2,065 research outputs found
Quality of Working Life and Employee Outcomes: A Literature Review
Quality of working life (QWL) is a research field studied since the 1970s,
which has grown considerably since then (Grote & Guest, 2017). QWL covers an
employee’s feelings about various dimensions of his or her work (Mosadeghrad, Ferlie &
Rosenberg, 2011) and includes dimensions related with home-work interface, working
condition, job and career satisfaction, control at work, stress at work, employee
commitment and general well-being (Fontinha, Van Laar & Easton, 2016). At an
individual level, positive outcomes of QWL include reduced absenteeism, lower
turnover, improved job satisfaction, improved individual productivity (Mosadeghrad,
Ferlie & Rosenberg, 2011), but studies that analyze, in a systematic way, all the
employee outcomes associated to QWL are scarce.
Following the systematic literature review (SLR) methodology, this article aims to
identify the employee outcomes associated to the QWL construct. This article
specifically explores research studies that have examined the QWL and consequences of it to individuals in a given organizational setting. Since our focus was to gain insight on the empirical investigation about QWL, we exclude studies with a primary focus on model development or testing measurement instruments. Extensive research has been performed at PROQUEST and EBSCO databases. The terms included the following on the title of the document: quality of life at work, work-related quality of life, quality of working life, working-life quality. Only the work-related consequences of QWL have been considered. The search has been limited to peer reviewed articles, theses, and conference papers published in the English language, between 1970 and 2017. The results show how a higher level of quality of life at work can improve several and relevant employee outcomes at work.CIEQV- Centro de Investigação em Qualidade de Vidainfo:eu-repo/semantics/publishedVersio
Liquid mixtures involving fluorinated alcohols: The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol) Experimental and Simulation
Liquid mixtures involving fluorinated alcohols:
The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol)
Experimental and Simulation
Pedro Duartea, Djêide Rodriguesa, Marcelo Silvaa, Pedro Morgadoa,
Luís Martinsa,b and Eduardo J. M. Filipea*
aCentro de Química Estrutural, Instituto Superior Técnico, 1049-001 Lisboa, Portugal
bCentro de Química de Évora, Universidade de Évora, 7000-671 Évora, Portugal
Fluorinated alcohols are substances with unique properties and high technological value in the pharmaceutical and chemical industries. Trifluoroethanol (TFE), in particular, displays a number of unusual properties as a solvent. For example, it dissolves nylon at room temperature and is effectively used as solvent in bioengineering. The presence of the three fluorines atoms gives the alcohol a high ionization constant, strong hydrogen bonding capability and stability at high temperatures.
In the pharmaceutical industry, TFE finds use as the major raw material for the production of inhalation anesthetics. Mixtures of TFE and water (known as Fluorinols®) are used as working fluids for Rankine cycle heat engines for terrestrial and space applications, as a result of a unique combination of physical and thermodynamic properties such as high thermal efficiency and excellent turbine expansion characteristics.
Environmentally, TFE is a CFC substitute with an acceptable short lifetime and with small ozone depletion potential. Additionally, TFE is known to induce conformational changes in proteins and it is used as a co-solvent to analyze structural features of partially folded states.
The (ethanol + TFE) system displays an interesting and peculiar behaviour, combining a negative azeotrope with high positive excess volumes.
In this work, liquid mixtures of (ethanol + TFE) were investigated. The densities of the mixtures were measured as a function of composition between 278K and 338K and at pressures up to 700 bar. The corresponding excess volumes as a function of temperature and pressure, the isothermal compressibilities and thermal expansivities were calculated from the experimental results. The mixtures are highly non-ideal with excess volumes ranging from 0.8 - 1.0 cm3mol-1.
Finally, molecular dynamic simulations were performed to model and interpret the experimental results. The Trappe force field was used to simulate the (TFE + ethanol) mixtures and calculate the corresponding excess volumes. The simulation results are able to reproduce the correct sign and order of magnitude of the experimental VE without fitting to the experimental data. Furthermore, the simulations suggest the presence of a particular type of hydrogen bridge between ethanol and TFE, that can help to rationalize the experimental results
SAFT-γ force field for the simulation of molecular fluids: 8. hetero-group coarse-grained models of perfluoroalkylalkanes assessed with new vapour-liquid interfacial tension data
The air-liquid interfacial behaviour of linear perfluoroalkylalkanes (PFAAs) is reported through a combined experimental and computer simulation study. The surface tensions of seven liquid PFAAs (perfluorobutylethane, F4H2; perfluorobutylpentane, F4H5; perfluorobutylhexane, F4H6, perfluorobutyloctane, F4H8; perfluorohexylethane, F6H2; perfluorohexylhexane, F6H6; and perfluorohexyloctane, F6H8) are experimentally determined over a wide temperature range (276 to 350 K). The corresponding surface thermodynamic properties and the critical temperatures of the studied compounds are estimated from the temperature dependence of the surface tension. Experimental density and vapour pressure data are employed to parameterize a generic heteronuclear coarse-grained intermolecular potential of the SAFT- γ family for PFAAs. The resulting force field is used in direct molecular dynamics simulations to predict with quantitative agreement the experimental tensions and to explore the conformations of the molecules in the interfacial region revealing a preferential alignment of the PFAA molecules towards the interface and an enrichment of the perfluoro-groups at the outer interface region
Generalized problematic internet use, emotional regulation and self-esteem in adults
Introduction: Many internationally studies, in the last two decades, found problematic internet use associated with a variety of psychosocial problems, but in Portugal this is a recent research question specially in adults. Objectives: To explore the relationship between problematic Internet use, emotional regulation and self-esteem. Methods: 138 Portuguese subjects (77.5% females), with a mean age of 27.76 years old (SD = 8.98, range: 18-58) filled in the Portuguese versions of the Generalized Problematic Internet Use Scale-2, the Difficulties in Emotion Regulation Scale and the Rosenberg Self-Esteem Scale. Results: Negative consequences subscale of generalized problematic internet use was positively correlated with all the emotional regulation difficulties subscales and negatively with Self-Esteem, and positively with daily hours of internet usage. A similar result was found for Self-Deficient Regulation subscale, except for Clarity subscale. Mood Regulation was correlated with Strategies, Goals and Self-Esteem. Males showed higher levels of Negative Consequences. Age and age onset of Internet use were negatively correlated with Mood Regulation, Self-Deficient Regulation and Negative Consequences. A statistically significant difference in Mood Regulation, Self-Deficient Regulation and Negative Consequences in marital status levels, and in professional situation, with higher median scores in divorced and single without a relationship and in student subjects; no significant differences were found in educational level. Conclusions: Generalized problematic Internet use, especially their Negative Consequences, is associated with higher emotional dysregulation, low self-esteem, lower age and lower age of Internet onset, being divorced or single without a relationship and being student, and it is more prevalent in males.info:eu-repo/semantics/publishedVersio
Anisotropic Energy Distribution in Three-Dimensional Vibrofluidized Granular Systems
We examine the energy distribution in a three-dimensional model granular
system contained in an open cylinder under the influence of gravity. Energy is
supplied to the system by a vibrating base. We introduce spatially resolved,
partial particle-particle ``dissipations'' for directions parallel and
perpendicular to the energy input, respectively. Energy balances show that the
total (integrated) ``dissipation'' is less than zero in the parallel direction
while greater than zero in the perpendicular directions. The energy supplied to
the perpendicular directions is dissipated by particle-wall collisions. We
further define a fractional energy transfer, which in the steady state
represents the fraction of the power supplied by the vibrating base that is
dissipated at the wall. We examine the dependence of the fractional energy
transfer on the number of particles, the velocity of the vibrating base, the
particle-particle restitution coefficient, and the particle-wall restitution
coefficient. We also explore the influence of the system parameters on the
spatially dependent partial dissipations.Comment: 10 pages, 10 figures, RevTeX forma
Correlation and power distribution of intercore crosstalk field components of polarization-coupled weakly coupled single-mode multicore fibres
The correlation and power distribution of intercore crosstalk (ICXT) field components of weakly coupled multicore fibers (WC-MCFs) are important properties that determine the statistics of the ICXT and ultimately impact the performance of WC-MCF optical communication systems. Using intensive numerical simulation of the coupled mode equations describing ICXT of a single-mode WC-MCF with intracore birefringence and linear propagation, we assess the mean, correlation, and power distribution of the four ICXT field components of unmodulated polarization-coupled homogeneous and quasi-homogeneous WC-MCFs with a single interfering core in a wide range of birefringence conditions and power distribution among the field components at the interfering core input. It is shown that, for homogeneous and quasi-homogeneous WC-MCFs, zero mean uncorrelated ICXT field components with similar power levels are observed for birefringence correlation length and birefringence beat length in the ranges of [0.5 m, 10 m] and [0.1 m, 10 m], respectively, regardless of the distribution of power between the four field components at the interfering core input.info:eu-repo/semantics/publishedVersio
The Static and Dynamic Transfer-Matrix Methods in the Analysis of Distributed-Feedback Lasers
Coworking in Lisbon: Experiences of collaboration and sharing on changing urban contexts
As innovative and creative ecosystems, Coworking Spaces (CWS) show high adaptability and recovery capacity in facing global event disruptions. This article is an exploratory study that aims to approach the development of coworking spaces in the city of Lisbon. It investigates the location patterns and adaptation of such ecosystems in Lisbon, by mapping the phenomenon and examining its spatio-temporal dynamics that was influenced by the urbanisation phases of the city, as well as the development and planning policies designed over the years. Starting from a broader view of CWS location in the city, this article moves on to present two particular cases, implemented in a different time and socio-economic circumstances in different parts of the city: LxFactory and The Creative Hub. This study is part of a broader contribution to COST Action (CA)18214 "The geography of the new workspaces and the impact on the periphery".info:eu-repo/semantics/publishedVersio
Efficacy of Aliskiren/Hydrochlorothiazide Combination for the Treatment of Hypertension: A Meta-Analytical Approach
Background: Single-pill combinations of aliskiren/hydrochlorothiazide have recently been approved by the
European Medicines Agency for the treatment of hypertension.
Objective: This study aimed to assess the antihypertensive efficacy of aliskiren/hydrochlorothiazide combination in
reducing systolic and diastolic blood pressure in hypertensive patients.
Methods: A search in International Pharmaceutical Abstracts, MEDLINE, The Cochrane Library and ISI Web of Knowledge
was performed from 2000 to November 2009, to identify randomized, double-blind, clinical trials using
aliskiren/hydrochlorothiazide for the treatment of hypertension. Studies were included if they evaluated the antihypertensive
efficacy of aliskiren/hydrochlorothiazide in patients with mild or moderate essential hypertension and age 18 years.
The meta-analytical approach calculated the weighted average reductions of systolic and diastolic blood pressure for each
daily dosage combination.
Results: We included 5 clinical trials testing several combinations of aliskiren/hydrochlorothiazide and containing data on
5448 patients. In all studies blood pressure was assessed at inclusion (baseline) and after 8 weeks of therapy. Blood pressure
reductions and control rates were significantly (p < 0.05) higher with the aliskiren/hydrochlorothiazide combinations
than with placebo and the same doses of aliskiren or hydrochlorothiazide alone. The weighted mean reductions (mm Hg)
from baseline of systolic and diastolic blood pressure for each aliskiren/hydrochlorothiazide combination were: -15.8/-
10.3 (150/25 mg); -15.9/-11.8 (300/12.5 mg); -16.9/-11.6 (300/25 mg). Blood pressure control rates (%) for the above
combinations were, at least, respectively: 43.8, 50.1 and 51.9.
Conclusions: Aliskiren/hydrochlorothiazide provided clinically significant additional blood pressure reductions and
improved blood pressure control rates over aliskiren or hydrochlorothiazide monotherapy.We thank the Fundação para a Ciência e a Tecnologia
(FCT) for supporting the fellowship grant SFRH/BD/36756/
2007 to Manuel Morgado
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