Creation of equal-spin triplet superconductivity at the Al/EuS interface

In conventional superconductors, electrons of opposite spins are bound into Cooper pairs. However, when the superconductor is in contact with a non-uniformly ordered ferromagnet, an exotic type of superconductivity can appear at the interface, with electrons bound into three possible spin-triplet states. Triplet pairs with equal spin play a vital role in low-dissipation spintronics. Despite the observation of supercurrents through ferromagnets, spectroscopic evidence for the existence of equal-spin triplet pairs is still missing. Here we show a theoretical model that reveals a characteristic gap structure in the quasiparticle density of states which provides a unique signature for the presence of equal-spin triplet pairs. By scanning tunnelling spectroscopy we measure the local density of states to reveal the spin configuration of triplet pairs. We demonstrate that the Al/EuS interface causes strong and tunable spin-mixing by virtue of its spin-dependent transmission.Comment: 10 pages, 4 figures, 17 pages supplementary information, 14 supplementary figure

Interest in Police Patrol Careers: An Assessment of Potential Candidates\u27 Impressions of the Police Recruitment, Selection, and Training Processes

Both criminal justice researchers and practitioners have suspected that generational preferences and the nature of police patrol work have acted as dual forces leading potential police recruits away from police careers, resulting in large numbers of unfilled police positions. This challenge is exacerbated by accelerating retirements and expanding police duties. Police recruitment became an even larger managerial issue after the 2008 recession failed to resolve the most critical factor driving people away from police careers in the first place: police departments saw fewer and fewer qualified applicants, despite the recession bringing more applicants in number. In the wake of the 2008 recession, attention has turned to generational preferences of post-Millennials and the potential incompatibility of their career expectations with the realities of police patrol work (Haggerty, 2009; Morison, 2017; Orrick, 2008; PERF, 2010; Wilson et al., 2010). Little research has been conducted from the demand, or applicant, side of this critical workforce management issue facing police departments, especially as public demands for accountability and police legitimacy are escalating. This research project addresses this critical question, and the results inform police leaders as to how better to market and recruit future officers more effectively while balancing community demands and budgetary realities. Additionally, it furthers workforce management theoretical perspectives on the nature and character of human resources dynamics among post- Millennials. This research project utilizes a survey questionnaire distributed to college students enrolled in criminal justice courses to gauge reaction to prompted statements regarding their perception of the police profession, the application process, contemporary public demands of police officers, and initial police training. Survey results detail “fear points” regarding these expectations. The sample is composed of undergraduate students at the following institutions: The University of Southern Mississippi, Illinois State University, Indiana University- Purdue University Indianapolis, University of Massachusetts Lowell, and Missouri State University. Participant responses gauge student expectations of a police career, examining their consideration of such a career. This data helps inform practitioner strategies for recruitment of post-Millennial generations

Magic angles in twisted bilayer graphene near commensuration: Towards a hypermagic regime

The Bistritzer-MacDonald continuum model (BM model) describes the low-energy moir\'e bands for twisted bilayer graphene (TBG) at small twist angles. We derive a generalized continuum model for TBG near any commensurate twist angle, which is characterized by complex interlayer hoppings at commensurate $AA$ stackings (rather than the real hoppings in the BM model), a real interlayer hopping at commensurate $AB/BA$ stackings, and a global energy shift. The complex phases of the $AA$ stacking hoppings and the twist angle together define a single angle parameter $\phi_0$. We compute the model parameters for the first six distinct commensurate TBG configurations, among which the $38.2^\circ$ configuration may be within experimentally observable energy scales. We identify the first magic angle for any $\phi_0$ at a condition similar to that of the BM model. At this angle, the lowest two moir\'e bands at charge neutrality become flat except near the $\boldsymbol\Gamma_M$ point and retain fragile topology but lose particle-hole symmetry. We further identify a hypermagic parameter regime centered at $\phi_0 = \pm\pi/2$ where many moir\'e bands around charge neutrality (often $8$ or more) become flat simultaneously. Many of these flat bands resemble those in the kagome lattice and $p_x$, $p_y$ 2-orbital honeycomb lattice tight-binding models.Comment: 49 pages, 22 figures, accepted by Physical Review

The Parent Diarsene HAs=AsH as side-on bound ligand in an Iron Carbonyl Complex

The terminal diarsene HAs=AsH ligand attracts special interest concerning its bonding relation in comparison to its isolable relative, ethene. Herein, by the methanolysis of [{Fe(CO)4}As(SiMe3)3] (1) the synthesis of [{Fe(CO)4}(η2‐As2H2)] (2) is reported, containing a parent diarsene as unprecedented side‐on coordinated ligand. Following this synthetic route, also the D‐labeled complex [{Fe(CO)4}(η2‐As2D2)] (2D) could be isolated. The electronic structure and bonding situation of 2 was elucidated by DFT calculations revealing that 2 is best described as an olefin‐like complex. Moreover, the reactivity of 2 towards the Lewis acids [{M(CO)5}(thf)] (M=Cr, W) was investigated, leading to the complexes [Fe(CO)4AsHW(CO)5]2 (3) and [{Fe(CO)4}2AsH{Cr(CO)5}] (4), respectively

International Space Station Microgravity Analytical Model Correlation And Update

The acceleration environment aboard the completed International Space Station (ISS) is a key resource for scientific and technological endeavors. Hardware verification activIties and early measurements indicate that the ISS is well on the way of meeting these "Assembly Complete" "microgravity" provisions, however, the simulation models that compute these accelerations have, to date, lacked the high degree of empirical validation typical of standard aerospace industry practices. Assembly stage, on-orbit measurements are used to address this shortcoming and to develop higher confidence in the simulation models. The Phase I correlation results show the analyses to be consistently conservative, producing higher than measured levels. The 25 to 30% greater quasi-steady computations are deemed acceptable for verification. Updates are made to localized structural dynamic and vibroacoustic parameters that reduce responses in selected one-third octave bands by almost 50%. These models are then used for the Assembly Complete verification analysis which concludes that the ISS vehicle meets the ISS microgravity requirements with minor reservations. Two of the sixteen rack are marginally non-compliant in the quasi-steady regime, and operational constraints are needed on the U. S. Lab and ESA APM vacuum resource vents, and the Russian Resistive Exercise Device in the structural dynamic regime

Thermal Decomposition Mechanisms of Lignin Model Compounds: From Phenol to Vanillin

Lignin is a complex, aromatic polymer abundant in cellulosic biomass (trees, switchgrass etc.). Thermochemical breakdown of lignin for liquid fuel production results in undesirable polycyclic aromatic hydrocarbons that lead to tar and soot byproducts. The fundamental chemistry governing these processes is not well understood. We have studied the unimolecular thermal decomposition mechanisms of aromatic lignin model compounds using a miniature SiC tubular reactor. Products are detected and characterized using time-of-flight mass spectrometry with both single photon (118.2 nm; 10.487 eV) and 1 + 1 resonance-enhanced multiphoton ionization (REMPI) as well as matrix isolation infrared spectroscopy. Gas exiting the heated reactor (300 K -- 1600 K) is subject to a free expansion after a residence time of approximately 100 µs. The expansion into vacuum rapidly cools the gas mixture and allows the detection of radicals and other highly reactive intermediates. By understanding the unimolecular fragmentation patterns of phenol (C6H5OH), anisole (C6H5OCH3) and benzaldehyde (C6H5CHO), the more complicated thermocracking processes of the catechols (HO-C6H4-OH), methoxyphenols (HO-C6H4-OCH3) and hydroxybenzaldehydes (HO-C6H4-CHO) can be interpreted. These studies have resulted in a predictive model that allows the interpretation of vanillin, a complex phenolic ether containing methoxy, hydroxy and aldehyde functional groups. This model will serve as a guide for the pyrolyses of larger systems including lignin monomers such as coniferyl alcohol. The pyrolysis mechanisms of the dimethoxybenzenes (H3C-C6H4-OCH3) and syringol, a hydroxydimethoxybenzene have also been studied. These results will aid in the understanding of the thermal fragmentation of sinapyl alcohol, the most complex lignin monomer. In addition to the model compound work, pyrolyisis of biomass has been studied via the pulsed laser ablation of poplar wood. With the REMPI scheme, aromatic lignin decomposition products are directly and selectively detected. A number of these products are the lignin model compounds listed above, providing a direct link between the model compound studies and the pyrolysis of actual biomass

Heterogeneity of spacer lengths in circles of amplified ribosomal DNA of two insect species, Dytiscus marginalis and Acheta domesticus

No abstract availabl