1,882 research outputs found
Chemosynthetic gas exchanger Final report, 8 Jun. 1964 - 14 Mar. 1967
Chemosynthetic bioregenerative system for long-term space exploration that employs functional coupling of water with biosynthesis by hydrogen bacteri
Non-Fermi Liquid Behavior and Double-Exchange Physics in Orbital-Selective Mott Systems
We study a multi-band Hubbard model in its orbital selective Mott phase, in
which localized electrons in a narrow band coexist with itinerant electrons in
a wide band. The low-energy physics of this phase is shown to be closely
related to that of a generalized double-exchange model. The high-temperature
disordered phase thus differs from a Fermi liquid, and displays a finite
scattering rate of the conduction electrons at the Fermi level, which depends
continuously on the spin anisotropy.Comment: 5 pages, minor typos correcte
Slave spin cluster mean field theory away from half-filling: Application to the Hubbard and the extended Hubbard Model
A new slave-spin representation of fermion operators has recently been
proposed for the half-filled Hubbard model. We show that with the addition of a
gauge variable, the formalism can be extended to finite doping. The resulting
spin problem can be solved using the cluster mean-field approximation. This
approximation takes short-range correlations into account by exact
diagonalization on the cluster, whereas long-range correlations beyond the size
of clusters are treated at the mean-field level. In the limit where the cluster
has only one site and the interaction strength is infinite, this approach
reduces to the Gutzwiller approximation. There are some qualitative differences
when the size of the cluster is finite. We first compute the critical for
the Mott transition as a function of a frustrating second-neighbor interaction
on lattices relevant for various correlated systems, namely the cobaltites, the
layered organic superconductors and the high-temperature superconductors. For
the triangular lattice, we also study the extended Hubbard model with
nearest-neighbor repulsion. In additionto a uniform metallic state, we find a
charge density wave in a broad doping regime,
including commensurate ones. We find that in the large limit, intersite
Coulomb repulsion strongly suppresses the single-particle weight of the
metallic state.Comment: 10 pages, 11 figures, submitted to PR
Supersolidity, entropy and frustration
We study the properties of t-t'-V model of hard-core bosons on the triangular
lattice that can be realized in optical lattices. By mapping to the spin-1/2
XXZ model in a field, we determine the phase diagram of the t-V model where the
supersolid characterized by the ordering pattern (x,x,-2x') ("ferrimagnetic" or
SS A) is a ground state for chemical potential \mu >3V. By turning on either
temperature or t' at half-filling \mu =3V, we find a first order transition
from SS A to the elusive supersolid characterized by the (x,-x,0) ordering
pattern ("antiferromagnetic" or SS C). In addition, we find a large region
where a superfluid phase becomes a solid upon raising temperature at fixed
chemical potential. This is an analog of the Pomeranchuk effect driven by the
large entropic effects associated with geometric frustration on the triangular
lattice.Comment: 4 pages, igures, LaTe
Is the Mott transition relevant to f-electron metals ?
We study how a finite hybridization between a narrow correlated band and a
wide conduction band affects the Mott transition. At zero temperature, the
hybridization is found to be a relevant perturbation, so that the Mott
transition is suppressed by Kondo screening. In contrast, a first-order
transition remains at finite temperature, separating a local moment phase and a
Kondo- screened phase. The first-order transition line terminates in two
critical endpoints. Implications for experiments on f-electron materials such
as the Cerium alloy CeLaTh are discussed.Comment: 5 pages, 3 figure
The origin and significance of euhedral apatite crystals on conodonts
Crystal overgrowth on fossil remains is well-documented in the literature. Attention has specifically focused on
bioapatite (i.e., an apatite of biochemical origin regardless of post-mortem changes) configurations, in order to
decipher any possible relation to fossilization/diagenesis. This study investigates the Rare Earth Element (REE)
and other High-Field-Strength Element (HFSE) composition of euhedral crystals formed on the surface of conodont elements compared with that of crystal-free surfaces. Euhedral crystals are by definition crystals characterized by sharp faces, developing solids that, for apatite, assume the form of hexagonal prisms, reflecting its crystal symmetry. Late Ordovician (Amorphognathus ordovicicus Zone) conodonts from two localities in Sardinia and the Carnic Alps (Italy) are herein investigated. Conodont elements reveal the occurrence of smooth surfaces and surfaces partially covered with euhedral crystals. Since euhedral crystals did not reasonably grow during the organism’s lifetime, the REE and HFSE analysis can provide important insights into the crystal growth process. The experimental results indicated a substantial contribution of diagenetic imprinting for all the analyzed material, although more evident on euhedral crystals that are significantly enriched in middle and, subordinately, in heavy REE with respect to smooth surfaces. The positive correlations between La + Th vs log[ΣREE] and Ce + Th
vs log[ΣREE] could support the hypothesis that the neoformed euhedral crystals grew also by depleting the pristine bioapatite of the conodont elements. Nevertheless, the occurrence of two types of apatite cannot be ruled out: euhedral crystals as neoformed products of diagenetic processes and smooth surfaces as remains of the pristine conodont bioapatite after diagenesis
Electronic correlations in Hund metals
To clarify the nature of correlations in Hund metals and its relationship with Mott physics we analyze the electronic correlations in multiorbital systems as a function of intraorbital interaction U, Hund's coupling JH, and electronic filling n. We show that the main process behind the enhancement of correlations in Hund metals is the suppression of the double occupancy of a given orbital, as it also happens in the Mott insulator at half-filling. However, contrary to what happens in Mott correlated states the reduction of the quasiparticle weight Z with JH can happen in spite of increasing charge fluctuations. Therefore, in Hund metals the quasiparticle weight and the mass enhancement are not good measurements of the charge localization. Using simple energetic arguments we explain why the spin polarization induced by Hund's coupling produces orbital decoupling. We also discuss how the behavior at moderate interactions, with correlations controlled by the atomic spin polarization, changes at large U and JH due to the proximity to a Mott insulating state
Charge Disproportionation, Mixed Valence, and Janus Effect in Multiorbital Systems: A Tale of Two Insulators
Multiorbital Hubbard models host strongly correlated "Hund's metals" even for interactions much stronger than the bandwidth. We characterize this interaction-resilient metal as a mixed-valence state. In particular, it can be pictured as a bridge between two strongly correlated insulators: a high-spin Mott insulator and a charge-disproportionated insulator which is stabilized by a very large Hund's coupling. This picture is confirmed comparing models with negative and positive Hund's coupling for different fillings. Our results provide a characterization of the Hund's metal state and connect its presence with charge disproportionation, which has indeed been observed in chromates and proposed to play a role in iron-based superconductors
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