249 research outputs found
Propagation of Surface Plasmons in Ordered and Disordered Chains of Metal Nanospheres
We report a numerical investigation of surface plasmon (SP) propagation in
ordered and disordered linear chains of metal nanospheres. In our simulations,
SPs are excited at one end of a chain by a near-field tip. We then find
numerically the SP amplitude as a function of propagation distance. Two types
of SPs are discovered. The first SP, which we call the ordinary or quasistatic,
is mediated by short-range, near-field electromagnetic interaction in the
chain. This excitation is strongly affected by Ohmic losses in the metal and by
disorder in the chain. These two effects result in spatial decay of the
quasistatic SP by means of absorptive and radiative losses, respectively. The
second SP is mediated by longer range, far-field interaction of nanospheres. We
refer to this SP as the extraordinary or non-quasistatic. The non-quasistatic
SP can not be effectively excited by a near-field probe due to the small
integral weight of the associated spectral line. Because of that, at small
propagation distances, this SP is dominated by the quasistatic SP. However, the
non-quasistatic SP is affected by Ohmic and radiative losses to a much smaller
extent than the quasistatic one. Because of that, the non-quasistatic SP
becomes dominant sufficiently far from the exciting tip and can propagate with
little further losses of energy to remarkable distances. The unique physical
properties of the non-quasistatic SP can be utilized in all-optical integrated
photonic systems
Fluorescence technique for comparative studies of substrate-binding subsites in serine proteinases. Application to subtilisins
Occurence of common dolphins (Delphinus delphis) in the Gulf of Trieste and the northern Adriatic Sea
1. The Mediterranean common dolphin (Delphinus delphis), considered to have been very common in the past, had undergone a dramatic decline across most of the basin by the end of 1970s. In the northern Adriatic Sea, one of the regions with most available historical information, the common dolphin is thought to have been the most common and abundant cetacean throughout most of the 20th century. However, by the end of 1970s, it had virtually disappeared from the region and is now considered generally absent from the entire Adriatic Sea. 2. This contribution summarizes the occurrence of common dolphins in the Gulf of Trieste and provides a brief review of published records in other parts of the Adriatic Sea. 3. Systematic boat surveys in the wider area of the Gulf of Trieste between 2002 and 2019 confirmed that the common bottlenose dolphin (Tursiops truncatus) is the only regularly occurring cetacean species in this area. Despite this, several records of common dolphins were documented in the Gulf of Trieste between 2009 and 2012, through sightings of live animals or recovery of dead stranded animals. 4. Dorsal fin markings allowed the photo‐identification of some of these, suggesting that at least four different live individuals (three adults and one calf) occurred here in recent times. Most cases involved single adult individuals, but one included a mother‐calf pair that was temporarily resident in a port for several months, a behaviour atypical for this species. Photo‐identification showed that the presumed mother had previously been sighted in the Ionian Sea in Greece, over 1,000 km from the Gulf of Trieste, making this the longest documented movement for this species worldwide. 5. At present, the common dolphin continues to be rare in the region.Publisher PDFPeer reviewe
Transformation bending device emulated by graded-index waveguide
We demonstrate that a transformation device can be emulated using a
gradient-index waveguide. The effective index of the waveguide is spatially
varied by tailoring a gradient thickness dielectric waveguide. Based on this
technology, we demonstrate a transformation device guiding visible light around
a sharp corner, with low scattering loss and reflection loss. The experimental
results are in good agreement with the numerical results.Comment: This paper is published at Optics Express 20, 13006 (2012
Diamine Catalyzed Addition of ZnEt2 to PhC(O)CF3: Two Mechanisms and Autocatalytic Asymmetric Enhancement
Producción CientíficaNMR studies of the catalytic addition reaction of ZnEt2 to PhC(O)CF3 in the presence of three very efficient catalysts [TMEDA, tBuBOX, and L; where L is a chiral diamine synthesized from optically pure (R,R)-1,2-diphenylethylenediamine and (S)-2,2'-bis-(bromomethyl)-1,1'-binaphthalene] reveal large differences in their behavior. For the ligands TMEDA and tBuBOX, the catalysis shows no unusual features and proceeds via [(N?N)Zn(Et){OC(CF3 )(Et)Ph}]. For N?N?L, the observation of autocatalytic asymmetric enhancement during the catalysis, and unusual inverse concentration dependence on the reaction rate, indicate the participation of an additional novel catalytic cycle that goes through a dinuclear intermediate containing one ZnEt2 and one ZnEt fragment connected by N?N and OR bridges. Interestingly, the (19) F NMR signals of the main product of the reaction ([Zn(Et){OC*(CF3 )(Et)Ph}]2 ) allowed us to assess the enantioselectivity of the processes in situ without the assistance of chiral chromatography.Ministerio de Economía, Industria y Competitividad (CTQ2013-48406-P)Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. GR169 and VA256U13
Intramolecular distances between tryptophan residues and the active-site serine residue in alkaline bacterial proteinases as measured by fluorescence energy-transfer studies
Branch Rings, Thinned Rings, Tree Enveloping Rings
We develop the theory of ``branch algebras'', which are infinite-dimensional
associative algebras that are isomorphic, up to taking subrings of finite
codimension, to a matrix ring over themselves. The main examples come from
groups acting on trees.
In particular, for every field k we construct a k-algebra K which (1) is
finitely generated and infinite-dimensional, but has only finite-dimensional
quotients;
(2) has a subalgebra of finite codimension, isomorphic to ;
(3) is prime;
(4) has quadratic growth, and therefore Gelfand-Kirillov dimension 2;
(5) is recursively presented;
(6) satisfies no identity;
(7) contains a transcendental, invertible element;
(8) is semiprimitive if k has characteristic ;
(9) is graded if k has characteristic 2;
(10) is primitive if k is a non-algebraic extension of GF(2);
(11) is graded nil and Jacobson radical if k is an algebraic extension of
GF(2).Comment: 35 pages; small changes wrt previous versio
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