Application of continuous-wave cavity ring-down spectroscopy to laminar flames

In this paper we describe the application of diode laser continuous-wave cavity ring-down spectroscopy (cw-CRDS) to in-situ flame diagnostics. Spectra of the P17e acetylene feature at 1535.4 nm were recorded in a premixed laminar ethylene/air flame. The overall absorption of the feature was measured to be ≈ 1.5×10−4 cm−1 a short distance above the reaction zone for a flame fuel equivalence ratio of 1.66, and the minimum detection limit (3σ) of the system was calculated to be1.2×10−5 cm−1. This demonstrates the potential of the technique for the measurement of weakly absorbing species in flames. Finally, we discuss the advantages and limitations of the cw-CRDS technique for flame measurements

A Bayesian framework for fracture characterization from surface seismic data

We describe a methodology for quantitatively characterizing the fractured nature of a hydrocarbon or geothermal reservoir from surface seismic data under a Bayesian inference framework. Fractures provide pathways for fluid flow in a reservoir, and hence, knowledge about a reservoir’s fractured nature can be used to enhance production of the reservoir. The fracture properties of interest in this study (to be inferred) are fracture orientation and excess compliance, where each of these properties are assumed to vary spatially over a 2D lateral grid which is assumed to represent the top of a reservoir. The Bayesian framework in which the inference problem is cast has the key benefits of (1) utilization of a prior model that allows geological information to be incorporated, (2) providing a straightforward means of incorporating all measurements (across the 2D spatial grid) into the estimates at each grid point, (3) allowing different types of measurements to be combined under a single inference procedure, and (4) providing a measure of uncertainty in the estimates. The observed data are taken from a 2D array of surface seismic receivers responding to an array of surface sources. Well understood features from the seismic traces are extracted and treated as the observed data, namely the P-wave reflection amplitude variation with acquisition azimuth (amplitude versus azimuth, or AvAz, data) and fracture transfer function (FTF) data. AvAz data are known to be more sensitive to fracture properties when the fracture spacing is significantly smaller than the seismic wavelength, whereas fracture transfer function data are more sensitive to fracture properties when the fracture spacing is on the order of the seismic wavelength. Combining these two measurements has the benefit of allowing inferences to be made about fracture properties over a larger range of fracture spacing than otherwise attainable. Geophysical forward models for the measurements are used to arrive at likelihood models for the data. The prior distribution for the hidden fracture variables is obtained by defining a Markov random field (MRF) over the lateral 2D grid where we wish to obtain fracture properties. The fracture variables are then inferred by application of loopy belief propagation (LBP) to yield approximations for the posterior marginal distributions of the fracture properties, as well as the maximum a posteriori (MAP) and Bayes least squares (BLS) estimates of these properties. Verification of the inference procedure is performed on a synthetic dataset, where the estimates obtained are shown to be at or near ground truth for a large range of fracture spacings

ESTIMATING LONG GRB JET OPENING ANGLES AND REST-FRAME ENERGETICS

We present a method to estimate the jet opening angles of long duration gamma-ray bursts (GRBs) using the prompt gamma-ray energetics and an inversion of the Ghirlanda relation, which is a correlation between the time-integrated peak energy of the GRB prompt spectrum and the collimation-corrected energy in gamma-rays. The derived jet opening angles using this method and detailed assumptions match well with the corresponding inferred jet opening angles obtained when a break in the afterglow is observed. Furthermore, using a model of the predicted long GRB redshift probability distribution observable by the Fermi Gamma-ray Burst Monitor (GBM), we estimate the probability distributions for the jet opening angle and rest-frame energetics for a large sample of GBM GRBs for which the redshifts have not been observed. Previous studies have only used a handful of GRBs to estimate these properties due to the paucity of observed afterglow jet breaks, spectroscopic redshifts, and comprehensive prompt gamma-ray observations, and we potentially expand the number of GRBs that can be used in this analysis by more than an order of magnitude. In this analysis, we also present an inferred distribution of jet breaks which indicates that a large fraction of jet breaks are not observable with current instrumentation and observing strategies. We present simple parameterizations for the jet angle, energetics, and jet break distributions so that they may be used in future studies

A Simple and Cost-efficient Technique to Generate Hyperpolarized Long-lived 15N-15N Nuclear Spin Order in a Diazine by Signal Amplification by Reversible Exchange

Signal Amplification by Reversible Exchange (SABRE) is an inexpensive and simple hyperpolarization technique and is capable of boosting Nuclear Magnetic Resonance (NMR) sensitivity by several orders of magnitude. It utilizes the reversible binding of para-hydrogen as hydride ligands and a substrate of interest to a metal catalyst to allow polarization transfer from para-hydrogen to the substrate nuclear spins. The nuclear spin lifetime of the created magnetization sets a strict upper limit on experimental timeframe. Short nuclear spin lifetimes are therefore a challenge for hyperpolarized metabolic imaging prospects. In this report we demonstrate how hyperpolarization and long nuclear spin lifetime can simultaneously be achieved in nitrogen-15 containing pyridazine and phthalazine derivatives by SABRE. These reflect two distinct classes of 15N2-coupled species with respect to their chemical symmetry and thus show different nuclear spin lifetime with the pyridazine derivative having a singlet state lifetime of ca. 2.5 minutes, produced with a signal enhancement of ca. 2,700. In contrast the phthalazine derivative yields a superior 15,000-fold enhancement at 11.7 T but has a much shorter singlet lifetime

A catalog of Nearby Poor Clusters of Galaxies

A catalog of 732 optically selected, nearby poor clusters of galaxies covering the entire sky north of $\rm -3^{\circ}$ declination is presented. The poor clusters, called WBL clusters, were identified as concentrations of 3 or more galaxies with photographic magnitudes brighter than 15.7, possessing a galaxy surface overdensity of $10^{4/3}$. These criteria are consistent with those used in the identification of the original Yerkes poor clusters, and this new catalog substantially increases the sample size of such objects. These poor clusters cover the entire range of galaxy associations up to and including Abell clusters, systematically including poor and rich galaxy systems spanning over three orders of magnitude in the cluster mass function. As a result, this new catalog contains a greater diversity of richness and structures than other group catalogs, such as the Hickson or Yerkes catalogs. The information on individual galaxies includes redshifts and cross-references to other galaxy catalogs. The entries for the clusters include redshift (where available) and cross-references to other group and cluster catalogs.Comment: 27 pages, 7 figures, + one 20-page landscape table, accepted for publication in A

Type and Timing of Rehabilitation Following Acute and Subacute Spinal Cord Injury: A Systematic Review

Objectives: The objective of this study was to conduct a systematic review of the literature to address the following clinical questions: In adult patients with acute and subacute complete or incomplete traumatic SCI, (1) does the time interval between injury and commencing rehabilitation affect outcome?; (2) what is the comparative effectiveness of different rehabilitation strategies, including different intensities and durations of treatment?; (3) are there patient or injury characteristics that affect the efficacy of rehabilitation?; and (4) what is the cost-effectiveness of various rehabilitation strategies? Methods: A systematic search was conducted for literature published through March 31, 2015 that evaluated rehabilitation strategies in adults with acute or subacute traumatic SCI at any level. Studies were critically appraised individually and the overall strength of evidence was evaluated using methods proposed by the GRADE (Grades of Recommendation Assessment, Development and Evaluation) working group. Results: The search strategy yielded 384 articles, 19 of which met our inclusion criteria. Based on our results, there was no difference between body weight–supported treadmill training and conventional rehabilitation with respect to improvements in Functional Independence Measure (FIM) Locomotor score, Lower Extremity Motor Scores, the distance walked in 6 minutes or gait velocity over 15.2 m. Functional electrical therapy resulted in slightly better FIM Motor, FIM Self-Care, and Spinal Cord Independence Measure Self-Care subscores compared with conventional occupational therapy. Comparisons using the Toronto Rehabilitation Institute Hand Function Test demonstrated no differences between groups in 7 of 9 domains. There were no clinically important differences in Maximal Lean Test, Maximal Sidewards Reach Test, T-shirt Test, or the Canadian Occupational Performance Measure between unsupported sitting training and standard in-patient rehabilitation. Conclusion: The current evidence base for rehabilitation following acute and subacute spinal cord injury is limited. Methodological challenges have contributed to this and further research is still needed. © 2017, © The Author(s) 2017

A Search for High-Energy Counterparts to Fast Radio Bursts

We report on a search for high-energy counterparts to fast radio bursts (FRBs) with the Fermi Gamma-ray Burst Monitor (GBM), Fermi Large Area Telescope (LAT), and the Neil Gehrels Swift Observatory Burst Alert Telescope (BAT). We find no significant associations for any of the 23 FRBs in our sample, but report upper limits to the high-energy fluence for each on timescales of 0.1, 1, 10, and 100 s. We report lower limits on the ratio of the radio to high-energy fluence, $\frac{f_{r}}{f_{\gamma}}$, for timescales of 0.1 and 100 s. We discuss the implications of our non-detections on various proposed progenitor models for FRBs, including analogs of giant pulses from the Crab pulsar and hyperflares from magnetars. This work demonstrates the utility of analyses of high-energy data for FRBs in tracking down the nature of these elusive sources