Passivation of pigment particles for thermal control coatings

The preparation of a matrix of 48 samples consisting of pigments and pigmented paints is described. The results obtained from testing these samples by electron spin resonance and by in situ spectral reflectance measurements in space simulation tests are presented. Conclusions and recommendations for further research are given

Mesons and Flavor on the Conifold

We explore the addition of fundamental matter to the Klebanov-Witten field theory. We add probe D7-branes to the ${\cal N}=1$ theory obtained from placing D3-branes at the tip of the conifold and compute the meson spectrum for the scalar mesons. In the UV limit of massless quarks we find the exact dimensions of the associated operators, which exhibit a simple scaling in the large-charge limit. For the case of massive quarks we compute the spectrum of scalar mesons numerically.Comment: 19 pages, 3 figures, v2: typos fixe

Mode signature and stability for a Hamiltonian model of electron temperature gradient turbulence

Stability properties and mode signature for equilibria of a model of electron temperature gradient (ETG) driven turbulence are investigated by Hamiltonian techniques. After deriving the infinite families of Casimir invariants, associated with the noncanonical Poisson bracket of the model, a sufficient condition for stability is obtained by means of the Energy-Casimir method. Mode signature is then investigated for linear motions about homogeneous equilibria. Depending on the sign of the equilibrium "translated" pressure gradient, stable equilibria can either be energy stable, i.e.\ possess definite linearized perturbation energy (Hamiltonian), or spectrally stable with the existence of negative energy modes (NEMs). The ETG instability is then shown to arise through a Kre\u{\i}n-type bifurcation, due to the merging of a positive and a negative energy mode, corresponding to two modified drift waves admitted by the system. The Hamiltonian of the linearized system is then explicitly transformed into normal form, which unambiguously defines mode signature. In particular, the fast mode turns out to always be a positive energy mode (PEM), whereas the energy of the slow mode can have either positive or negative sign

Cation occupancy determination in manganese zinc ferrites using Fourier transform infrared spectroscopy

The magnetic and electric properties of ferrites are influenced by the cation distribution within the crystalline spinel lattice. Methods such as extended x-ray-absorption fine structure(EXAFS) have been used to determine cation occupancies within the crystalline structure of materials such as manganesezincferrite (MZFO); however, it is not practical to be used for daily analysis. Fourier transform infrared (FTIR)spectroscopy is another technique which has the potential to determine cation occupancy while offering speed and convenience. In the literature it has been demonstrated that in ferrite systems FTIR data can be correlated to cation percentages when comparing tetrahedral (Td) and octahedral (Oh) sites. FTIRspectra were collected on a series of MZFO nanoparticles in the range from 200 to 600cm−1 and two absorbance peaks were observed. The first absorption region shifted with changing sample composition as calculated from transmission EXAFS experiments and elemental analysis. The data was normalized to the maximum of the peak of interest and the shifts were correlated to cation occupancy

Mirror Manifolds in Higher Dimension

We describe mirror manifolds in dimensions different from the familiar case of complex threefolds. We emphasize the simplifying features of dimension three and supply more robust methods that do not rely on such special characteristics and hence naturally generalize to other dimensions. The moduli spaces for Calabi--Yau $d$-folds are somewhat different from the ``special K\"ahler manifolds'' which had occurred for $d=3$, and we indicate the new geometrical structures which arise. We formulate and apply procedures which allow for the construction of mirror maps and the calculation of order-by-order instanton corrections to Yukawa couplings. Mathematically, these corrections are expected to correspond to calculating Chern classes of various parameter spaces (Hilbert schemes) for rational curves on Calabi--Yau manifolds. Our results agree with those obtained by more traditional mathematical methods in the limited number of cases for which the latter analysis can be carried out. Finally, we make explicit some striking relations between instanton corrections for various Yukawa couplings, derived from the associativity of the operator product algebra.Comment: 44 pages plus 3 tables using harvma

Validity and practical utility of accelerometry for the measurement of in-hand physical activity in horses

Background: Accelerometers are valid, practical and reliable tools for the measurement of habitual physical activity (PA). Quantification of PA in horses is desirable for use in research and clinical settings. The objective of this study was to evaluate a triaxial accelerometer for objective measurement of PA in the horse by assessment of their practical utility and validity. Horses were recruited to establish both the optimal site of accelerometer attachment and questionnaire designed to explore owner acceptance. Validity and cut-off values were obtained by assessing PA at various gaits. Validation study- 20 horses wore the accelerometer while being filmed for 10 min each of rest, walking and trotting and 5 mins of canter work. Practical utility study- five horses wore accelerometers on polls and withers for 18 h; compliance and relative data losses were quantified. Results: Accelerometry output differed significantly between the four PA levels (P <0•001) for both wither and poll placement. For withers placement, ROC analyses found optimal sensitivity and specificity at a cut-off of <47 counts per minute (cpm) for rest (sensitivity 99.5 %, specificity 100 %), 967–2424 cpm for trotting (sensitivity 96.7 %, specificity 100 %) and ≥2425 cpm for cantering (sensitivity 96.0 %, specificity 97.0 %). Attachment at the poll resulted in optimal sensitivity and specificity at a cut-off of <707 counts per minute (cpm) for rest (sensitivity 97.5 %, specificity 99.6 %), 1546–2609 cpm for trotting (sensitivity 90.33 %, specificity 79.25 %) and ≥2610 cpm for cantering (sensitivity 100 %, specificity 100 %) In terms of practical utility, accelerometry was well tolerated and owner acceptance high. Conclusion: Accelerometry data correlated well with varying levels of in-hand equine activity. The use of accelerometers is a valid method for objective measurement of controlled PA in the horse

Atomistic Theory of Coherent Spin Transfer between Molecularly Bridged Quantum Dots

Time-resolved Faradary rotation experiments have demonstrated coherent transfer of electron spin between CdSe colloidal quantum dots coupled by conjugated molecules. We employ here a Green's function approach, using semi-empirical tight-binding to treat the nanocrystal Hamiltonian and Extended Huckel theory to treat the linking molecule Hamiltonian, to obtain the coherent transfer probabilities from atomistic calculations, without the introduction of any new parameters. Calculations on 1,4-dithiolbenzene and 1,4-dithiolcyclohexane linked nanocrystals agree qualitatively with experiment and provide support for a previous transfer Hamiltonian model. We find a striking dependence on the transfer probabilities as a function of nanocrystal surface site attachment and linking molecule conformation. Additionally, we predict quantum interference effects in the coherent transfer probabilities for 2,7-dithiolnaphthalene and 2,6-dithiolnaphthalene linking molecules. We suggest possible experiments based on these results that would test the coherent, through-molecule transfer mechanism.Comment: 12 pages, 9 figures. Submitted Phys. Rev.

Combinatorial Games with a Pass: A dynamical systems approach

By treating combinatorial games as dynamical systems, we are able to address a longstanding open question in combinatorial game theory, namely, how the introduction of a "pass" move into a game affects its behavior. We consider two well known combinatorial games, 3-pile Nim and 3-row Chomp. In the case of Nim, we observe that the introduction of the pass dramatically alters the game's underlying structure, rendering it considerably more complex, while for Chomp, the pass move is found to have relatively minimal impact. We show how these results can be understood by recasting these games as dynamical systems describable by dynamical recursion relations. From these recursion relations we are able to identify underlying structural connections between these "games with passes" and a recently introduced class of "generic (perturbed) games." This connection, together with a (non-rigorous) numerical stability analysis, allows one to understand and predict the effect of a pass on a game.Comment: 39 pages, 13 figures, published versio

Electrophoresis of a polyelectrolyte through a nanopore

A hydrodynamic model for determining the electrophoretic speed of a polyelectrolyte through a nanopore is presented. It is assumed that the speed is determined by a balance of electrical and viscous forces arising from within the pore and that classical continuum electrostatics and hydrodynamics may be considered applicable. An explicit formula for the translocation speed as a function of the pore geometry and other physical parameters is obtained and is shown to be consistent with experimental measurements on DNA translocation through nanopores in silicon membranes. Experiments also show a weak dependence of the translocation speed on polymer length that is not accounted for by the present model. It is hypothesized that this is due to secondary effects that are neglected here.Comment: 5 pages, 2 column, 2 figure