Substrate influence on the plasmonic response of clusters of spherical nanoparticles

The plasmonic response of nanoparticles is exploited in many subfields of science and engineering to enhance optical signals associated with probes of nanoscale and subnanoscale entities. We develop a numerical algorithm based on previous theoretical work that addresses the influence of a substrate on the plasmonic response of collections of nanoparticles of spherical shape. Our method is a real space approach within the quasi-static limit that can be applied to a wide range of structures. We illustrate the role of the substrate through numerical calculations that explore single nanospheres and nanosphere dimers fabricated from either a Drude model metal or from silver on dielectric substrates, and from dielectric spheres on silver substrates.Comment: 12 pages, 13 figure

Modelling of Electroluminescence in Polymers Using a Bipolar Charge Transport Model

Electroluminescence (EL) in polymeric materials is thought to occur due to the energy dissipation process from the recombination of opposite polarity charge carriers. It is considered as an indication of storage and transport of charge carriers in cable insulation subject to electrical stresses and may indicate the change in charge movement due to aging or degradation processes. Under ac electric fields, the interaction of opposite polarity charge carriers at the interface of polymer/conductor is enhanced compared with dc conditions, and seems to contribute a lot to the electroluminescence rather than the charge behaviours in the bulk of polymers. The dynamics of charge carriers both at the interface of polymer/conductor and in the bulk of polymers is investigated through a simulation work using a bipolar charge transport model. Figure 1 compares experimental electroluminescence results with simulated data from the recombination of injected charge carriers. The paper will give more details on EL model and comparison under various waveforms and frequencies

A Comparison between Electroluminescence Models and Experimental Results

Electrical insulation ages and degrades until its eventual failure under electrical stress. One cause of this relates to the movement and accumulation of charge within the insulation. The emission of a low level of light from polymeric materials while under electrical stressing occurs before the onset of currently detectable material degradation. This light is known as electroluminescence (EL) and under an ac electric field is thought to relate to the interaction of charge in close proximity to the electrode-polymer interface. Understanding the cause of this light emission gives a very high-resolution method of monitoring charge interaction and its influence on material ageing. A possible cause of this light emission is the bipolar charge recombination theory. This theory involves the injection, trapping and recombination of charge carriers during each half cycle of the applied field [1]. This work compares two models that to simulate the EL emission according to this bipolar charge recombination theory. Model 1 assumes a fixed space charge region and all injected charge is uniformly distributed in this region with charges able to either become trapped or to recombine with opposite polarity charge carriers [2]. This recombination relates directly the excitation needed for the emission of a photon of light as measured in experiments. Model 2 develops on this by accounting for the transport and extraction of charge with an exponential distribution of trap levels rather than a uniform distribution [3]. Figure 1 shows a good correlation between the two models and experimental data. The full paper will describe the models in more detail and present results comparing the simulated and experimental results under various applied waveforms. Model 1 and model 2 both provide a good correlation with experimental data but model 2 allows a greater understanding of the space charge profile in the region close to the electrodes as well as the shape of the conduction current. Further work involves developing these models to support changes in the charge trapping profiles due to material ageing and supporting simulated results with measured conduction current

Decay rate and other properties of the positronium negative ion

A new method for detecting the positronium minus ion is described, and the possibility of a long positronium mean free path in a solid is discussed

Efficient syntheses of climate relevant isoprene nitrates and (1R,5S)-(−)-myrtenol nitrate

Here we report the chemoselective synthesis of several important, climate relevant isoprene nitrates using silver nitrate to mediate a ’halide for nitrate’ substitution. Employing readily available starting materials, reagents and Horner–Wadsworth–Emmons chemistry the synthesis of easily separable, synthetically versatile ‘key building blocks’ (E)- and (Z)-3-methyl-4-chlorobut-2-en-1-ol as well as (E)- and (Z)-1-((2-methyl-4-bromobut-2-enyloxy)methyl)-4-methoxybenzene has been achieved using cheap, ’off the shelf’ materials. Exploiting their reactivity we have studied their ability to undergo an ‘allylic halide for allylic nitrate’ substitution reaction which we demonstrate generates (E)- and (Z)-3-methyl-4-hydroxybut-2-enyl nitrate, and (E)- and (Z)-2-methyl-4-hydroxybut-2-enyl nitrates (‘isoprene nitrates’) in 66–80% overall yields. Using NOESY experiments the elucidation of the carbon–carbon double bond configuration within the purified isoprene nitrates has been established. Further exemplifying our ‘halide for nitrate’ substitution chemistry we outline the straightforward transformation of (1R,2S)-(−)-myrtenol bromide into the previously unknown monoterpene nitrate (1R,2S)-(−)-myrtenol nitrate

The healing mechanism for excited molecules near metallic surfaces

Radiation damage prevents the ability to obtain images from individual molecules. We suggest that this problem can be avoided for organic molecules by placing them in close proximity with a metallic surface. The molecules will then quickly dissipate any electronic excitation via their coupling to the metal surface. They may therefore be observed for a number of elastic scattering events that is sufficient to determine their structure.Comment: 4 pages, 4 figures. Added reference

Oligonucleotide sequences forming short self-complimentary hairpins can expedite the down-regulation of Coprinopsis cinerea genes

Gene silencing in fungi is often induced by dsRNA hairpin forming constructs the preparation of which can require multiple cloning steps. To simplify gene silencing in the filamentous fungi we have evaluated a high throughput cloning method for target sequences using the homobasidiomycete Coprinopsis cinerea, the GFP reporter and a commercially available vector system. The pSUPER RNAi System™, which was developed for mammalian experiments, exploits the human H1 Polymerase III (Pol III) RNA gene promoter and expedites cloning/expression of specific user-defined oligonucleotide sequences to form short self-complimentary hairpins. Transformation of C. cinerea with pSUPER constructs harboring specific oligonucleotides (19 nt stem length) enabled recovery of transformants with reduced transcripts of the GFP transgene, that were less fluorescent in protein assays and microscopic phenotypes. This technological advance should expedite functional genomic studies in C. cinerea and has wider potential for utility in other homobasidiomycete and filamentous fungi

Nano-droplets deposited in microarrays by femtosecond Ti:sapphire laser-induced forward transfer

The authors present the deposition of nanoscale droplets of Cr using femtosecond Ti:Sapphire Laser-Induced Forward Transfer. Deposits around 300 nm in diameter, significantly smaller than any previously reported, are obtained from a 30 nm thick source film. Deposit size, morphology, and adhesion to a receiver substrate as functions of applied laser fluence are investigated. We show that deposits can be obtained from previously irradiated areas of the source material film with negligible loss of deposition quality, allowing sub-spot size period microarrays to be produced without the need to move the source film

The TTF finite-energy spectral features in photoemission of TTF-TCNQ: The Hubbard-chain description

A dynamical theory which accounts for all microscopic one-electron processes is used to study the spectral function of the 1D Hubbard model for the whole $(k, \omega)$-plane, beyond previous studies which focused on the weight distribution in the vicinity of the singular branch lines only. While our predictions agree with those of the latter studies concerning the tetracyanoquinodimethane (TCNQ) related singular features in photoemission of the organic compound tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ) metallic phase, the generalized theory also leads to quantitative agreement concerning the tetrathiafulvalene (TTF) related finite-energy spectral features, which are found to correspond to a value of the on-site repulsion $U$ larger than for TCNQ. Our study reveals the microscopic mechanisms behind the unusual spectral features of TTF-TCNQ and provides a good overall description of those features for the whole $(k, \omega)$-plane.Comment: To appear in Journal of Physics: Condensed Matte