Structure control of silica-supported mono and bimetallic Au–Pt catalysts via mercapto capping synthesis

Cataloged from PDF version of article.SiO2-supported monometallic and bimetallic platinum-gold catalysts are prepared by deposition of metal nanoparticles stabilized by mercaptopropyltriethoxysilane (MPTES) after different aging time of the solution containing metal ions and MPTES. The materials are tested in the hydrodesulfurization (HDS) reaction of thiophene and compared with corresponding catalysts prepared by the conventional deposition-precipitation (DP) method. The monometallic Pt and the bimetallic Au-Pt prepared by DP have comparable activity. With respect to the platinum catalyst prepared by DP, the corresponding platinum catalyst prepared by MPTES particle stabilization exhibits a substantial enhancement of the activity regardless the solution aging time. On the contrary, the MPTES-assisted Au-Pt catalysts have different activities, depending on the solution aging time, with the most active being the one obtained with the 5-day-aged solution. In accord with XRD, XPS, and FTIR, the aging time of the solution, through the different interaction of Pt or Au precursors with the mercapto groups, has a crucial effect on the structure and on the surface of the catalysts. The observed differences in the catalytic activity are related to the structural and compositional changes of the bimetallic particles. (C) 2012 Elsevier Inc. All rights reserved

Infant nutrition and allergy

The correct nutrition in the first year of a child’s life is an important factor determining the physical and intellectual capabilities of a person at a later age and has an important meaning to the risk of developing a food allergy. The aim of our study was to determine whether breastfeeding practices, including exceptional breastfeeding, and using hydrolysed milk alter the risk of developing a food allergy in infants. Material and Methods: We tracked 180 healthy infants up to the age of one year old and 94 – with manifestations of allergy. The statistical processing and visualisation of the results were done with the products Statgraphics Plus and Microsoft Excel. Results: The success of breastfeeding in the monitored mothers in terms of duration of breastfeeding was influenced by the level of education, ethnicity and current place of residence. In normal birth and caesarean delivery, healthy children are breastfed over 7 months of age, while children with manifestations of allergy – up to 1-2 months of age. Among the monitored by us children food allergy was seen more frequently in infants with low birth weight.  More commonly during the first year we observed skin-gastrointestinal form toward cow’s milk proteins. Among the observed children with allergic manifestation we found elevated levels of immunoglobin E(36,5IU/ml), eosinophiles – over 7%, anaemic syndrome – 40,5%. About 93% of children with initial manifestations of allergy were fed milk for infants, 4,3% were on mixed feeding (breast milk and supplementation with infant milk), 2,1 - on exceptional breastfeeding. Conclusion: The frequent clinical manifestation of allergic colitis and confirmation of allergy to cow's milk with immunoglobulin E and eosinophils require the introduction of an elimination diet and prolonged feeding with protein hydrolysate 6-12 months

Associations of cytokines genetic polymorphisms with hypertension progress

The article presents results of comparative analysis of cytokines genes polymorphous variants occurrence among hypertension patients with burdened familial history regarding this disease and in a control grou

Effect of treatment with enrofloxacin and Lactobacillus probiotics on ABCB1, ABCC2 and ABCG2 mRNA expression in poultry

Poultry feed is often supplemented by Lactobacillus probiotics which may alter drug bioavailability by affecting the expression of intestinal ATP-binding cassette (ABC) efflux transporters. Therefore the effect of probiotics, administered alone or in combination with enrofloxacin, on the expression of ABCB1, ABCC2 and ABCG2 mRNAs in chickens was evaluated. Day-old Ross chicks (n=24) were divided in four equal groups. Control group was not treated. The second group received feed with addition of probiotics Lactobacillus brevis, L. plantarum and L. bulgaricus 5 days after hatching, for 15 days. The third group received probiotics as described above and enrofloxacin at the age of 15 days (10 mg/kg, via drinking water for 5 days). The last group received enrofloxacin at age of 15 days (10 mg/kg, via drinking water for 5 days). Expression of ABC transporters in liver, duodenum and jejunum was determined by qRT-PCR. Down-regulation of ABCG2 mRNA in the liver (P<0.05), its up-regulation in the duodenum (P<0.05) and increased ABCB1 mRNA levels in the jejunum (P<0.05) can be attributed to enrofloxacin treatment. Decrease in ABCC2 mRNA expression in the duodenum can be associated with enrofloxacin administration. The observed changes were related to enrofloxacin administration and to lesser extent to Lactobacillus supplementation

The role of receptor MAS in microglia-driven retinal vascular development

Objective: The receptor MAS, encoded by Mas1, is expressed in microglia and its activation has been linked to anti-inflammatory actions. However, microglia are involved in several different processes in the central nervous system, including the promotion of angiogenesis. We therefore hypothesized that the receptor MAS also plays a role in angiogenesis via microglia. Approach and results: To assess the role of MAS on vascular network development, flat-mounted retinas from 3-day-old wild-type (WT) and Mas1−/− mice were subjected to Isolectin B4 staining. The progression of the vascular front was reduced (− 24%, p < 0.0001) and vascular density decreased (− 38%, p < 0.001) in Mas1−/− compared to WT mice with no change in the junction density. The number of filopodia and filopodia bursts were decreased in Mas1−/− mice at the vascular front (− 21%, p < 0.05; − 29%, p < 0.0001, respectively). This was associated with a decreased number of vascular loops and decreased microglial density at the vascular front in Mas1−/− mice (-32%, p < 0.001; − 26%, p < 0.05, respectively). As the front of the developing vasculature is characterized by reduced oxygen levels, we determined the expression of Mas1 following hypoxia in primary microglia from 3-day-old WT mice. Hypoxia induced a 14-fold increase of Mas1 mRNA expression (p < 0.01). Moreover, stimulation of primary microglia with a MAS agonist induced expression of Notch1 (+ 57%, p < 0.05), Dll4 (+ 220%, p  < 0.001) and Jag1 (+ 137%, p < 0.001), genes previously described to mediate microglia/endothelial cell interaction during angiogenesis. Conclusions: Our study demonstrates that the activation of MAS is important for microglia recruitment and vascular growth in the developing retina

Statistics of magnetic field measurements in OBA stars and the evolution of their magnetic fields

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim We review the measurements of magnetic fields of OBA stars. Based on these data, we confirm that magnetic fields are distributed according to a lognormal law with mean log B = − 0.5 (B in kG) with a standard deviation σ = 0.5. The shape of the magnetic field distribution (MFD) is similar to that for neutron stars. This finding favors the hypothesis that the magnetic field of a neutron star is determined mainly by the magnetic field of its predecessor, namely the massive OB star. Further, we model the evolution of an ensemble of magnetic massive stars in the Galaxy. We use our own population synthesis code to obtain the distribution of stellar radii, ages, masses, temperatures, effective magnetic fields, and magnetic fluxes from the pre-main-sequence (PMS) via zero-age main sequence (ZAMS) up to the terminal-age main sequence stages. A comparison of the MFD obtained in our model with that obtained from the recent measurements of the stellar magnetic field allows us to conclude that the evolution of magnetic fields of massive stars is slow if not absent. The shape of the real MFD shows no indications of the magnetic desert proposed previously. Based on this finding, we argue that the observed fraction of magnetic stars is determined by physical conditions at the PMS stage of stellar evolution