is achievable using the composite material as a catalyst, and we monitor the resulting product slates using pyrolysis-gas chromatography/mass spectrometry. Our analysis of the product vapors indicates that variation of the P:C molar ratio in the composite material affords product slates of varying complexity and composition, which is indicated by the number of products and their relative proportions in the product slate. Our results demonstrate that targeted vapor product composition can be obtained, which can potentially be utilized for tuning of the composition of the bio-oil downstream

Environmentally Friendly Process for Recovery of Wood Preservative from Used Copper Naphthenate-Treated Railroad Ties

© 2017 American Chemical Society. Removal of copper naphthenate (CN) from used wooden railroad ties was investigated to improve the commercial viability of this biomass as a fuel source and avoid alternative disposal methods such as landfilling. Bench-scale thermal desorption of organic preservative components from CN-impregnated ties was followed by extraction of the copper fraction with ethylenediaminetetraacetic acid, 1-hydroxy ethylidene-1,1-diphosphonic acid, or 2,6-pyridine dicarboxylic acid (PDA). Naphthenic acid (NA) and carrier oil were recovered at desorption temperatures between 225 and 300 °C and could potentially be recycled to treat new ties. The thermal treatment also mimicked torrefaction, improving the biomass properties for use as a thermochemical conversion feedstock. Chelation with PDA, a biodegradable chelating agent, after desorption had the highest extraction efficiency of copper and other naturally present inorganics, extracting 100% of the copper from both the raw and 225 °C-treated samples. Optimized desorbed material showed a 64% decrease in ash content when extracted with PDA; however, extraction efficiency decreased as desorption temperature increased, indicating that thermal treatment caused the inorganics to be less extractable. We concluded that the optimum desorption conditions were between 250 and 275 °C for 45 min followed by extraction with PDA when considering both NA removal and inorganic extraction efficiency

Mean Hα+[N ii]+[S ii] EW inferred for star-forming galaxies at z ∼ 5.1–5.4 using high-quality Spitzer /IRAC photometry

Recent Spitzer/InfraRed Array Camera (IRAC) photometric observations have revealed that rest-frame optical emission lines contribute significantly to the broad-band fluxes of high-redshift galaxies. Specifically, in the narrow redshift range z ∼ 5.1–5.4 the [3.6]–[4.5] colour is expected to be very red, due to contamination of the 4.5 μm band by the dominant Hα line, while the 3.6 μm filter is free of nebular emission lines. We take advantage of new reductions of deep Spitzer/IRAC imaging over the Great Observatories Origins Deep Survey-North+South fields (Labbé et al. 2015) to obtain a clean measurement of the mean Hα equivalent width (EW) from the [3.6]–[4.5] colour in the redshift range z = 5.1–5.4. The selected sources either have measured spectroscopic redshifts (13 sources) or lie very confidently in the redshift range z = 5.1–5.4 based on the photometric redshift likelihood intervals (11 sources). Our zphot = 5.1–5.4 sample and zspec = 5.10–5.40 spectroscopic sample have a mean [3.6]–[4.5] colour of 0.31 ± 0.05 and 0.35 ± 0.07 mag, implying a rest-frame EW (Hα+[N II]+[S II]) of 665 ± 53 and 707 ± 74 Å, respectively, for sources in these samples. These values are consistent albeit slightly higher than derived by Stark et al. at z ∼ 4, suggesting an evolution to higher values of the Hα+[N II]+[S II] EW at z > 2. Using the 3.6 μm band, which is free of emission line contamination, we perform robust spectral energy distribution fitting and find a median specific star formation rate of sSFR = 17+2−517−5+2 Gyr−1, 7+1−2×7−2+1× higher than at z ∼ 2. We find no strong correlation (<2σ) between the Hα+[N II]+[S II] EW and the stellar mass of sources. Before the advent of JWST, improvements in these results will come through an expansion of current spectroscopic samples and deeper Spitzer/IRAC measurements

Fluctuations of energy flux in a simple dissipative out-of-equilibrium system

We report the statistical properties of the fluctuations of the energy flux in an electronic RC circuit driven with a stochastic voltage. The fluctuations of the power injected in the circuit are measured as a function of the damping rate and the forcing parameters. We show that its distribution exhibits a cusp close to zero and two asymmetric exponential tails, the asymmetry being driven by the mean dissipation. This simple experiment allows to capture the qualitative features of the energy flux distribution observed in more complex dissipative systems. We also show that the large fluctuations of injected power averaged on a time lag do not verify the Fluctuation Theorem even for long averaging time. This is in contrast with the findings of previous experiments due to their small range of explored fluctuation amplitude. The injected power in a system of N components either correlated or not is also studied to mimic systems with large number of particles, such as in a dilute granular gas.Comment: to be published in Phys. Rev.

Catalytic transfer hydrogenolysis of organosolv lignin using B-containing FeNi alloyed catalysts

© 2017 Elsevier B.V. In this work, FeB, NiB, and FeNiB nanomaterials were examined as catalysts for catalytic transfer hydrogenolysis (CTH) using supercritical ethanol (sc-EtOH) as the hydrogen donor and reaction solvent. The earth-abundant alloys were synthesized using simple aqueous chemical reductions and characterized using ICP-OES, XRD, and STEM-EDS. Using acetophenone to model the desired catalytic reactivity, FeNiB was identified as having superior reactivity (74% conversion) and selectivity for complete deoxygenation to ethylbenzene (84%) when compared to the monometallic materials. Given its high reactivity and selectivity for deoxygenation over ring saturation, FeNiB was screened as a lignin valorization catalyst. FeNiB mediates deoxygenation of aliphatic hydroxyl and carbonyls in organosolv lignin via CTH in sc-EtOH. A combination of gel permeation chromatography, GC/MS, and NMR spectroscopy was used to demonstrate the production of a slate of monomeric phenols with intact deoxygenated aliphatic side chains. In total, these results highlight the utility of CTH for the valorization of biorefinery-relevant lignin using an inexpensive, earth-abundant catalyst material and a green solvent system that can be directly derived from the polysaccharide fraction of lignocellulosic biomass

Vapor-Phase Stabilization of Biomass Pyrolysis Vapors Using Mixed-Metal Oxide Catalysts

© 2019 American Chemical Society. Mixed-metal oxides possess a wide range of tunability and show promise for catalytic stabilization of biomass pyrolysis products. For materials derived from layered double hydroxides, understanding the effect of divalent cation species and divalent/trivalent cation stoichiometric ratio on catalytic behavior is critical to their successful implementation. In this study, four mixed-metal oxide catalysts consisting of Al, Zn, and Mg in different stoichiometric ratios were synthesized and tested for ex-situ catalytic fast pyrolysis (CFP) using pine wood as feedstock. The catalytic activity and deactivation behavior of these catalysts were monitored in real-time using a lab-scale pyrolysis reactor and fixed catalyst bed coupled with a molecular beam mass spectrometer (MBMS), and data were analyzed by multivariate statistical approaches. In the comparison between Mg-Al and Zn-Al catalyst materials, we demonstrated that the Mg-Al materials possessed greater quantities of basic sites, which we attributed to their higher surface areas, and they produced upgraded pyrolysis vapors which contained less acids and more deoxygenated aromatic hydrocarbons such as toluene and xylene. However, detrimental impacts on carbon yields were realized via decarbonylation and decarboxylation reactions and coke formation. Given that the primary goals of catalytic upgrading of bio-oil are deoxygenation, reduction of acidity, and high carbon yield, these results highlight both promising catalytic effects of mixed-metal oxide materials and opportunities for improvement