675 research outputs found
Governance, representation and the ‘monstrous regiment’: is the collective feminine?
Alternatives to the individualistic emphasis of liberal theory focus attention on collective dimensions of social life with implications for legal and political analysis of the state, of representation, and of international law. In this context, relationships between the individual–collective dichotomy and the dichotomy of gender demand attention because of the claimed affiliations of individualism with social understandings of masculinity
Engaging and empowering first-year students through curriculum design: perspectives from the literature
There is an increasing value being placed on engaging and empowering first-year students and first-year curriculum design is a key driver and opportunity to ensure early enculturation into successful learning at university. This paper summarises the literature on first-year curriculum design linked to student engagement and empowerment. We present conceptualisations of ‘curriculum’ and examples from first-year curriculum design. We also note the limited literature where students have been involved in designing first-year curricula. The results of the literature review suggest that key characteristics of engaging first-year curricula include active learning, timely feedback, relevance and challenge. The literature also points to the importance of identifying students' abilities on entry to university as well as being clear about desired graduate attributes and developmental goals. Acknowledging realities and constraints, we present a framework for the first-year curriculum design process based on the literature
Flux through a hole from a shaken granular medium
We have measured the flux of grains from a hole in the bottom of a shaken
container of grains. We find that the peak velocity of the vibration, vmax,
controls the flux, i.e., the flux is nearly independent of the frequency and
acceleration amplitude for a given value of vmax. The flux decreases with
increasing peak velocity and then becomes almost constant for the largest
values of vmax. The data at low peak velocity can be quantitatively described
by a simple model, but the crossover to nearly constant flux at larger peak
velocity suggests a regime in which the granular density near the container
bottom is independent of the energy input to the system.Comment: 14 pages, 4 figures. to appear in Physical Review
Competing C–Br and C–C Bond Fission Following 1[n(O),π∗(C=O)] Excitation in Bromoacetone: Conformation Dependence of Nonadiabaticity at a Conical Intersection
These experiments investigate the competition between C-C and C-Br bond fission in bromoacetone excited in the (1)[n(O),pi(*)(C=O)] absorption, elucidating the role of molecular conformation in influencing the probability of adiabatically traversing the conical intersection along the C-C fission reaction coordinate. In the first part of the paper, measurement of the photofragment velocity and angular distributions with a crossed laser-molecular beam time-of-flight technique identifies the primary photofragmentation channels at 308 nm. The time-of-flight spectra evidence two dissociation channels, C-Br fission and fission of one of the two C-C bonds, BrH2C-COCH3. The distribution of relative kinetic energies imparted to the C-Br fission and C-C fission fragments show dissociation is not occurring via internal conversion to the ground electronic state and allow us to identify these channels in the closely related systems of bromoacetyl- and bromopropionyl chloride. In the second part of the work we focus on the marked conformation dependence to the branching between C-C fission and C-Br fission. Photofragment angular distribution measurements show that C-Br fission occurs primarily from the minor, anti, conformer, giving a beta of 0.8, so C-C fission must dominate the competition in the gauche conformer. Noting that the dynamics of these two bond fission pathways are expected to be strongly influenced by nonadiabatic recrossing of the reaction barriers, we investigate the possible mechanisms for the conformation dependence of the nonadiabatic recrossing with low-level ab initio electronic structure calculations on the C-Br reaction coordinate and qualitative consideration of the conical intersection along the C-C reaction coordinate. The resulting model proposes that C-C bond fission,cannot compete with C-Br fission in the anti conformer because the dissociation samples regions of the phase space near the conical intersection along the CC fission reaction coordinate, where nonadiabaticity inhibits C-C fission, while from the gauche conformer C-C fission can proceed more adiabatically and dominate C-Br fission. A final experiment confirms that the branching ratio changes with the relative conformer populations in accord with this model
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Nuclear structure and shapes from prompt gamma ray spectroscopy of fission products
Many nuclear shape phenomena are predicted to occur in neutron-rich nuclei. The best source for the production of these nuclides is the spontaneous fission which produces practically hundreds of nuclides with yields of greater than 0.1 % per decay. Measurements of coincident gamma rays with large Ge arrays have recently been made to obtain information on nuclear structures and shapes of these neutron- rich nuclei. Among the important results that have been obtained from such measurements are octupole correlations in Ba isotopes, triaxial shapes in Ru nuclei, two-phonon vibrations in {sup 106}Mo and level lifetimes and quadrupole moments in Nd isotopes and A=100 nuclei. These data have been used to test theoretical models
Use of the breeding technique to estimate the structure of the analysis 'errors of the day'
A 3D-variational data assimilation scheme for a quasi-geostrophic channel model (Morss, 1998) is used to study the structure of the background error and its relationship to the corresponding bred vectors. The "true" evolution of the model atmosphere is defined by an integration of the model and "rawinsonde observations" are simulated by randomly perturbing the true state at fixed locations. Case studies using different observational densities are considered to compare the evolution of the Bred Vectors to the spatial structure of the background error. In addition, the bred vector dimension (BV-dimension), defined by Patil et al. (2001) is applied to the bred vectors. It is found that after 3-5 days the bred vectors develop well organized structures which are very similar for the two different norms (enstrophy and streamfunction) considered in this paper. When 10 surrogate bred vectors (corresponding to different days from that of the background error) are used to describe the local patterns of the background error, the explained variance is quite high, about 85-88%, indicating that the statistical average properties of the bred vectors represent well those of the background error. However, a subspace of 10 bred vectors corresponding to the time of the background error increased the percentage of explained variance to 96-98%, with the largest percentage when the background errors are large. These results suggest that a statistical basis of bred vectors collected over time can be used to create an effective constant background error covariance for data assimilation with 3D-Var. Including the "errors of the day" through the use of bred vectors corresponding to the background forecast time can bring an additional significant improvement
The Politics of Pleasure: Promenading on the Corniche and Beachgoing
Can the pleasures of young Palestinian women from refugee camps in promenading on the Beirut seaside Corniche on a warm summer evening be political? Or days spent at women-only beaches? If so, how do we understand such pleasure as everyday practices, as a politics of the present moment, or conversely (or simultaneously) as mechanisms of being co-opted into a broader apparatus of consumerist ideology and capitalist complacency? Drawing on ethnographic research over 2 years I argue that these moments of pleasure are caesuras in the massive apparatus of power – welded from strands of work, neoliberal practice, nationalist certitudes and political exclusion – which binds these women. These acts of pleasure cannot easily be categorised as ‘resistance’ but I argue that they should not facilely be considered reinforcements of hegemonic control either. They are momentary and ephemeral recognitions of ordinary life lived in hard times, attempts at clawing back an instant of joy from the drudgery of the everyday, and a surrender to the enjoyment of conviviality in public and urban spaces. If they are at all political, they are so because such conviviality is ever harder to sustain in the calamity of hopelessness that characterises so much politics today
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EXAFS studies of lanthanide coordination in crystalline phosphates and amorphous phytates
As part of the DOE Efficient Separations and Processing Integrated Program, techniques are being developed to stabilize radioactive and hazardous contaminants to prevent their migration from buried wastes. This report is part of a study to immobilize actinide ions in the near-surface environment by reacting them with organophosphorus complexants that decompose to phosphates. Nd and Gd ions were used as models for Pu, Am, and Cm ions; phytic acid was used as the complexant. Solid Nd and Gd phytates were prepared and the coordination characterized by EXAFS
Financial phantasmagoria: corporate image-work in times of crisis
Our purpose in this article is to relate the real movements in the economy during 2008 to the ?image-work? of financial institutions. Over the period January?December 2008 we collected 241 separate advertisements from 61 financial institutions published in the Financial Times. Reading across the ensemble of advertisements for themes and evocative images provides an impression of the financial imaginaries created by these organizations as the global financial crisis unfolded. In using the term ?phantasmagoria? we move beyond its colloquial sense of a set of strange images designed to dazzle towards the more technical connotation used by Ranci�re (2004) who suggested that words and images can offer a trace of an overall determining set-up if they are torn from their obviousness so they become phantasmagoric figures. The key phantasmagoric figure we identify here is that of the financial institution as timeless, immortal and unchanging; a coherent and autonomous entity amongst other actors. This notion of uniqueness belies the commonality of thinking which precipitated the global financial crisis as well as the limited capacity for control of financial institutions in relation to market events. It also functions as a powerful naturalizing force, making it hard to question certain aspects of the recent period of ?capitalism in crisis?
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