Leveraging BIM and big data to deliver well maintained highways

The Highway infrastructure is one of the most valuable assets for any state or national Government. Efficient operations of Highways lead to success of national and local economies as well as improve the quality of life of the general public dependent on it.  In order to ensure aging road networks continues to move with its ever increasing number of users, requires maintenance and improvements to the road network at the highest standard. Increasing scrutiny over the cost of maintenance along with increasing pressure from Government and the public for transparency over road network spending, has made a strong case for more efficient management of the Highway road asset and traffic management data. Better management of information could allow for life cycle management of asset data and predictive analytics. This paper focuses on proposing a platform that integrates various technologies and systems of Highways Authority and its supply chain, to allow for continuous flow of data throughout an assets life-cycle, leading to seamless, collaborative and effecting working. The integration takes into account developments in the area of BIM and big data; BIM provides a platform to better integrate information whereas big data can provide analytical platform to draw insights

Dicyanidobis(thio­urea-κS)cadmium(II) monohydrate

In the title compound, [Cd(CN)2(CH4N2S)2]·H2O, the Cd atom lies on a twofold rotation axis and is bonded to two S atoms of thio­urea and two C atoms of the cyanide anions in a distorted tetra­hedral environment. The crystal structure is stabilized by N—H⋯N(CN), N—H⋯O, O—H⋯N and N—H⋯S hydrogen bonds

Drug overdose: a wake up call! Experience at a tertiary care centre in Karachi, Pakistan

OBJECTIVE: To study the characteristics of patients admitted with drug overdose caused either by accidental overdose of the prescribed medications or as an act of deliberate self harm (DSH) at a tertiary care hospital in Karachi, Pakistan.METHODS: A retrospective case series review was conducted at the Aga Khan University Hospital from January 2002 to October 2006. Three hundred and twenty four adult patients admitted with drug overdose were included in the study.RESULTS: Our sample group revealed mean age of 36.2 +/- 17.0 years, more females (59%), housewives (34%), and students (20%). Fifty six percent of patients committing DSH were married (p = 0.001), 81% needed in-patient psychiatric services (p = 0.016) of whom a significantly high number (38%) refused it. Domestic and social issues were rated highest among DSH group (p = 0.003), depression among females was common (p = 0.028) and Benzodiazepines (41%) was the most frequently used drug (p = 0.021). Sub-group analysis of accidental overdoses revealed mean age of 45.6 +/- 19.6 years, single (75.4%) and males (54.1%). Drugs used were mainly Benzodiazepines (18%) followed by Opioids (11%), Antiepileptics (10%) and Warfarin (10%).CONCLUSION: Our study showed that depressed housewives are at greater risk for DSH. Domestic and social issues were rated highest and Benzodiazepines were the most commonly used agents. Most of our patients refused inpatient psychiatric treatment leading us to believe that general awareness of psychiatric illnesses is imperative in our community. High number of accidental overdoses is alarming in older, single males convincing us to believe that existing pharmacy system needs further evaluation and modification

Structural modulation of π-conjugated linkers in D–π–A dyes based on triphenylamine dicyanovinylene framework to explore the NLO properties

A donor–π–acceptor type series of Triphenylamine–dicyanovinylene-based chromophores (DPMN1–DPMN11) was designed theoretically by the structural tailoring of π-linkers of experimentally synthesized molecules DTTh and DTTz to exploit changes in the optical properties and their nonlinear optical materials (NLO) behaviour. Density functional theory (DFT) computations were employed to understand the electronic structures, absorption spectra, charge transfer phenomena and the influence of these structural modifications on NLO properties. Interestingly, all investigated chromophores exhibited lower band gap (2.22–2.60 eV) with broad absorption spectra in the visible region, reflecting the remarkable NLO response. Furthermore, natural bond orbital (NBO) findings revealed a strong push–pull mechanism in DPMN1–DPMN11 as donor and π-conjugates exhibited positive, while all acceptors showed negative values. Examination of electronic transitions from donor to acceptor moieties via π-conjugated linkers revealed greater linear (〈α〉 = 526.536–641.756 a.u.) and nonlinear (βtot = 51 313.8–314 412.661 a.u.) response. It was noted that the chromophores containing imidazole in the second p-linker expressed greater hyperpolarizability when compared with the ones containing pyrrole. This study reveals that by controlling the type of π-spacers, interesting metal-free NLO materials can be designed, which can be valuable for the hi-tech NLO applications

Groundwater Quality Assessment for Drinking Purpose of Taluka Chachro, Thar Desert, Pakistan; Using Water Quality Indices, and Geospatial Techniques

Groundwater quality of taluka Chachro was investigated by analyzing thirty-two groundwater samples for drinking purpose. Multivariate statistical approaches with GIS interpolations (IDW) were applied for the identification of significant geochemical processes governing the groundwater quality.. Results showed the concentrations of physiochemical parameter in the study area exceeded the prescribed level of WHO guidelines. The EC and TDS varied from 2593-18950 µS/cm and 1659-12128 mg/l, respectively. The Ca, Mg, Na, and K range from 36-288, 17-272, 420-3280, and 9.5-101 mg/l, respectively. While, Cl, HCO3, SO4, and NO3 varied from 539-5738, 210-1150, 79-870, and 6.66-17.13 mg/l respectively. The mean values of EC, TDS, Na, Cl, HCO3, SO4, and NO3 were higher than the prescribed level of WHO 2011. Higher concentrations above the acceptable limits were recorded for K 96.15%, SO488.46%, and HCO3 82.16% of analysed samples. Multivariate statistical analysis suggested that the input of natural processes have influenced groundwater quality which resulted in changing the groundwater chemistry of taluka Chachro. The results revealed the dominant trend among the cations was Na>Ca>Mg>K while among the anions it was Cl>HCO3>SO4. Based on the drinking water quality index 50% were unsuitable for drinking

Effect of 1-Methyl Cyclopropane and Modified Atmosphere Packaging on the Storage of Okra (Abelmoschus esculentus L.) : Theory and Experiments

Okra possesses a short shelf-life which limits its marketability, thereby, the present study investigates the individual and combined effect of 1-methylcyclopropene (1-MCP) and modified atmosphere packaging (MAP) on the postharvest storage life of okra. The treated/ untreated okra samples were stored at ambient (i.e., 27 °C) and low (i.e., 7 °C) temperatures for eight and 20 days, respectively. Results revealed that the 1-MCP and/or MAP treatment successfully inhibited fruit softening, reduction in mucilage viscosity, and color degradation (hue angle, ∆E, and BI) in the product resulting in a longer period of shelf-life. However, MAP with or without 1-MCP was more effective to reduce weight loss in okra stored at both ambient and cold storage conditions. Additionally, ascorbic acid and total antioxidants were also retained in 1-MCP with MAP during cold storage. The 1-MCP in combination with MAP effectively suppressed respiration rate and ethylene production for four days and eight days at 27 °C and 7 °C temperature conditions, respectively. According to the results, relatively less chilling injury stress also resulted when 1-MCP combined with MAP. The combined treatment of okra pods with 1-MCP and MAP maintained the visual quality of the product in terms of overall acceptability for four days at 20 °C and 20 days at 7 °C

Hydrogeochemical Assessment of Groundwater of Taluka Chachro, Thar Parker, district, Sindh, Pakistan

The study was conducted to evaluate the hydrogeochemistry of groundwater. Twenty-six groundwater samples were analysed for the groundwater quality of Chachro Taluka. The EC and TDS contents in most of the water samples were above WHO (2011) recommended limits. Almost all water samples collected from dugwells located in the study area have elevated concentrations of Na and Cl exceeding the WHO guidelines. Results of Ca, and Mg show that 92% and 96% of groundwater samples were within the prescribed limit respectively. Whereas, HCO3, SO4, and NO3 contnets of 88%, 77%, and 69% respectively are also above the guidelines. Statistical results revealed a dominating trend among the cations of Na+>Ca+2>Mg+2>K+ and anions occur in the order of abundance, as Cl->HCO3->SO4 ->NO3, respectively. The water quality index (WQI) shows that 15% groundwater samples belong to poor category, and 35% water samples were found belonging to very poor category.While, remaining 50% wells were found unsuitable for drinking purpos