Variation of Absorption Angstrom Exponent in Aerosols From Different Emission Sources

The absorption Angstrom exponent (AAE) describes the spectral dependence of light absorption by aerosols. AAE is typically used to differentiate between different aerosol types for example., black carbon, brown carbon, and dust particles. In this study, the variation of AAE was investigated mainly in fresh aerosol emissions from different fuel and combustion types, including emissions from ships, buses, coal-fired power plants, and residential wood burning. The results were assembled to provide a compendium of AAE values from different emission sources. A dual-spot aethalometer (AE33) was used in all measurements to obtain the light absorption coefficients at seven wavelengths (370-950 nm). AAE(470/950) varied greatly between the different emission sources, ranging from -0.2 +/- 0.7 to 3.0 +/- 0.8. The correlation between the AAE(470/950) and AAE(370-950) results was good (R-2 = 0.95) and the mean bias error between these was 0.02. In the ship engine exhaust emissions, the highest AAE(470/950) values (up to 2.0 +/- 0.1) were observed when high sulfur content heavy fuel oil was used, whereas low sulfur content fuels had the lowest AAE(470/950) (0.9-1.1). In the diesel bus exhaust emissions, AAE(470/950) increased in the order of acceleration (0.8 +/- 0.1), deceleration (1.1 +/- 0.1), and steady driving (1.2 +/- 0.1). In the coal-fired power plant emissions, the variation of AAE(470/950) was substantial (from -0.1 +/- 2.1 to 0.9 +/- 1.6) due to the differences in the fuels and flue gas cleaning conditions. Fresh wood-burning derived aerosols had AAE(470/950) from 1.1 +/- 0.1 (modern masonry heater) to 1.4 +/- 0.1 (pellet boiler), lower than typically associated with wood burning, while the burn cycle phase affected AAE variation.Peer reviewe

Analysis of Peculiarities of the Stellar Velocity Field in the Solar Neighborhood

Based on a new version of the Hipparcos catalogue and an updated Geneva-Copenhagen survey of F and G dwarfs, we analyze the space velocity field of about 17000 single stars in the solar neighborhood. The main known clumps, streams, and branches (Pleiades, Hyades, Sirius, Coma Berenices, Hercules, Wolf 630-alpha Ceti, and Arcturus) have been identified using various approaches. The evolution of the space velocity field for F and G dwarfs has been traced as a function of the stellar age. We have managed to confirm the existence of the recently discovered KFR08 stream. We have found 19 Hipparcos stars, candidates for membership in the KFR08 stream, and obtained an isochrone age estimate for the stream, 13 Gyr. The mean stellar ages of the Wolf 630-alpha Ceti and Hercules streams are shown to be comparable, 4--6 Gyr. No significant differences in the metallicities of stars belonging to these streams have been found. This is an argument for the hypothesis that these streams owe their origin to a common mechanism.Comment: 23 pages, 9 figure

Galactic Kinematics from OB3 Stars with Distances determined from Interstellar Ca II Lines

Based on data for 102 OB3 stars with known proper motions and radial velocities, we have tested the distances derived by Megier et al. from interstellar Ca II spectral lines. The internal reconciliation of the distance scales using the first derivative of the angular velocity of Galactic rotation {\Omega}'0 and the external reconciliation with Humphreys's distance scale for OB associations refined by Mel'nik and Dambis show that the initial distances should be reduced by \approx 20%. Given this correction, the heliocentric distances of these stars lie within the range 0.6-2.6 kpc. A kinematic analysis of these stars at a fixed Galactocentric distance of the Sun, R0=8 kpc, has allowed the following parameters to be determined:(1) the solar peculiar velocity components (U_o,V_o,W_o)=(8.9,10.3,6.8)\pm(0.6,1.0,0.4) km/s;(2) the Galactic rotation parameters {\Omega}_o=-31.5\pm0.9 km/s/kpc, {\Omega}'_o=+4.49\pm0.12 km/s/kpc^2, {\Omega}"_o=-1.05\pm0.38 km/s/kpc^3, (the corresponding Oort constants are A=17.9\pm0.5 km/s/kpc, B=-13.6\pm1.0 km/s/kpc and the circular rotation velocity of the solar neighborhood is |V_o|=252\pm14 km/s); (3) the spiral density wave parameters, namely: the perturbation amplitudes for the radial and azimuthal velocity components, respectively, f_R = -12.5\pm1.1 km/s and f_{\theta}=2.0\pm1.6 km/s; the pitch angle for the two-armed spiral pattern i=-5.3\pm0.3 degrees, with the wavelength of the spiral density wave at the solar distance being {\lambda}=2.3\pm0.2 kpc; the Sun's phase in the spiral wave {\chi}_o=-91\pm4 degrees.Comment: 14 pages, 4 figures, 3 table

Household solid waste combustion with wood increases particulate trace metal and lung deposited surface area emissions

In households, municipal solid waste (MSW) is often burned along with wood to get rid of waste, to help in ignition or simply to reduce fuel costs. The aim of this study was to characterize the influence of household waste combustion, along with wood, on the physical and chemical properties of particulate emissions in a flue gas of a masonry heater. The MSW burning alongside wood increased average particulate matter (PM) mass (65%), lung deposited surface areas (LDSA, 15%), black carbon (BC, 65%) concentrations and the average particle size in the flue gas. The influence of MSW was smaller during ignition and burning phases, but especially during fuel additions, the mass, number, and LDSA concentrations increased significantly and their size distributions moved towards larger particles. For wood burning the trace metal emissions were relatively low, but significant increase (3.3–179 -fold increase over cycle) was seen when MSW was burned along the wood. High ratios were observed especially during fuel addition phases but, depending on compounds, also during ignition and burning end phases. The highest ratios were observed for chloride compounds (HCl, KCl, NaCl). The observed increase in light-absorbing particle, trace metal and BC concentrations in flue gas when adding wood with MSW are likely to have negative impacts on air quality, visibility, human health and climate. Furthermore, metals may also affect the condition and lifetime of the burning device due to corrosion.publishedVersionPeer reviewe