Laser-modified one- and two-photon absorption:Expanding the scope of optical nonlinearity

It is shown that conventional one-photon and two-photon absorption processes can be made subject to nonlinear optical control, in each case significantly modifying the efficiency of absorption, through the effect of a secondary, off-resonant stimulus laser beam. The mechanistic origin of these laser-modified absorption processes, in which the stimulus beam emerges unchanged, is traced to higher-order terms in standard perturbation treatments. These normally insignificant terms become unusually prominent when the secondary optical stimulus is moderately intense. Employing a quantum formulation, the effects of the stimulus beam on one-photon and two-photon absorption are analyzed, and calculations are performed to determine the degree of absorption enhancement, and the form of spectral manifestation, under various laser intensities. The implications of differences in selection rules are also considered and exemplified, leading to the identification of dark states that can be populated as a result of laser-modified absorption. Attention is also drawn to the possibility of quantum nondemolition measurements, based on such a form of optical nonlinearity

Methodology for interpretation of SST retrievals using the AVHRR split window algorithm

Intercomparisons of sea surface temperature (SST) products derived from the operational NOAA-7 AVHRR-II algorithm and in situ observations are made. The 1982 data sets consist of ship survey data during the winter from the Mid-Atlantic Bight (MAB), ship and buoy measurements during April and September in the Gulf of Mexico and shipboard observations during April off the N.W. Spanish coast. The analyses included single pixel comparisons and the warmest pixel technique for 2 x 2 pixel and 10 x 10 pixel areas. The reason for using multi-pixel areas was for avoiding cloud contaminated pixels in the vicinity of the field measurements. Care must be taken when applying the warmest pixel technique near oceanic fronts. The Gulf of Mexico results clearly indicate a persistent degradation in algorithm accuracy due to El Chichon aerosols. The MAB and Spanish data sets indicate that very accurate estimates can be achieved if care is taken to avoid clouds and oceanic fronts

Ocean Chlorophyll Studies from a U-2 Aircraft Platform

Chlorophyll gradient maps of large ocean areas were generated from U-2 ocean color scanner data obtained over test sites in the Pacific and Atlantic Oceans. The delineation of oceanic features using the upward radiant intensity relies on an analysis method which presupposes that radiation backscattered from the atmosphere and ocean surface can be properly modeled using a measurement made at 778 nm. An estimation of the chlorophyll concentration was performed by properly ratioing radiances measured at 472 nm and 548 nm after removing the atmospheric effects. The correlation between the remotely sensed data and in-situ surface chlorophyll measurements was validated in two sets of data. The results show that the correlation between the in-situ measured chlorophyll and the derived quantity is a negative exponential function and the correlation coefficient was calculated to be -0.965