2,538 research outputs found
Frequency response in surface-potential driven electro-hydrodynamics
Using a Fourier approach we offer a general solution to calculations of slip
velocity within the circuit description of the electro-hydrodynamics in a
binary electrolyte confined by a plane surface with a modulated surface
potential. We consider the case with a spatially constant intrinsic surface
capacitance where the net flow rate is in general zero while harmonic rolls as
well as time-averaged vortex-like components may exist depending on the spatial
symmetry and extension of the surface potential. In general the system displays
a resonance behavior at a frequency corresponding to the inverse RC time of the
system. Different surface potentials share the common feature that the
resonance frequency is inversely proportional to the characteristic length
scale of the surface potential. For the asymptotic frequency dependence above
resonance we find a 1/omega^2 power law for surface potentials with either an
even or an odd symmetry. Below resonance we also find a power law omega^alpha
with alpha being positive and dependent of the properties of the surface
potential. Comparing a tanh potential and a sech potential we qualitatively
find the same slip velocity, but for the below-resonance frequency response the
two potentials display different power law asymptotics with alpha=1 and
alpha~2, respectively.Comment: 4 pages including 1 figure. Accepted for PR
Micro- vs. macro-phase separation in binary blends of poly(styrene)-poly(isoprene) and poly(isoprene)-poly(ethylene oxide) diblock copolymers
In this paper we present an experimentally determined phase diagram of binary blends of the diblock copolymers poly(styrene)-poly(isoprene) and poly(isoprene)-poly(ethylene oxide). At high temperatures, the blends form an isotropic mixture. Upon lowering the temperature, the blend macro-phase separates before micro-phase separation occurs. The observed phase diagram is compared to theoretical predictions based on experimental parameters. In the low-temperature phase the crystallisation of the poly(ethylene oxide) block influences the spacing of the ordered phase
Andreev magnetotransport in low-dimensional proximity structures: Spin-dependent conductance enhancement
We study the excess conductance due to the superconducting proximity effect
in a ballistic two-dimensional electron system subject to an in-plane magnetic
field. We show that under certain conditions the interplay of the Zeeman spin
splitting and the effect of a screening supercurrent gives rise to a
spin-selective Andreev enhancement of the conductance and anomalies in its
voltage, temperature and magnetic field characteristics. The magnetic-field
influence on Andreev reflection is discussed in the context of using
superconducting hybrid junctions for spin detection.Comment: 4 pages, 5 figure
Determination of yolk contamination in liquid egg white using Raman spectroscopy
Purified egg white is an important ingredient in a number of baked and confectionary foods because of its foaming properties. However, yolk contamination in amounts as low as 0.01% can impede the foaming ability of egg white. In this study, we used Raman spectroscopy to evaluate the hypothesis that yolk contamination in egg white could be detected based on its molecular optical properties. Yolk contaminated egg white samples (n = 115) with contamination levels ranging from 0% to 0.25% (on weight basis) were prepared. The samples were excited with a 785 nm laser and Raman spectra from 250 to 3,200 cm−1 were recorded. The Raman spectra were baseline corrected using an optimized piecewise cubic interpolation on each spectrum and then normalized with a standard normal variate transformation. Samples were randomly divided into calibration (n = 77) and validation (n = 38) data sets. A partial least squares regression (PLSR) model was developed to predict yolk contamination levels, based on the Raman spectral fingerprint. Raman spectral peaks, in the spectral region of 1,080 and 1,666 cm−1, had the largest influence on detecting yolk contamination in egg white. The PLSR model was able to correctly predict yolk contamination levels with an R2 = 0.90 in the validation data set. These results demonstrate the capability of Raman spectroscopy for detection of yolk contamination at very low levels in egg white and present a strong case for development of an on-line system to be deployed in egg processing plants
The impact of prior outpatient ACE inhibitor use on 30-day mortality for patients hospitalized with community-acquired pneumonia
BACKGROUND: Recent studies suggest that angiotensin-converting enzyme (ACE) inhibitors may have beneficial effects for patients at risk for some types of infections. We examined the effect of prior outpatient use of ACE inhibitors on mortality for patients hospitalized with community-acquired pneumonia. METHODS: A retrospective cohort study conducted at two tertiary teaching hospitals. Eligible subjects were admitted with a diagnosis of, had a chest x-ray consistent with, and had a discharge ICD-9 diagnosis of pneumonia. Subjects were excluded if they were "comfort measures only" or transferred from another acute care hospital. Subjects were considered to be on a medication if they were taking it at the time of presentation. RESULTS: Data was abstracted on 787 subjects at the two hospitals. Mortality was 9.2% at 30-days and 13.6% at 90-days. At presentation 52% of subjects were low risk, 34% were moderate risk, and 14% were high risk. In the multivariable conditional logistic regression analysis, after adjusting for potential confounders, the use of ACE inhibitors at presentation (odds ratio 0.44, 95% confidence interval 0.22–0.89) was significantly associated with 30-day mortality. CONCLUSION: Prior outpatient use of an ACE inhibitor was associated with decreased mortality in patients hospitalized with community-acquired pneumonia despite their use being associated with comorbid illnesses likely to contribute to increased mortality. Confirmatory studies are needed, as well as research to determine the mechanism(s) of this protective effect
Density functional study of the adsorption and van der Waals binding of aromatic and conjugated compounds on the basal plane of MoS2
Accurate calculations of adsorption energies of cyclic molecules are of key importance in investigations of, e.g., hydrodesulfurization (HDS) catalysis. The present density functional theory (DFT) study of a set of important reactants, products, and inhibitors in HDS catalysis demonstrates that van der Waals interactions are essential for binding energies on MoS2 surfaces and that DFT with a recently developed exchange-correlation functional (vdW-DF) accurately calculates the van der Waals energy. Values are calculated for the adsorption energies of butadiene, thiophene, benzothiophene, pyridine, quinoline, benzene, and naphthalene on the basal plane of MoS2, showing good agreement with available experimental data, and the equilibrium geometry is found as flat at a separation of about 3.5 \uc5 for all studied molecules. This adsorption is found to be due to mainly van der Waals interactions. Furthermore, the manifold of adsorption-energy values allows trend analyses to be made, and they are found to have a linear correlation with the number of main atoms. \ua9 2009 American Institute of Physics
Interwoven magnetic and flux line structures in single crystal (Tm,Er)Ni2B2C
We review studies of the interactions between magnetic order and the flux line lattice (FLL) in the (RE)Ni2B2Cintermetallic borocarbides for (RE)=Tm and Er using small angle neutron scattering (SANS) and magneto-transport. For (RE)=Tm the magnetic order and the FLL assume a common symmetry, sharing a phase transition at ∼2 kOe, despite an order of magnitude difference in periodicity. For (RE)=Er, the penetration depth λ and the coherence length ξ, both of which are derived from the FLL form factor, are modified near TN=6 K by a theoretically predicted weakly divergent pairbreaking. Finally, below 2.3 K, (RE)=Er shows a coexistence of weak ferromagnetism and superconductivity. This state reveals a highly disordered FLL and a striking increase in the critical current, both arising from the strong ferromagnetic pairbreaking
Coulomb Drag in Coherent Mesoscopic Systems
We present a theory for Coulomb drag between two mesoscopic systems. Our
formalism expresses the drag in terms of scattering matrices and wave
functions, and its range of validity covers both ballistic and disordered
systems. The consequences can be worked out either by analytic means, such as
the random matrix theory, or by numerical simulations. We show that Coulomb
drag is sensitive to localized states, which usual transport measurements do
not probe. For chaotic 2D-systems we find a vanishing average drag, with a
nonzero variance. Disordered 1D-wires show a finite drag, with a large
variance, giving rise to a possible sign change of the induced current.Comment: 4 pages including 2 figures. Minor changes. Accepted for publication
in Phys. Rev. Let
A seven-octave-bandwidth echo sounding system for application to fish and zooplankton
Abstract only. Journal home page: http://scitation.aip.org/jasa
Overcoming the myths of mainstream economics to enable a newwellbeing economy
Increasingly, empirical evidence refutes many of the theoretical pillars of mainstream economics. These theories have persisted despite the fact that they support unsustainable and undesirable environmental, social, and economic outcomes. Continuing to embrace them puts at risk the possibility of achieving the Sustainable Development Goals and overcoming other global challenges. We discuss a selection of paradoxes and delusions surrounding mainstream economic theories related to: (1) efficiency and resource use, (2) wealth and wellbeing, (3) economic growth, and (4) the distribution of wealth within and between rich and poor nations. We describe a wellbeing economy as an alternative for guiding policy development. In 2018, a network of Wellbeing Economy Governments (WEGo), (supported by, but distinct from, the larger Wellbeing Economy Alliance-WEAll) promoting new forms of governance that diverge from the ones on which the G7 and G20 are based, has been launched and is now a living project. Members of WEGo aim at advancing the three key principles of a wellbeing economy: Live within planetary ecological boundaries, ensure equitable distribution of wealth and opportunity, and efficiently allocate resources (including environmental and social public goods), bringing wellbeing to the heart of policymaking, and in particular economic policymaking. This network has potential to fundamentally re-shape current global leadership still anchored to old economic paradigms that give primacy to economic growth over environmental and social wealth and wellbeing
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