Excitation and relaxation dynamics in ultrafast laser irradiated optical glasses

We discuss the dynamics of ultrashort pulsed laser excitation in bulk optical silica-based glasses (fused silica and borosilicate BK7) well-above the permanent modification threshold. We indicate subsequent structural and thermomechanical energy relaxation paths that translate into positive and negative refractive index changes, compression and rarefaction zones. If fast electronic decay occurs at low excitation levels in fused silica via self-trapping of excitons, for carrier densities in the vicinity of the critical value at the incident wavelength, persistent long-living absorptive states indicate the achievement of low viscosity matter states manifesting pressure relaxation, rarefaction, void opening and compaction in the neighboring domains. An intermediate ps-long excited carrier dynamics is observed for BK7 in the range corresponding to structural expansion and rarefaction. The amount of excitation and the strength of the subsequent hydrodynamic evolution is critically dependent on the pulse time envelope, indicative of potential optimization schemes

Ultrashort pulse laser cutting of glass by controlled fracture propagation

International audienceLaser induced controlled fracture propagation has great potential in cutting brittle materials such as glass or sapphire. In this paper we demonstrate that the use of ultrashort pulse laser sources may be advantageous since it allows to overcome several restrictions of the convenient method

Rapid assessment of nonlinear optical propagation effects in dielectrics

Ultrafast laser processing applications need fast approaches to assess the nonlinear propagation of the laser beam in order to predict the optimal range of processing parameters in a wide variety of cases. We develop here a method based on the simple monitoring of the nonlinear beam shaping against numerical prediction. The numerical code solves the nonlinear Schrödinger equation with nonlinear absorption under simplified conditions by employing a state-of-the art computationally efficient approach. By comparing with experimental results we can rapidly estimate the nonlinear refractive index and nonlinear absorption coefficients of the material. The validity of this approach has been tested in a variety of experiments where nonlinearities play a key role, like spatial soliton shaping or fs-laser waveguide writing. The approach provides excellent results for propagated power densities for which free carrier generation effects can be neglected. Above such a threshold, the peculiarities of the nonlinear propagation of elliptical beams enable acquiring an instantaneous picture of the deposition of energy inside the material realistic enough to estimate the effective nonlinear refractive index and nonlinear absorption coefficients that can be used for predicting the spatial distribution of energy deposition inside the material and controlling the beam in the writing process

Ultrafast laser micro-nano structuring of transparent materials with high aspect ratio

Ultrafast lasers are ideal tools to process transparent materials because they spatially confine the deposition of laser energy within the material's bulk via nonlinear photoionization processes. Nonlinear propagation and filamentation were initially regarded as deleterious effects. But in the last decade, they turned out to be benefits to control energy deposition over long distances. These effects create very high aspect ratio structures which have found a number of important applications, particularly for glass separation with non-ablative techniques. This chapter reviews the developments of in-volume ultrafast laser processing of transparent materials. We discuss the basic physics of the processes, characterization means, filamentation of Gaussian and Bessel beams and provide an overview of present applications

Bond-breaking mechanism of vitreous silica densification by IR femtosecond laser pulses

The densification of the vitreous silica (v-SiO2) due to laser irradiation appears reasonable to cause the change in refractive index. In this letter, the v-SiO2 densification under IR femtosecond laser irradiation is studied within molecular-dynamics simulation. The single- and multi-pulse interactions are explored numerically with an account of the bond-breaking mechanism. By analyzing the network at nanoscale, the nature of v-SiO2 densification is assigned to the reduction of major ring fractions of six- and seven-membered rings to minor fractions of three- and four-membered rings (related to D2 and D1 Raman signatures, respectively). The athermal behavior of v-SiO2 densification is disclosed at different degrees of ionization for both the single- and multi-pulse cases at sub-threshold regimes. The good agreement between calculated and measured D2 defect line and Si-O-Si angle changes argues in favor of the found mechanism

Optimization of the energy deposition in glasses with temporally-shaped femtosecond laser pulses

Bulk machining of glasses with femtosecond laser pulses enables the fabrication of embedded optical functions. Due to the nonlinear character of the laser-matter interaction, structural modifications can occur within the focal region. To reach a full control of the process, ways of controlling the deposition of the laser energy inside the material have to be unveiled. From static and time-resolved pictures of bulk-excitation of a-SiO2 and borosilicate glass, we show that particular laser temporal shapes such as picosecond sequences can better confine the energy deposition than the femtosecond sequence by reducing the propagation artifacts

Investigation and control of ultrafast laser-induced isotropic and anisotropic nanoscale-modulated index patterns in bulk fused silica

Ultrafast laser-induced refractive index changes in a-SiO2 consist, depending on the irradiation conditions, of either positive variations, voids, or regular nanoscale patterns, each of these underlying specific structural transformations. These allow for obtaining a large palette of optical functions ranging from low loss guiding to anisotropic scattering. While briefly reviewing the excitation mechanisms, we spectroscopically interrogate local electronic and structural transformations of the glass in the isotropic index zones and in the regular self-organized nanostructures, indicating bond breaking and matrix oxygen deficiency. A spatial defect segregation marks the material transformation in the different photoinscription regimes. We equally propose a method of real time control of nanogratings formation under the action of ultrashort laser pulse with variable envelopes. Application as polarizing optical devices is discussed. (C) 2013 Optical Society of Americ

Femtosecond laser processing of silver-containing glass with optical vortex beams

We report on vortex-assisted femtosecond direct laser writing (DLW) in silver-containing phosphate glasses with complex light fields endowed with optical phase singularities. This allows us to engrave complex patterns showing sub-wavelength dimensions. The associated linear and nonlinear optical properties show remarkably correlated but distinct spatial distributions. The creation of a perennial buried electric field leads to an efficient electric- field induced second harmonic generation. The magnitude and distribution of such buried field is also considered to actively drive the pattern topology of the fluorescent silver clusters. Using DLW with phase and amplitude engineered beams, we demonstrate a promising approach to control both fluorescent and nonlinear responses below the diffraction limit

Thermo-elasto-plastic simulations of femtosecond laser-induced multiple-cavity in fused silica

The formation and the interaction of multiple cavities, induced by tightly focused femtosecond laser pulses, are studied using a developed numerical tool, including the thermo-elasto-plastic material response. Simulations are performed in fused silica in cases of one, two, and four spots of laser energy deposition. The relaxation of the heated matter, launching shock waves in the surrounding cold material, leads to cavity formation and emergence of areas where cracks may be induced. Results show that the laser-induced structure shape depends on the energy deposition configuration and demonstrate the potential of the used numerical tool to obtain the desired designed structure or technological process