Ultrafast Intramolecular Charge Transfer of Formyl Perylene Observed Using Femtosecond Transient Absorption Spectroscopy

The excited-state photophysics of formylperylene (FPe) have been investigated in a series of nonpolar, polar aprotic, and polar protic solvents. A variety of experimental and theoretical methods were employed including femtosecond transient absorption (fs-TA) spectroscopy with 130 fs temporal resolution. We report that the ultrafast intramolecular charge transfer from the perylene unit to the formyl (CHO) group can be facilitated drastically by hydrogen-bonding interactions between the carbonyl group oxygen of FPe and hydrogen-donating solvents in the electronically excited state. The excited-state absorption of FPe in methanol (MeOH) is close to the reported perylene radical cation produced by bimolecular quenching by an electron acceptor. This is a strong indication for a substantial charge transfer in the S1 state in protic solvents. The larger increase of the dipole moment change in the protic solvents than that in aprotic ones strongly supports this observation. Relaxation mechanisms including vibrational cooling and solvation coupled to the charge-transfer state are also discussed

Soliton dynamics in gas-filled hollow-core photonic crystal fibers

Gas-filled hollow-core photonic crystal fibers offer unprecedented opportunities to observe novel nonlinear phenomena. The various properties of gases that can be used to fill these fibers give additional degrees of freedom for investigating nonlinear pulse propagation in a wide range of different media. In this review, we will consider some of the the new nonlinear interactions that have been discovered in recent years, in particular those which are based on soliton dynamics

Soliton-radiation trapping in gas-filled photonic crystal fibers

We propose an optical trapping technique in which a fundamental soliton traps an ultrashort small amplitude radiation in a symmetric hollow-core photonic crystal fiber filled with a noble gas, preventing its dispersion. The system is Raman- and plasma-free. Trapping is due to the cross phase modulation effect between the two pulses. The trapped radiation inside the soliton-induced potential will oscillate periodically due to the shock effect, similar to the motion of a mechanical pendulum. DOI: 10.1103/PhysRevA.87.04380

Trapped Bose-Einstein condensates in the presence of a current nonlinearity

We investigate the effect of a current nonlinearity on the evolution of a trapped atomic Bose-Einstein condensate. We have implemented techniques from the field of nonlinear optics to provide new insights into the irregular dynamics associated with chiral superfluids. We have found that the current nonlinearity can be treated as a Kerr-like nonlinearity modulated by a spatiotemporal function that can lead to a number of processes such as broadening and compression of the wave function. In the long time scale limit, the wave function is drastically deformed and delocalised compared to its initial state. However, localised modes which oscillate with the period of the inverse trap frequency can still be observed.Comment: A short note on the links between nonlinear gauge potentials and nonlinear optics. Comments are welcom

Sidelobe Control in Collaborative Beamforming via Node Selection

Collaborative beamforming (CB) is a power efficient method for data communications in wireless sensor networks (WSNs) which aims at increasing the transmission range in the network by radiating the power from a cluster of sensor nodes in the directions of the intended base station(s) or access point(s) (BSs/APs). The CB average beampattern expresses a deterministic behavior and can be used for characterizing/controling the transmission at intended direction(s), since the mainlobe of the CB beampattern is independent on the particular random node locations. However, the CB for a cluster formed by a limited number of collaborative nodes results in a sample beampattern with sidelobes that severely depend on the particular node locations. High level sidelobes can cause unacceptable interference when they occur at directions of unintended BSs/APs. Therefore, sidelobe control in CB has a potential to increase the network capacity and wireless channel availability by decreasing the interference. Traditional sidelobe control techniques are proposed for centralized antenna arrays and, therefore, are not suitable for WSNs. In this paper, we show that distributed, scalable, and low-complexity sidelobe control techniques suitable for CB in WSNs can be developed based on node selection technique which make use of the randomness of the node locations. A node selection algorithm with low-rate feedback is developed to search over different node combinations. The performance of the proposed algorithm is analyzed in terms of the average number of trials required to select the collaborative nodes and the resulting interference. Our simulation results approve the theoretical analysis and show that the interference is significantly reduced when node selection is used with CB.Comment: 30 pages, 10 figures, submitted to the IEEE Trans. Signal Processin

Optimum design of composite prestressed concrete girder railway bridges

This paper deals with the formulation of design optimisation of pretsressed concrete bridges. The bridge is of a slab-on-girder type, hence modeled as an equivalent orthotropic plate. The whole bridge system is considered as a simply supported right angle plate. Following linear elastic behaviour, the governing fourth order differential equation of the plate for patch load is solved in order to find out load distribution on the girders forming the bridge as well as the deflections and internal forces at critical sections of the whole bridge. The optimisation problem is formulated for various cross sectional geometries including rectangular, symmetrical I, unsymmetrical I, box, T and inverted T sections. The design variables are the main cross sectional dimensions, prestressing force and tendon eccentricity. The objective function comprises the cost of concrete material, formwork and prestressing steel tendons. The constraint functions are set to satisfy design requirements as per British Standards for bridges (BS 5400). Nonlinear optimisation method based on sequential unconstrained minimisation technique (SUMT) is employed to achieve optimum bridge configuration for specific design parameters of span length, concrete compressive strength and railway loading patterns. A purpose built computer program is set up to carry out the solution of the design optimisation problem efficiently in terms of time and effort. A typical example of unsymmetrical I-section having a small bottom flange as compared to the top flange width with composite deck effect is presented. The results show that the total cost increases as the span increases due to the increase of the initial prestressing force. Furthermore, the total cost decreases as the concrete compressive strength increases in spite of the increasing of the prestressing force. This is due to decrease of the overall depth, top and bottom flange widths, hence leading to a smaller girder size. Such finding will encourage engineers to adopt high strength concrete for bridges as it will help reducing not only the initial cost but also the life cycle cost of the bridge over its entire life

Strong Raman-induced non-instantaneous soliton interactions in gas-filled photonic crystal fibers

We have developed an analytical model based on the perturbation theory in order to study the optical propagation of two successive intense solitons in hollow-core photonic crystal fibers filled with Raman-active gases. Based on the time delay between the two solitons, we have found that the trailing soliton dynamics can experience unusual nonlinear phenomena such as spectral and temporal soliton oscillations and transport towards the leading soliton. The overall dynamics can lead to a spatiotemporal modulation of the refractive index with a uniform temporal period and a uniform or chirped spatial period