Quantum Markovian activated surface diffusion of interacting adsorbates

A quantum Markovian activated atom-surface diffusion model with interacting adsorbates is proposed for the intermediate scattering function, which is shown to be complex-valued and factorizable into a classical-like and a quantum-mechanical factor. Applications to the diffusion of Na atoms on flat (weakly corrugated) and corrugated-Cu(001) surfaces at different coverages and surface temperatures are analyzed. Quantum effects are relevant to diffusion at low surface temperatures and coverages even for relatively heavy particles, such as Na atoms, where transport by tunneling is absent.Comment: 6 pages, 4 figure

A causal look into the quantum Talbot effect

A well-known phenomenon in both optics and quantum mechanics is the so-called Talbot effect. This near field interference effect arises when infinitely periodic diffracting structures or gratings are illuminated by highly coherent light or particle beams. Typical diffraction patterns known as quantum carpets are then observed. Here the authors provide an insightful picture of this nonlocal phenomenon as well as its classical limit in terms of Bohmian mechanics, also showing the causal reasons and conditions that explain its appearance. As an illustration, theoretical results obtained from diffraction of thermal He atoms by both N-slit arrays and weak corrugated surfaces are analyzed and discussed. Moreover, the authors also explain in terms of what they call the Talbot-Beeby effect how realistic interaction potentials induce shifts and distortions in the corresponding quantum carpets.Comment: 12 pages, 6 figure

Quasi-elastic peak lineshapes in adsorbate diffusion on nearly flat surfaces at low coverages: the motional narrowing effect in Xe on Pt(111)

Quasi-elastic helium atom scattering measurements have provided clear evidence for a two-dimensional free gas of Xe atoms on Pt(111) at low coverages. Increasing the friction due to the surface, a gradual change of the shape of the quasi-elastic peak is predicted and analyzed for this system in terms of the so-called motional narrowing effect. The type of analysis presented here for the quasi-elastic peak should be prior to any deconvolution procedure carried out in order to better extract information from the process, e.g. diffusion coefficients and jump distributions. Moreover, this analysis also provides conditions for the free gas regime different than those reported earlier.Comment: 12 pages, 4 figures (revised version

Hydrodynamic View of Wave-Packet Interference: Quantum Caves

Wave-packet interference is investigated within the complex quantum Hamilton-Jacobi formalism using a hydrodynamic description. Quantum interference leads to the formation of the topological structure of quantum caves in space-time Argand plots. These caves consist of the vortical and stagnation tubes originating from the isosurfaces of the amplitude of the wave function and its first derivative. Complex quantum trajectories display counterclockwise helical wrapping around the stagnation tubes and hyperbolic deflection near the vortical tubes. The string of alternating stagnation and vortical tubes is sufficient to generate divergent trajectories. Moreover, the average wrapping time for trajectories and the rotational rate of the nodal line in the complex plane can be used to define the lifetime for interference features.Comment: 4 pages, 3 figures (major revisions with respect to the previous version have been carried out

Corona-Australis DANCe I. Revisiting the census of stars with Gaia-DR2 data

Context. Corona-Australis is one of the nearest regions to the Sun with recent and ongoing star formation, but the current picture of its stellar (and substellar) content is not complete yet. Aims. We take advantage of the second data release of the Gaia space mission to revisit the stellar census and search for additional members of the young stellar association in Corona-Australis. Methods. We applied a probabilistic method to infer membership probabilities based on a multidimensional astrometric and photometric data set over a field of 128 deg(2) around the dark clouds of the region. Results. We identify 313 high-probability candidate members to the Corona-Australis association, 262 of which had never been reported as members before. Our sample of members covers the magnitude range between G greater than or similar to 5 mag and G less than or similar to 20 mag, and it reveals the existence of two kinematically and spatially distinct subgroups. There is a distributed "off-cloud" population of stars located in the north of the dark clouds that is twice as numerous as the historically known "on-cloud" population that is concentrated around the densest cores. By comparing the location of the stars in the HR-diagram with evolutionary models, we show that these two populations are younger than 10 Myr. Based on their infrared excess emission, we identify 28 Class II and 215 Class III stars among the sources with available infrared photometry, and we conclude that the frequency of Class II stars (i.e. "disc-bearing" stars) in the on-cloud region is twice as large as compared to the off-cloud population. The distance derived for the Corona-Australis region based on this updated census is d = 149.4(-0.4)(+0.4) pc, which exceeds previous estimates by about 20 pc. Conclusions. In this paper we provide the most complete census of stars in Corona-Australis available to date that can be confirmed with Gaia data. Furthermore, we report on the discovery of an extended and more evolved population of young stars beyond the region of the dark clouds, which was extensively surveyed in the past

Quantum Zeno and anti-Zeno effects in surface diffusion of interacting adsorbates

Surface diffusion of interacting adsorbates is here analyzed within the context of two fundamental phenomena of quantum dynamics, namely the quantum Zeno effect and the anti-Zeno effect. The physical implications of these effects are introduced here in a rather simple and general manner within the framework of non-selective measurements and for two (surface) temperature regimes: high and very low (including zero temperature). The quantum intermediate scattering function describing the adsorbate diffusion process is then evaluated for flat surfaces, since it is fully analytical in this case. Finally, a generalization to corrugated surfaces is also discussed. In this regard, it is found that, considering a Markovian framework and high surface temperatures, the anti-Zeno effect has already been observed, though not recognized as such.Comment: 17 pages, 1 figur

Line Shape Broadening in Surface Diffusion of Interacting Adsorbates with Quasielastic He Atom Scattering

The experimental line shape broadening observed in adsorbate diffusion on metal surfaces with increasing coverage is usually related to the nature of the adsorbate-adsorbate interaction. Here we show that this broadening can also be understood in terms of a fully stochastic model just considering two noise sources: (i) a Gaussian white noise accounting for the surface friction, and (ii) a shot noise replacing the physical adsorbate-adsorbate interaction potential. Furthermore, contrary to what could be expected, for relatively weak adsorbate-substrate interactions the opposite effect is predicted: line shapes get narrower with increasing coverage.Comment: 4 pages, 2 figures (slightly revised version

Origin of the Electron-Phonon Interaction of Topological Semimetal Surfaces Measured with Helium Atom Scattering

He atom scattering has been demonstrated to be a sensitive probe of the electron-phonon interaction parameter $\lambda$ at metal and metal-overlayer surfaces. Here it is shown that the theory linking $\lambda$ to the thermal attenuation of atom scattering spectra (the Debye-Waller factor), can be applied to topological semimetal surfaces, like the quasi-one dimensional charge-density-wave system Bi(114) and the layered pnictogen chalcogenides

Setting up tunneling conditions by means of Bohmian mechanics

Usually tunneling is established after imposing some matching conditions on the (time-independent) wave function and its first derivative at the boundaries of a barrier. Here an alternative scheme is proposed to determine tunneling and estimate transmission probabilities in time-dependent problems, which takes advantage of the trajectory picture provided by Bohmian mechanics. From this theory a general functional expression for the transmission probability in terms of the system initial state can be reached. This expression is used here to analyze tunneling properties and estimate transmissions in the case of initial Gaussian wave packets colliding with ramp-like barriers.Comment: 18 pages, 4 figure