Predicción de la frescura del aceite de oliva virgen extra durante el almacenamiento mediante espectroscopía de fluorescencia

Virgin olive oil quality relates to flavor and unique health benefits. Some of these properties are at the most desirable level when the oil is just extracted, since it is not a product that improves with age. On the contrary, the concentrations of many compounds change during its shelf-life. These changes reveal the aging of the oil but do not necessarily mean decay in sensory properties, so in some cases an aged oil from healthy olives may be better qualified than a fresh one from olives affected by fermentation. The aim of this work is to analyze different methodologies proposed for assessing the quality of virgin olive oil with implications in freshness and aging of the oil, and to highlight the possibilities of rapid spectrofluorimetric techniques for assessing oil freshness by checking the evolution of pigments during storage. The observed change in the selected spectral features and mathematical modelling over time was compared with the accepted model for predicting the amount of pyropheophytin a, which is based on isokinetic studies. The best regression was obtained for 655 nm (adjustedR2 = 0.91) wavelength, which matches the distinctive band of pigments. The two mathematical models described in this study highlight the usefulness of pigments in the prediction of the shelf-life of extra virgin olive oil.La calidad del aceite de oliva virgen está relacionada con su flavor y sus beneficios únicos para la salud. Algunas de estas propiedades se encuentran en el nivel más deseable cuando el aceite está recién extraído, ya que no es un producto que mejore con el tiempo. Por el contrario, las concentraciones de muchos compuestos cambian a lo largo de la vida útil. Estos cambios revelan el envejecimiento del aceite, pero no implican necesariamente la alteración de las propiedades sensoriales, por lo que en algunos casos un aceite envejecido procedente de aceitunas sanas puede presentar mejor calidad que uno fresco procedente de aceitunas afectadas por procesos de fermentación. El objetivo de este trabajo es estudiar diferentes metodologías propuestas para evaluar la calidad del aceite de oliva virgen con implicaciones en la frescura y el envejecimiento del aceite, destacando las posibilidades de las rápidas técnicas espectrofluorométricas para evaluar la frescura del aceite verificando la evolución de los pigmentos durante el almacenamiento. El cambio observado en las características espectrales seleccionadas y su modelado matemático a lo largo del tiempo se comparó con el modelo aceptado para predecir la cantidad de pirofeofitina a, que se basa en estudios isocinéticos. Los dos modelos matemáticos descritos en este estudio pusieron de manifiesto la utilidad de los pigmentos en la predicción de la vida útil del aceite de oliva virgen extra. La mejor regresión se obtuvo para 655 nm (R2 -ajustado = 0,91), longitud de onda que coincide con la banda distintiva de pigmentos.Secretaría de Estado de Investigación, Desarrollo e Innovación de España-AGL2015-69320-

Predicción de la frescura del aceite de oliva virgen extra durante el almacenamiento mediante espectroscopía de fluorescencia

Virgin olive oil quality relates to flavor and unique health benefits. Some of these properties are at the most desirable level when the oil is just extracted, since it is not a product that improves with age. On the contrary, the concentrations of many compounds change during its shelf-life. These changes reveal the aging of the oil but do not necessarily mean decay in sensory properties, so in some cases an aged oil from healthy olives may be better qualified than a fresh one from olives affected by fermentation. The aim of this work is to analyze different methodologies proposed for assessing the quality of virgin olive oil with implications in freshness and aging of the oil, and to highlight the possibilities of rapid spectrofluorimetric techniques for assessing oil freshness by checking the evolution of pigments during storage. The observed change in the selected spectral features and mathematical modelling over time was compared with the accepted model for predicting the amount of pyropheophytin a, which is based on isokinetic studies. The best regression was obtained for 655 nm (adjustedR2 = 0.91) wavelength, which matches the distinctive band of pigments. The two mathematical models described in this study highlight the usefulness of pigments in the prediction of the shelf-life of extra virgin olive oil.La calidad del aceite de oliva virgen está relacionada con su flavor y sus beneficios únicos para la salud. Algunas de estas propiedades se encuentran en el nivel más deseable cuando el aceite está recién extraído, ya que no es un producto que mejore con el tiempo. Por el contrario, las concentraciones de muchos compuestos cambian a lo largo de la vida útil. Estos cambios revelan el envejecimiento del aceite, pero no implican necesariamente la alteración de las propiedades sensoriales, por lo que en algunos casos un aceite envejecido procedente de aceitunas sanas puede presentar mejor calidad que uno fresco procedente de aceitunas afectadas por procesos de fermentación. El objetivo de este trabajo es estudiar diferentes metodologías propuestas para evaluar la calidad del aceite de oliva virgen con implicaciones en la frescura y el envejecimiento del aceite, destacando las posibilidades de las rápidas técnicas espectrofluorométricas para evaluar la frescura del aceite verificando la evolución de los pigmentos durante el almacenamiento. El cambio observado en las características espectrales seleccionadas y su modelado matemático a lo largo del tiempo se comparó con el modelo aceptado para predecir la cantidad de pirofeofitina a, que se basa en estudios isocinéticos. Los dos modelos matemáticos descritos en este estudio pusieron de manifiesto la utilidad de los pigmentos en la predicción de la vida útil del aceite de oliva virgen extra. La mejor regresión se obtuvo para 655 nm (R2 -ajustado = 0,91), longitud de onda que coincide con la banda distintiva de pigmentos.Secretaría de Estado de Investigación, Desarrollo e Innovación de España-AGL2015-69320-

Virtual Processes and Superradiance in Spin-Boson Models

We consider spin-boson models composed by a single bosonic mode and an ensemble of $N$ identical two-level atoms. The situation where the coupling between the bosonic mode and the atoms generates real and virtual processes is studied, where the whole system is in thermal equilibrium with a reservoir at temperature $\beta^{-1}$. Phase transitions from ordinary fluorescence to superradiant phase in three different models is investigated. First a model where the coupling between the bosonic mode and the $j-th$ atom is via the pseudo-spin operator $\sigma^{,z}_{(j)}$ is studied. Second, we investigate the generalized Dicke model, introducing different coupling constants between the single mode bosonic field and the environment, $g_{1}$ and $g_{2}$ for rotating and counter-rotating terms, respectively. Finally it is considered a modified version of the generalized Dicke model with intensity-dependent coupling in the rotating terms. In the first model the zero mode contributes to render the canonical entropy a negative quantity for low temperatures. The last two models presents phase transitions, even when only Hamiltonian terms which generates virtual processes are considered

Cinema en curs: Transmission of film as creation and creation as experience

This article – initially published in Spanish by Toma Uno in 2012 – explores the Catalonian project Cinema en curs, an annual, recurring and now international programme of film education that takes place with students aged 10–18 in schools and colleges. First detailing both the rationale and methodology motivating the project, the article goes on to discuss core aspects of the approach of Cinema en curs: the Lumière minutes exercise and the short films which serve as the culmination of students’ work on the project. In doing so, the article also explores the value of approaches to film education that help learners develop an appreciation of their own lived experiences and the places in which they live. A new introduction from the authors places the article’s discussion of Cinema en curs in a contemporary context

Daily Solar Energy Estimation for Minimizing Energy Storage Requirements in PV Power Plants

This paper proposes an optimized energy management strategy (EMS) for photovoltaic (PV) power plants with energy storage (ES) based on the estimation of the daily solar energy production. This EMS produces a constant-by-hours power reference which mitigates the stochastic nature of PV production typically associated to the solar resource, and enables PV power plants to take part in the day and intraday electricity markets. The possibility of using the intraday market sessions to refine the plant's power reference paves the way to minimizing the energy capacity ratings of the ES system required to operate the PV power plant without incurring excessive production deviations. This proposal is analyzed on an annual basis using actual irradiance data and theoretical irradiance models extracted from official databases

Predicción de la frescura del aceite de oliva virgen extra durante el almacenamiento mediante espectroscopía de fluorescencia

Virgin olive oil quality relates to flavor and unique health benefits. Some of these properties are at the most desirable level when the oil is just extracted, since it is not a product that improves with age. On the contrary, the concentrations of many compounds change during its shelf-life. These changes reveal the aging of the oil but do not necessarily mean decay in sensory properties, so in some cases an aged oil from healthy olives may be better qualified than a fresh one from olives affected by fermentation. The aim of this work is to analyze different methodologies proposed for assessing the quality of virgin olive oil with implications in freshness and aging of the oil, and to highlight the possibilities of rapid spectrofluorimetric techniques for assessing oil freshness by checking the evolution of pigments during storage. The observed change in the selected spectral features and mathematical modelling over time was compared with the accepted model for predicting the amount of pyropheophytin a, which is based on isokinetic studies. The best regression was obtained for 655 nm (adjusted-R2 = 0.91) wavelength, which matches the distinctive band of pigments. The two mathematical models described in this study highlight the usefulness of pigments in the prediction of the shelf-life of extra virgin olive oil.La calidad del aceite de oliva virgen está relacionada con su flavor y sus beneficios únicos para la salud. Algunas de estas propiedades se encuentran en el nivel más deseable cuando el aceite está recién extraído, ya que no es un producto que mejore con el tiempo. Por el contrario, las concentraciones de muchos compuestos cambian a lo largo de la vida útil. Estos cambios revelan el envejecimiento del aceite, pero no implican necesariamente la alteración de las propiedades sensoriales, por lo que en algunos casos un aceite envejecido procedente de aceitunas sanas puede presentar mejor calidad que uno fresco procedente de aceitunas afectadas por procesos de fermentación. El objetivo de este trabajo es estudiar diferentes metodologías propuestas para evaluar la calidad del aceite de oliva virgen con implicaciones en la frescura y el envejecimiento del aceite, destacando las posibilidades de las rápidas técnicas espectrofluorométricas para evaluar la frescura del aceite verificando la evolución de los pigmentos durante el almacenamiento. El cambio observado en las características espectrales seleccionadas y su modelado matemático a lo largo del tiempo se comparó con el modelo aceptado para predecir la cantidad de pirofeofitina a, que se basa en estudios isocinéticos. Los dos modelos matemáticos descritos en este estudio pusieron de manifiesto la utilidad de los pigmentos en la predicción de la vida útil del aceite de oliva virgen extra. La mejor regresión se obtuvo para 655 nm (R2-ajustado = 0,91), longitud de onda que coincide con la banda distintiva de pigmentos

Sustainability Improvements to Embry-Riddles Shuttle Services

Embry Riddle Aeronautical University (ERAU) is an aviation focused school that has an undergraduate population of 7,177 students as of Fall 2022. ERAU’s shuttle service is an essential resource for students to commute to and from school. Although a widely used resource, the current routes offered are limited to nearby student apartment complexes and operate only during weekdays. The current fleet of shuttle buses only contains five vans and transports students from the university to neighboring complexes such as Eagle Landing, Chanute, OnShore, Bellamy, and the Micaplex. Sustainability at ERAU is important to achieve development that meets the needs of the present student population without compromising the ability of prospective students, while preserving the current state of the university. The first step involves understanding the current situation of the shuttle system to plan where improvements can be made. This analysis will be conducted by gathering shuttle operation data that includes route maps, operation hours, vehicle cost, and student use. The second step will be to define the long-term and short-term goals of the proposed sustainability plan with periods specified to track the plan’s efficiency. The short-term goals will be to increase student use by 15% within 2-3 years by increasing the shuttle system capacity, expanding the days and times the shuttle operates, and diversifying the route the shuttle system provides. The long-term goal is to transfer into electrically powered vans such as the Ford E-Transit van within ten years. The third step will be developing and implementing the sustainability plan. This plan will follow the three ‘Overlapping Circles\u27 sustainability model. A stakeholder analysis will be implemented to understand how to communicate our plan across diverse stakeholders with the financial and social perspective\u27s ability to bring it to life. An office of sustainability will be established to accurately assess the progress and promote the implemented sustainability plan via posters and included in the prospective student tour guide speeches. This will be conducted on a two-stage surveying process. First, surveys will focus on the current users of the shuttle system. The second round of surveys will focus on gathering data from students that own a car and do not use the shuttle system to help the office of sustainability to make appropriate changes that will attract them to use it. Embry-Riddle should be focused on innovation and inclusion for all their students by giving them the ability of choosing a sustainable transportation system