TiAIN based nanoscale multilayer coatings designed to adapt their tribological properties at elevated temperatures

The addition of properly selected elements, coupled in nanoscale multilayer structures, can further enhance the properties of TiAlN coatings and bring new high performance. The incorporation of Y in the nanoscale pseudo-superlattice TiAlCrN/TiAlYN with typical period of 1.7 nm not only improves the oxidation resistance but also effectively reduces the coefficient of friction of the coating from 0.9 to 0.65 at temperatures in the range of 850–950 °C. The adaptation of the tribological properties occurs as a result of the preferential migration of the Y to the column boundaries. TiAlN/VN superlattice can achieve another self-adaptation process. During friction the coatings adapt themselves to the combined thermal and mechanical wear by the formation of highly lubricious vanadium-oxides due to high flash temperatures at the asperity contacts on the surface. The integrity of the bulk of the coating is retained, leading to exceptionally low, for superhard coatings, friction coefficient of 0.5 and a wear coefficient of 2 × 10−17 m3·N−1·m−1. The coatings have been deposited by the combined steered cathodic arc unbalanced magnetron sputtering method.</p

Elastic constants of fibre-textured thin films determined by X-ray diffraction

Supposing the Hill grain-interaction model, it is demonstrated that X-ray elastic constants can be used to determine mechanical elastic constants of cubic fibre-textured thin films. The new approach is demonstrated by the experimental characterization of out-of-plane moduli of fibre-textured Cu and CrN thin films

Stroop dilution but not word-processing dilution : evidence for attention capture

Stroop dilution refers to the observation that the impact of a color word on the naming of a color bar is reduced if another word-like object is displayed simultaneously. Recently, Brown, Roos-Gilbert, and Carr (1995) concluded that Stroop dilution is due to early-visual interference. This conclusion was evaluated in three experiments. Experiment 1 showed that, contrary to the predictions of an early-visual interference account, (a) diluters that are similar in terms of visual complexity induced different amounts of dilution and (b) the size of the dilution effect is proportional to the size of the Stroop interference effect when the diluters are used as single distractors. Experiments 2 and 3 revealed that when the position of the color bar is pre-cued, Stroop dilution disappears. We argue that these findings support Van der Heijden’s (1992) attention-capture account of Stroop dilution.The first author was supported by a grant of the Westfalisch-Lippische Universitatsgesellschaft, Biefeld, Germany.peer-reviewe

Structure-property relations in ZrCN coatings for tribologic applications

ZrCN coatings were deposited by dc reactive magnetron sputtering with N2 flows ranging from 2 to 10 sccm in order to investigate the influence of the nitrogen incorporation on structure and properties. Information about the chemical composition was obtained by glow discharge optical emission spectroscopy and Rutherford backscattering spectroscopy. The evolution of the crystal structure studied by X-ray diffraction revealed the formation of a face-centred cubic ZrCN phase for N2 flows greater than 4 sccm. Additionally, the presence of an amorphous phase in the coatings deposited with the highest N2 flows could be evidenced by Raman spectroscopy and X-ray photoelectron spectroscopy. This phase can act as a lubricant resulting in a low coefficient of friction as shown in the conducted ball-on-disc tests. Nanoindentation measurements showed that coatings deposited with a 6 sccm N2 flow had the maximum hardness which also revealed the best performance in the conducted dry cutting tests.CRUP InstitutionSpanish Ministry of Science and InnovationChristian Doppler Research Associatio

Effects of Place of Articulation Changes on Auditory Neural Activity: A Magnetoencephalography Study

In casual speech, phonemic segments often assimilate such that they adopt features from adjacent segments, a typical feature being their place of articulation within the vocal tract (e.g., labial, coronal, velar). Place assimilation (e.g., from coronal /n/ to labial /m/: rainbow→*raimbow) alters the surface form of words. Listeners' ability to perceptually compensate for such changes seems to depend on the phonemic context, on whether the adjacent segment (e.g., the /b/ in “rainbow”) invites the particular change. Also, some assimilations occur frequently (e.g., /n/→/m/), others are rare (e.g., /m/→/n/). We investigated the effects of place assimilation, its contextual dependency, and its frequency on the strength of auditory evoked mismatch negativity (MMN) responses, using pseudowords. Results from magnetoencephalography (MEG) revealed that the MMN was modulated both by the frequency and contextual appropriateness of assimilations

Description and discrimination of freshness and biometric qualities of three different fishes: Grass carp, pacu, and catfish

The goal of this work was to wade into the freshness quality and biometric evaluation, by means of distinct statistical descriptive methods, on three fresh catch species of fish, as well as to evaluate the discriminant potential of the variables targeted in the study. The species grass carp (Ctenopharyngodon idella), pacu (Piaractus mesopotamicus), and catfish (Ictalurus punctatus) were caught at a rural property located in the city of Pato Branco, PR, Brazil. These fresh catch were weighed, measured, eviscerated, and cut into fillets for acquisition of biometric parameters. Freshness was judged by the analysis of the total volatile basic nitrogen (TVB-N) value and pH. The comparison between means and medians showed symmetries for biometric measures. Correlations between body measures and fillet yield showed a weak relation regardless of the species analysed, wherein the best equation for predictions was obtained by relating total weight to the fillet's weight. The biometric variables were the best discriminants for the species

Synthesis of bulk reactive Ni-Al composites using high pressure torsion

17 USC 105 interim-entered record; under review.The article of record as published may be found at http://dx.doi.org/10.1016/j.jallcom.2020.157503Self-propagating exothermic reactions, for instance in the nickel-aluminum (Ni-Al) system, have been widely studied to create high performance intermetallic compounds or for in-situ welding. Their easy ignition once the phase spacing is reduced below the micron scale, makes top-down methods like high energy ball milling, ideal to fabricate such reactive nanostructures. A major drawback of ball milling is the need of a sintering step to form bulk pieces of the reactive material. However, this is not possible, as the targeted reactions would already proceed. Therefore, we investigate the ability of high pressure torsion as an alternative process, capable to produce bulk nanocomposites from powder mixtures. Severe straining of powder mixtures with a composition of 50 wt% Ni and 50 wt% Al enables fabrication of self reactive bulk samples with microstructures similar to those obtained from ball milling or magnetron sputtering. Samples deformed at ambient temperature are highly reactive and can be ignited signifi cantly below the Al melting point, finally predominantly consisting of Al3Ni2 and Al3Ni, independent of the applied strain. Although the reaction proceeds first at the edge of the disk, the strain gradient present in the disks does not prevent reaction of the whole sample.COMETAustrian Federal MinistriesDepartment of Energy National Nuclear Security AdministrationERC Advanced Grant INTELHYBCOMET programERC-2013-ADG-340025DENA0002377Project No 859480DE-AC02-06CH1135

Spatial consistency and bias in avalanche forecasts – a case study in the European Alps

In the European Alps, the public is provided with regional avalanche forecasts, issued by about 30 forecast centers throughout the winter, covering a spatially contiguous area. A key element in these forecasts is the communication of avalanche danger according to the five-level, ordinal European Avalanche Danger Scale (EADS). Consistency in the application of the avalanche danger levels by the individual forecast centers is essential to avoid misunderstandings or misinterpretations by users, particularly those utilizing bulletins issued by different forecast centers. As the quality of avalanche forecasts is difficult to verify, due to the categorical nature of the EADS, we investigated forecast goodness by focusing on spatial consistency and bias, exploring real forecast danger levels from four winter seasons (477 forecast days). We describe the operational constraints associated with the production and communication of the avalanche bulletins, and we propose a methodology to quantitatively explore spatial consistency and bias. We note that the forecast danger level agreed significantly less often when compared across national and forecast center boundaries (about 60&thinsp;%) than within forecast center boundaries (about 90&thinsp;%). Furthermore, several forecast centers showed significant systematic differences in terms of more frequently using lower (or higher) danger levels than their neighbors. Discrepancies seemed to be greatest when analyzing the proportion of forecasts with danger level 4 – high and 5 – very high. The size of the warning regions, the smallest geographically clearly specified areas underlying the forecast products, differed considerably between forecast centers. Region size also had a significant impact on all summary statistics and is a key parameter influencing the issued danger level, but it also limits the communication of spatial variations in the danger level. Operational constraints in the production and communication of avalanche forecasts and variation in the ways the EADS is interpreted locally may contribute to inconsistencies and may be potential sources for misinterpretation by forecast users. All these issues highlight the need to further harmonize the forecast production process and the way avalanche hazard is communicated to increase consistency and hence facilitate cross-border forecast interpretation by traveling users.</p