The absence of the 10 um silicate feature in the isolated Herbig Ae star HD 100453

We analyse the optical and IR spectra, as well as the spectral energy distribution (UV to mm) of the candidate Herbig Ae star HD100453. This star is particular, as it shows an energy distribution similar to that of other isolated Herbig Ae/Be stars (HAEBEs), but unlike most of them, it does not have a silicate emission feature at 10 um, as is shown in Meeus (2001). We confirm the HAEBE nature of HD100453 through an analysis of its optical spectrum and derived location in the H-R diagram. The IR spectrum of HD100453 is modelled by an optically thin radiative transfer code, from which we derive constraints on the composition, grain-size and temperature distribution of the circumstellar dust. We show that it is both possible to explain the lack of the silicate feature as (1) a grain-size effect - lack of small silicate grains, and (2) a temperature effect - lack of small, hot silicates, as proposed by Dullemond (2001), and discuss both possibilities.Comment: 9 pages, 7 figures; accepted by A&

Herschel observations of the circumstellar environment of the two Herbig Be stars R Mon and PDS27

We report and analyse FIR observations of two Herbig Be stars, R Mon and PDS 27, obtained with Herschel's instruments PACS and SPIRE. We construct SEDs and derive the infrared excess. We extract line fluxes from the PACS and SPIRE spectra and construct rotational diagrams in order to estimate the excitation temperature of the gas. We derive CO, [OI] and [CI] luminosities to determine physical conditions of the gas, as well as the dominant cooling mechanism. We confirm that the Herbig Be stars are surrounded by remnants from their parental clouds, with an IR excess that mainly originates in a disc. In R Mon we detect [OI], [CI], [CII], CO (26 transitions), water and OH, while in PDS 27 we only detect [CI] and CO (8 transitions). We attribute the absence of OH and water in PDS 27 to UV photo-dissociation and photo-evaporation. From the rotational diagrams, we find several components for CO: we derive $T_{rot}$ 949$\pm$90 K, 358$\pm$20 K & 77$\pm$12 K for R Mon, 96$\pm$12 K & 31$\pm$4 K for PDS 27 and 25$\pm$8 K & 27$\pm$6 K for their respective compact neighbours. The forsterite feature at 69$\mu$m was not detected in either of the sources, probably due to the lack of (warm) crystalline dust in a flat disc. We find that cooling by molecules is dominant in the Herbig Be stars, while this is not the case in Herbig Ae stars where cooling by [OI] dominates. Moreover, we show that in the Herbig Be star R Mon, outflow shocks are the dominant gas heating mechanism, while in Herbig Ae stars this is stellar. The outflow of R Mon contributes to the observed line emission by heating the gas, both in the central spaxel/beam covering the disc and the immediate surroundings, as well as in those spaxels/beams covering the parabolic shell around it. PDS 27, a B2 star, has dispersed a large part of its gas content and/or destroyed molecules; this is likely given its intense UV field.Comment: Accepted for publication in Astronomy & Astrophysic

New CP-violation and preferred-frame tests with polarized electrons

We used a torsion pendulum containing $\sim 9 \times 10^{22}$ polarized electrons to search for CP-violating interactions between the pendulum's electrons and unpolarized matter in the laboratory's surroundings or the sun, and to test for preferred-frame effects that would precess the electrons about a direction fixed in inertial space. We find $|g_{\rm P}^e g_{\rm S}^N|/(\hbar c)< 1.7 \times 10^{-36}$ and $|g_{\rm A}^e g_{\rm V}^N|/(\hbar c) < 4.8 \times 10^{-56}$ for $\lambda > 1$AU. Our preferred-frame constraints, interpreted in the Kosteleck\'y framework, set an upper limit on the parameter $|\bm{\tilde {b}}^e| \leq 5.0 \times 10^{-21}$ eV that should be compared to the benchmark value $m_e^2/M_{\rm Planck}= 2 \times 10^{-17}$ eV.Comment: 4 figures, accepted for publication in Physical Review Letter

ISO spectroscopy of circumstellar dust in 14 Herbig Ae/Be systems: towards an understanding of dust processing

We present Infrared Space Observatory (ISO) spectra of fourteen isolated Herbig Ae/Be (HAEBE) stars, to study the characteristics of their circumstellar dust. These spectra show large star-to-star differences, in the emission features of both carbon-rich and oxygen-rich dust grains. The IR spectra were combined with photometric data ranging from the UV through the optical into the sub-mm region. We defined two key groups, based upon the spectral shape of the infrared region. The derived results can be summarized as follows: (1) the continuum of the IR to sub-mm region of all stars can be reconstructed by the sum of a power-law and a cool component, which can be represented by a black body. Possible locations for these components are an optically thick, geometrically thin disc (power-law component) and an optically thin flared region (black body); (2) all stars have a substantial amount of cold dust around them, independent of the amount of mid-IR excess they show; (3) also the near-IR excess is unrelated to the mid-IR excess, indicating different composition/location of the emitting material; (4) remarkably, some sources lack the silicate bands; (5) apart from amorphous silicates, we find evidence for crystalline silicates in several stars, some of which are new detections; (6) PAH bands are present in at least 50% of our sample, and their appearance is slightly different from PAHs in the ISM; (7) PAH bands are, with one exception, not present in sources which only show a power-law continuum in the IR; their presence is unrelated to the presence of the silicate bands; (8) the dust in HAEBE stars shows strong evidence for coagulation; this dust processing is unrelated to any of the central star properties (such as age, spectral type and activity).Comment: 15 pages, accepted by A&

Rapporto con la famiglia e sviluppo del concetto di s\ue9 in adolescenza [family relationship and self concept development in adolescence]

The aim of this study was to investigate associations between family relationships and self-concept in adolescence. Specifically, we investigated how adolescent attachment (expressed by levels of trust, communication, and alienation; Armsden & Greenberg, 1987) to both parents is associated with self-concept clarity (Campbell, 1990), that indicates the extent to which self beliefs are clear, internally consistent and stable. Participants were 2113 Italian adolescents (979 boys and 1134 girls), with ages ranging between 11 and 18 years (1023 were attending junior high schools and 1090 were attending high schools). Participants filled out the Inventory of Parent and Peer Attachment (Nada-Raja, McGee, & Stanton, 1992) and the Self-Concept Clarity Scale (Campbell, Trapnell, Heine, Katz, Lavalle, & Lehman, 1996). Main findings of the multivariate analyses of variance indicated that quality of paternal and maternal relationships worsened during adolescence: trust in both parents and quality of communication with them was lower among older adolescents, that reported also higher levels of alienation. Second, self-concept clarity varied as a function of both gender and age (i.e., self-concept clarity increased over time for male adolescents, whereas it decreased for female adolescents). Results of regression analyses pointed out that paternal and maternal trust were positively related to self-concept clarity, whereas paternal and maternal alienation and maternal communication were negatively linked to it. A further exploration of these associations within gender and age adolescent groups highlighted that within the younger adolescent category paternal and maternal relationships were related to self-concept clarity in both male and female groups. On the contrary, within the older adolescent category only paternal attachment was related to boys\u2019 self-concept clarity and only maternal attachment was linked to girls\u2019 self-concept clarity

Accretion variability of Herbig Ae/Be stars observed by X-Shooter. HD 31648 and HD 163296

This work presents X-Shooter/VLT spectra of the prototypical, isolated Herbig Ae stars HD 31648 (MWC 480) and HD 163296 over five epochs separated by timescales ranging from days to months. Each spectrum spans over a wide wavelength range covering from 310 to 2475 nm. We have monitored the continuum excess in the Balmer region of the spectra and the luminosity of twelve ultraviolet, optical and near infrared spectral lines that are commonly used as accretion tracers for T Tauri stars. The observed strengths of the Balmer excesses have been reproduced from a magnetospheric accretion shock model, providing a mean mass accretion rate of 1.11 x 10^-7 and 4.50 x 10^-7 Msun yr^-1 for HD 31648 and HD 163296, respectively. Accretion rate variations are observed, being more pronounced for HD 31648 (up to 0.5 dex). However, from the comparison with previous results it is found that the accretion rate of HD 163296 has increased by more than 1 dex, on a timescale of ~ 15 years. Averaged accretion luminosities derived from the Balmer excess are consistent with the ones inferred from the empirical calibrations with the emission line luminosities, indicating that those can be extrapolated to HAe stars. In spite of that, the accretion rate variations do not generally coincide with those estimated from the line luminosities, suggesting that the empirical calibrations are not useful to accurately quantify accretion rate variability.Comment: 14 pages, 7 Figures, Accepted in Ap

Dust evolution in protoplanetary disks around Herbig Ae/Be stars - The Spitzer view

In this paper we present mid-infrared spectra of a comprehensive set of Herbig Ae/Be stars observed with the Spitzer Space Telescope. The signal-to-noise ratio of these spectra is very high, ranging between about a hundred and several hundreds. During the analysis of these data we tested the validity of standard protoplanetary dust models and studied grain growth and crystal formation. On the basis of the analyzed spectra, the major constituents of protoplanetary dust around Herbig Ae/Be stars are amorphous silicates with olivine and pyroxene stoichiometry, crystalline forsterite and enstatite and silica. No other solid state features, indicating other abundant dust species, are present in the Spitzer spectra. Deviations of the synthetic spectra from the observations are most likely related to grain shape effects and uncertainties in the iron content of the dust grains. Our analysis revealed that larger grains are more abundant in the disk atmosphere of flatter disks than in that of flared disks, indicating that grain growth and sedimentation decrease the disk flaring. We did not find, however, correlations between the value of crystallinity and any of the investigated system parameters. Our analysis shows that enstatite is more concentrated toward the warm inner disk than forsterite, in contrast to predictions of equilibrium condensation models. None of the three crystal formation mechanisms proposed so far can alone explain all our findings. It is very likely that all three play at least some role in the formation of crystalline silicates.Comment: 56 pages, 21 figures, accepted for publication in Ap

On the interplay between flaring and shadowing in disks around Herbig Ae/Be stars

Based on the SED, Herbig stars have been categorized into two observational groups, reflecting their overall disk structure: group I members have disks with a higher degree of flaring than their group II counterparts. We investigate the 5-35 um Spitzer IRS spectra of a sample of 13 group I sources and 20 group II sources. We focus on the continuum emission to study the underlying disk geometry. We have determined the [30/13.5] and [13.5/7] continuum flux ratios. The 7-um flux excess with respect to the stellar photosphere is measured, as a marker for the strength of the near-IR emission produced by the inner disk. We have compared our data to self-consistent passive-disk model spectra, for which the same quantities were derived. We confirm the literature result that the difference in continuum emission between group I and II sources can largely be explained by a different amount of small dust grains. However, we report a strong correlation between the [30/13.5] and [13.5/7] flux ratios for Meeus group II sources. Moreover, the [30/13.5] flux ratio decreases with increasing 7-um excess for all targets in the sample. To explain these correlations with the models, we need to introduce an artificial scaling factor for the inner disk height. In roughly 50% of the Herbig Ae/Be stars in our sample, the inner disk must be inflated by a factor 2 to 3 beyond what hydrostatic calculations predict. The total disk mass in small dust grains determines the degree of flaring. We conclude, however, that for any given disk mass in small dust grains, the shadowing of the outer (tens of AU) disk is determined by the scale height of the inner disk (1 AU). The inner disk partially obscures the outer disk, reducing the disk surface temperature. Here, for the first time, we prove these effects observationally.Comment: 4 pages, 3 figures, accepted by A&

A Co(TAML)-based artificial metalloenzyme for asymmetric radical-type oxygen atom transfer catalysis

We show that the incorporation of a biotinylated Co(TAML) cofactor within streptavidin enables asymmetric radical-type oxygen atom transfer catalysis with improved activity and enantioselectivity.</p