Destruction of toxic and environmental harmful gases

Environmental and Occupational Health and Safety or OH&S issues have influenced the focus to capture / destroy toxic and environmental harmful gases expelled from fumigated storage. These storages are aerated to Threshold Limit Value (TLV) levels at the completion of fumigation to ensure it is safe for human reentry. Most fumigants by design are toxic and some have additional environmental hazards. The once universal fumigant, methyl bromide (CH3Br), while restricted by the Montreal Protocol because it is an ozone depletor, is still used commercially in tonnage quantities. The use of CH3Br is now mostly restricted to Quarantine Pre-Shipment (QPS) fumigations. The CH3Br dose level is approximately 10.000 ppm and the recommended maximum respiratory level is 5 ppm. The universal fumigant gas, phosphine (PH3), a very toxic gas, has a recommended TLV of 0.3 ppm. The sterilant, ethylene oxide (EtO), a known carcinogen, could have niche fumigation-sterilisation applications if the aerated gas could be destroyed. The use of heat to decompose toxic gases can involve the extracted contaminated air being fed into a burner where the hot zone destroys and decomposes the vulnerable fumigant gas. While flame burning at high temperature pyrolysis is 100% effective with EtO, most fumigants will form acidic by-product. Other issues include the need to re-locate capture and destruction equipment to service multiple locations and the large dilution required to reach TLV levels. A current alternative consists of adsorbing fumigants on activated charcoal. The spent activated charcoal requires chemical processing and or burial. There are cost issues with the initial purchase of the activated charcoal and post-treatment chemical processing of the adsorbed fumigant. Another disposal option is the burial of the spent charcoal in landfill sites. The ongoing safe use of fumigants is critical to important export industries especially the large volume bulk grain and export timber market.Keywords: Fumigants, Capture, Destruction, Incineration, Acidic reactants

Radio Observations of Infrared Luminous High Redshift QSOs

We present Very Large Array (VLA) observations at 1.4 GHz and 5 GHz of a sample of 12 Quasi-stellar Objects (QSOs) at z = 3.99 to 4.46. The sources were selected as the brightest sources at 250 GHz from the recent survey of Omont et al. (2001). We detect seven sources at 1.4 GHz with flux densities, S_{1.4} > 50 microJy. These centimeter (cm) wavelength observations imply that the millimeter (mm) emission is most likely thermal dust emission. The radio-through-optical spectral energy distributions for these sources are within the broad range defined by lower redshift, lower optical luminosity QSOs. For two sources the radio continuum luminosities and morphologies indicate steep spectrum, radio loud emission from a jet-driven radio source. For the remaining 10 sources the 1.4 GHz flux densities, or limits, are consistent with those expected for active star forming galaxies. If the radio emission is powered by star formation in these systems, then the implied star formation rates are of order 1e3 M_solar/year. We discuss the angular sizes and spatial distributions of the radio emitting regions, and we consider briefly these results in the context of co-eval black hole and stellar bulge formation in galaxies.Comment: to appear in the A

The external benefits of higher education

The private market benefits of education are widely studied at the micro level, although the magnitude of their macroeconomic impact is disputed. However, there are additional benefits of education, which are less well understood. In this paper the macroeconomic effects of external benefits of higher education are estimated using the “micro-to-macro” simulation approach. Two types of externalities are explored: technology spillovers and productivity spillovers in the labour market. These links are illustrated and the results suggest they could be very large. However, this is qualified by the dearth of microeconomic evidence, for which we hope to encourage further work

The compact, ∼1 kpc host galaxy of a quasar at a redshift of 7.1

We present Atacama Large Millimeter/submillimeter Array (ALMA) observations of the [C ii] fine-structure line and the underlying far-infrared (FIR) dust continuum emission in J1120+0641, the most distant quasar currently known ($z=7.1$). We also present observations targeting the CO(2–1), CO(7–6), and [C i] 369 μm lines in the same source obtained at the Very Large Array and Plateau de Bure Interferometer. We find a [C ii] line flux of ${F}_{[{\rm{C}}{\rm{II}}]}=1.11\pm 0.10$ Jy $\mathrm{km}\,{{\rm{s}}}^{-1}$ and a continuum flux density of ${S}_{227\mathrm{GHz}}=0.53\pm 0.04$ mJy beam−1, consistent with previous unresolved measurements. No other source is detected in continuum or [C ii] emission in the field covered by ALMA (~ 25''). At the resolution of our ALMA observations (0farcs23, or 1.2 kpc, a factor of ~70 smaller beam area compared to previous measurements), we find that the majority of the emission is very compact: a high fraction (~80%) of the total line and continuum flux is associated with a region 1–1.5 kpc in diameter. The remaining ~20% of the emission is distributed over a larger area with radius lesssim4 kpc. The [C ii] emission does not exhibit ordered motion on kiloparsec scales: applying the virial theorem yields an upper limit on the dynamical mass of the host galaxy of $(4.3\pm 0.9)\times {10}^{10}$ ${M}_{\odot }$, only ~20 × higher than the central black hole (BH). The other targeted lines (CO(2–1), CO(7–6), and [C i]) are not detected, but the limits of the line ratios with respect to the [C ii] emission imply that the heating in the quasar host is dominated by star formation, and not by the accreting BH. The star formation rate (SFR) implied by the FIR continuum is 105–340 ${M}_{\odot }\,{\mathrm{yr}}^{-1}$, with a resulting SFR surface density of ~100–350 ${M}_{\odot }\,{\mathrm{yr}}^{-1}$ kpc−2, well below the value for Eddington-accretion-limited star formation

The Deficit of Distant Galaxy Clusters in the RIXOS X-ray Survey

Clusters of galaxies are the largest gravitationally bound systems and therefore provide an important way of studying the formation and evolution of the large scale structure of the Universe. Cluster evolution can be inferred from observations of the X-ray emission of the gas in distant clusters, but interpreting these data is not straightforward. In a simplified view, clusters grow from perturbations in the matter distribution: their intracluster gas is compressed and shock-heated by the gravitational collapse$^{1}$. The resulting X-ray emission is determined by the hydrostatic equilibrium of the gas in the changing gravitational potential. However, if processes such as radiative cooling or pre-collapse heating of the gas are important, then the X-ray evolution will be strongly influenced by the thermal history of the gas. Here we present the first results from a faint flux-limited sample of X-ray selected clusters compiled as part of the ROSAT International X-ray and Optical Survey (RIXOS). Very few distant clusters have been identified. Most importantly, their redshift distribution appears to be inconsistent with simple models based on the evolution of the gravitational potential. Our results suggest that radiative cooling or non-gravitational heating of the intracluster gas must play an important role in the evolution of clusters.Comment: uuencoded compressed postscript. The preprint is also available at http://www.ast.cam.ac.uk/preprint/PrePrint.htm

Resolving the Submillimeter Background: the 850-micron Galaxy Counts

Recent deep blank field submillimeter surveys have revealed a population of luminous high redshift galaxies that emit most of their energy in the submillimeter. The results suggest that much of the star formation at high redshift may be hidden to optical observations. In this paper we present wide-area 850-micron SCUBA data on the Hawaii Survey Fields SSA13, SSA17, and SSA22. Combining these new data with our previous deep field data, we establish the 850-micron galaxy counts from 2 mJy to 10 mJy with a >3-sigma detection limit. The area coverage is 104 square arcmin to 8 mJy and 7.7 square arcmin to 2.3 mJy. The differential 850-micron counts are well described by the function n(S)=N_0/(a+S^3.2), where S is the flux in mJy, N_0=3.0 x 10^4 per square degree per mJy, and a=0.4-1.0 is chosen to match the 850-micron extragalactic background light. Between 20 to 30 per cent of the 850-micron background resides in sources brighter than 2 mJy. Using an empirical fit to our >2 mJy data constrained by the EBL at lower fluxes, we argue that the bulk of the 850-micron extragalactic background light resides in sources with fluxes near 1 mJy. The submillimeter sources are plausible progenitors of the present-day spheroidal population.Comment: 5 pages, accepted by The Astrophysical Journal Letter