Standing Swells Surveyed Showing Surprisingly Stable Solutions for the Lorenz '96 Model

The Lorenz '96 model is an adjustable dimension system of ODEs exhibiting chaotic behavior representative of dynamics observed in the Earth's atmosphere. In the present study, we characterize statistical properties of the chaotic dynamics while varying the degrees of freedom and the forcing. Tuning the dimensionality of the system, we find regions of parameter space with surprising stability in the form of standing waves traveling amongst the slow oscillators. The boundaries of these stable regions fluctuate regularly with the number of slow oscillators. These results demonstrate hidden order in the Lorenz '96 system, strengthening the evidence for its role as a hallmark representative of nonlinear dynamical behavior.Comment: 10 pages, 8 figure

Micromechanical investigation of fines liberation and transport during coal seam dewatering

The reduction of subsurface hydrostatic pressure to allow natural gas desorption is an integral step in the production of coal seam gas (CSG). During this dewatering stage, viscous stresses can cause the liberation and transport of fines, which are predominantly comprised of inorganic clay groups such as smectite, illite and kaolin, from within the coal matrix. Dislodged particles migrate in production fluid through fractures towards the wellbore where capture and deposition can deteriorate the reservoir's permeability. Once in the wellbore, these particles can adversely affect the performance of mechanical equipment such as pumps. This study uses direct numerical simulation of a synthetic coal fracture to help elucidate the particle detachment process. This is approached using a coupled lattice Boltzmann-discrete element method to capture both physical and physicochemical interactions based on Derjaguin-Landau-Verwey-Overbeek (DLVO) theory. Preliminary testing with the developed model suggests that particles move almost freely along the bounding surface regardless of electrostatic interactions, and that Hele-Shaw predictions of particle lift in particular can be inadequate. Further, larger-scale simulations indicated that the DLVO parameters can significantly impact the vertical position of propagating fines with variations in eroded mass of over 100% observed for the range of tested salinity levels

Structure/activity relationships applied to the hydrogenation of α,β-unsaturated carbonyls: The hydrogenation of 3-butyne-2-one over alumina-supported palladium catalysts

The gas phase hydrogenation of 3-butyne-2-one, an alkynic ketone, over two alumina-supported palladium catalysts is investigated using infrared spectroscopy in a batch reactor at 373 K. The mean particle size of the palladium crystallites of the two catalysts are comparable (2.4 ± 0.1 nm). One catalyst (Pd(NO3)2/Al2O3) is prepared from a palladium(II) nitrate precursor, whereas the other catalyst (PdCl2/Al2O3) is prepared using palladium(II) chloride as the Pd precursor compound. A three-stage sequential process is observed with the Pd(NO3)2/Al2O3 catalyst facilitating complete reduction all the way through to 2-butanol. However, hydrogenation stops at 2-butanone with the PdCl2/Al2O3 catalyst. The inability of the PdCl2/Al2O3 catalyst to reduce 2-butanone is attributed to the inaccessibility of edge sites on this catalyst, which are blocked by chlorine retention originating from the catalyst’s preparative process. The reaction profiles observed for the hydrogenation of this alkynic ketone are consistent with the site-selective chemistry recently reported for the hydrogenation of crotonaldehyde, an alkenic aldehyde, over the same two catalysts. Thus, it is suggested that a previously postulated structure/activity relationship may be generic for the hydrogenation of α,β-unsaturated carbonyl compounds over supported Pd catalysts

A change in temperature modulates defence to yellow (stripe) rust in wheat line UC1041 independently of resistance gene Yr36

Background Rust diseases are of major importance in wheat production worldwide. With the constant evolution of new rust strains and their adaptation to higher temperatures, consistent and durable disease resistance is a key challenge. Environmental conditions affect resistance gene performance, but the basis for this is poorly understood. Results Here we show that a change in day temperature affects wheat resistance to Puccinia striiformis f. sp tritici (Pst), the causal agent of yellow (or stripe) rust. Using adult plants of near-isogenic lines UC1041 +/- Yr36, there was no significant difference between Pst percentage uredia coverage in plants grown at day temperatures of 18°C or 25°C in adult UC1041 + Yr36 plants. However, when plants were transferred to the lower day temperature at the time of Pst inoculation, infection increased up to two fold. Interestingly, this response was independent of Yr36, which has previously been reported as a temperature-responsive resistance gene as Pst development in adult UC1041 -Yr36 plants was similarly affected by the plants experiencing a temperature reduction. In addition, UC1041 -Yr36 plants grown at the lower temperature then transferred to the higher temperature were effectively resistant and a temperature change in either direction was shown to affect Pst development up to 8 days prior to inoculation. Results for seedlings were similar, but more variable compared to adult plants. Enhanced resistance to Pst was observed in seedlings of UC1041 and the cultivar Shamrock when transferred to the higher temperature. Resistance was not affected in seedlings of cultivar Solstice by a temperature change in either direction. Conclusions Yr36 is effective at 18°C, refining the lower range of temperature at which resistance against Pst is conferred compared to previous studies. Results reveal previously uncharacterised defence temperature sensitivity in the UC1041 background which is caused by a change in temperature and independently of Yr36. This novel phenotype is present in some cultivars but absent in others, suggesting that Pst defence may be more stable in some cultivars than others when plants are exposed to varying temperatures

Development OF A Multi-Scale Framework for Mapping Global Evapotranspiration

As the worlds water resources come under increasing tension due to dual stressors of climate change and population growth, accurate knowledge of water consumption through evapotranspiration (ET) over a range in spatial scales will be critical in developing adaptation strategies. Remote sensing methods for monitoring consumptive water use (e.g, ET) are becoming increasingly important, especially in areas of significant water and food insecurity. One method to estimate ET from satellite-based methods, the Atmosphere Land Exchange Inverse (ALEXI) model uses the change in mid-morning land surface temperature to estimate the partitioning of sensible and latent heat fluxes which are then used to estimate daily ET. This presentation will outline several recent enhancements to the ALEXI modeling system, with a focus on global ET and drought monitoring

Trapping of magnetic flux by the plunge region of a black hole accretion disk

The existence of the radius of marginal stability means that accretion flows around black holes invariably undergo a transition from a MHD turbulent disk-like flow to an inward plunging flow. We argue that the plunging inflow can greatly enhance the trapping of large scale magnetic field on the black hole, and therefore may increase the importance of the Blandford-Znajek (BZ) effect relative to previous estimates that ignore the plunge region. We support this hypothesis by constructing and analyzing a toy-model of the dragging and trapping of a large scale field by a black hole disk, revealing a strong dependence of this effect on the effective magnetic Prandtl number of the MHD turbulent disk. Furthermore, we show that the enhancement of the BZ effect depends on the geometric thickness of the accretion disk. This may be, at least in part, the physical underpinnings of the empirical relation between the inferred geometric thickness of a black hole disk and the presence of a radio jet.Comment: 18 pages, 3 figures, accepted for publication in the Astrophysical Journal. See http://www.astro.umd.edu/~chris/publications/movies/flux_trapping.html for animation

Happiness and the patterns of life: A study of geolocated tweets

The patterns of life exhibited by large populations have been described and modeled both as a basic science exercise and for a range of applied goals such as reducing automotive congestion, improving disaster response, and even predicting the location of individuals. However, these studies have had limited access to conversation content, rendering changes in expression as a function of movement invisible. In addition, they typically use the communication between a mobile phone and its nearest antenna tower to infer position, limiting the spatial resolution of the data to the geographical region serviced by each cellphone tower. We use a collection of 37 million geolocated tweets to characterize the movement patterns of 180,000 individuals, taking advantage of several orders of magnitude of increased spatial accuracy relative to previous work. Employing the recently developed sentiment analysis instrument known as the hedonometer, we characterize changes in word usage as a function of movement, and find that expressed happiness increases logarithmically with distance from an individual\u27s average location

An introduction to communicating science

It is becoming increasingly recognised that students in Higher Education must acquire the skills necessary for professional and personal development, as well as for academic progress. The media have recently focused on the issue of declining public interest in the sciences and the lack of accurate reporting of science. We have developed a new programme, which endeavours to address both issues involving a three day intensive course covering writing, TV and radio. In addition to the targeted activities of learning the skills of science communication, the programme encourages partnerships, and exploits the resources and expertise available from various institutions. The undertaking of this type of programme is not limited to the acquisition of time slots in a studio such as Bush House. Most university campuses are now home to their own recording studios and even have television facilities. However, the programme requires only a video camera and audio recording equipment. The success of this science communication module and oftwo others run by MOAC and CBC (Team Development and Decision-making and Leadership) has encouraged us to develop a complete postgraduate certificate in transferable skills. We anticipate the certificate will be a valuable vehicle for consolidating and enhancing the training discussed in this article

Shocks and sonic booms in the intracluster medium: X-ray shells and radio galaxy activity

Motivated by hydrodynamic simulations, we discuss the X-ray appearance of radio galaxies embedded in the intracluster medium (ICM) of a galaxy cluster. We distinguish three regimes. In the early life of a powerful source, the entire radio cocoon is expanding supersonically and hence drives a strong shock into the ICM. Eventually, the sides of the cocoon become subsonic and the ICM is disturbed by the sonic booms of the jet's working surface. In both of these regimes, X-ray observations would find an X-ray shell. In the strong shock regime, this shell will be hot and relatively thin. However, in the weak shock (sonic-boom) regime, the shell will be approximately the same temperature as the undisturbed ICM. If a cooling flow is present, the observed shell may even be cooler than the undisturbed ICM due to the lifting of cooler material into the shell from the inner (cooler) regions of the cluster. In the third and final regime, the cocoon has collapsed and no well-defined X-ray shell will be seen. We discuss ways of estimating the power and age of the source once its regime of behavior has been determined.Comment: 4 pages, submitted for publication in Astrophysical Journal. Full paper (including figure) can be obtained from http://rocinante.Colorado.EDU/~chris/papers/xray_hydro.p