4,913 research outputs found
Thermophysical properties of parahydrogen from the freezing liquid line to 5000 R for pressures to 10000 psia
The tables include entropy, enthalpy, internal energy, density, volume, speed of sound, specific heat, thermal conductivity, viscosity, thermal diffusivity, Prandtl number, and the dielectric constant for 65 isobars. Quantities of special utility in heat transfer and thermodynamic calculations are also included in the isobaric tables. In addition to the isobaric tables, tables for the saturated vapor and liquid are given, which include all of the above properties, plus the surface tension. Tables for the P-T of the freezing liquid, index of refraction, and the derived Joule-Thomson inversion curve are also presented
On quantum effects near the liquid-vapor transition in helium
The liquid-vapor transition in He-3 and He-4 is investigated by means of
path-integral molecular dynamics and the quantum virial expansion. Both methods
are applied to the critical isobar and the critical isochore. While previous
path-integral simulations have mainly considered the lambda transition and
superfluid regime in He-4, we focus on the vicinity of the critical point and
obtain good agreement with experimental results for the molar volume and the
internal energy down to subcritical temperatures. We find that an effective
classical potential that properly describes the two-particle radial
distribution function exhibits a strong temperature dependence near the
critical temperature. This contrasts with the behavior of essentially classical
systems like xenon, where the effective potential is independent of
temperature. It is conjectured that, owing to this difference in behavior
between classical and quantum-mechanical systems, the crossover behavior
observed for helium in the vicinity of the critical point differs qualitatively
from that of other simple liquids
Specifying security requirements improvement for IEEE Standard 830
This paper presents a concept on how the software requirements specifications template provided by IEEE Standard 830 could be updated to ensure that security is analyzed during the early stages of the software development lifecycle. This improved security requirement in the software requirements specifications will ensure that software developers will have a more clear understanding of how to protect digital information
Implicit Formulations of Bounded-Impulse Trajectory Models for Preliminary Interplanetary Low-Thrust Analysis
The bounded-impulse approach to low-thrust interplanetary trajectory optimization is widely used. In an effort to efficiently implement this approach using NASAs OpenMDAO optimization software, the authors have implemented implicit formulations of the forward shooting/backwards-shooting methods commonly used in bounded-impulse models. These implicit approaches allow for vectorization of the underlying calculations which can significantly reduce runtime in interpreted languages. An implicit approach may be either converged by using an underlying nonlinear solver to converge the state propagation, or as a constraint in an optimizer-driven multiple-shooting approach. Significant computational efficiency gains are realized through the utilization of the modular approach to unified derivatives. Further computational efficiency is achieved by capitalizing on the sparsity of the constraint Jacobian matrix. This work demonstrates that a vectorized multiple-shooting approach for propagating a state-time history is superior in terms of computational efficiency as the number of segments in the state-propagation is increased
Chemical Vapour Deposition of Amorphous Ru(P) Thin Films from Ru Trialkylphosphite Hydride Complexes
The ruthenium phosphite hydride complexes H2Ru(P(OR)(3))(4) (R = Me (1), Et (2), Pr-i (3)) were used as CVD precursors for the deposition of films of amorphous ruthenium-phosphorus alloys. The as-deposited films were X-ray amorphous and XPS analysis revealed that they were predominantly comprised of Ru and P in zero oxidation states. XPS analysis also showed the presence of small amounts of oxidized ruthenium and phosphorus. The composition of the films was found to depend on ligand chemistry as well as the deposition conditions. The use of H-2 as the carrier gas had the effect of increasing the relative concentrations of P and O for all films. Annealing films to 700 degrees C under vacuum produced films of polycrystalline hcp Ru while a flowing stream of H-2 resulted in polycrystalline hcp RuP.Welch Foundation F-816Petroleum Research FundAmerican Chemical Society 47014-ACSNSF 0741973Chemistr
Viscosity and thermal conductivity coefficients of gaseous and liquid oxygen
Equations and tables are presented for the viscosity and thermal conductivity coefficients of gaseous and liquid oxygen at temperatures between 80 K and 400 K for pressures up to 200 atm. and at temperatures between 80 K and 2000 K for the dilute gas. A description of the anomalous behavior of the thermal conductivity in the critical region is included. The tabulated coefficients are reliable to within about 15% except for a region in the immediate vicinity of the critical point. Some possibilities for future improvements of this reliability are discussed
Thermophysical properties of helium-4 from 4 to 3000 R with pressures to 15000 psia
Data on many of the properties of helium commonly used in engineering calculations are compiled over as wide a temperature and pressure range as is practical. These properties are presented in a form which is convenient to the engineer. All of these properties have been critically evaluated and represent the best values for that property at this time
Interactive FORTRAN IV computer programs for the thermodynamic and transport properties of selected cryogens (fluids pack)
The thermodynamic and transport properties of selected cryogens had programmed into a series of computer routines. Input variables are any two of P, rho or T in the single phase regions and either P or T for the saturated liquid or vapor state. The output is pressure, density, temperature, entropy, enthalpy for all of the fluids and in most cases specific heat capacity and speed of sound. Viscosity and thermal conductivity are also given for most of the fluids. The programs are designed for access by remote terminal; however, they have been written in a modular form to allow the user to select either specific fluids or specific properties for particular needs. The program includes properties for hydrogen, helium, neon, nitrogen, oxygen, argon, and methane. The programs include properties for gaseous and liquid states usually from the triple point to some upper limit of pressure and temperature which varies from fluid to fluid
Analytical Rescaling of Polymer Dynamics from Mesoscale Simulations
We present a theoretical approach to scale the artificially fast dynamics of
simulated coarse-grained polymer liquids down to its realistic value. As
coarse-graining affects entropy and dissipation, two factors enter the
rescaling: inclusion of intramolecular vibrational degrees of freedom, and
rescaling of the friction coefficient. Because our approach is analytical, it
is general and transferable. Translational and rotational diffusion of
unentangled and entangled polyethylene melts, predicted from mesoscale
simulations of coarse-grained polymer melts using our rescaling procedure, are
in quantitative agreement with united atom simulations and with experiments.Comment: 6 pages, 2 figures, 2 table
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