239 research outputs found

    How to protect a wind turbine from lightning

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    Techniques for reducing the chances of lightning damage to wind turbines are discussed. The methods of providing a ground for a lightning strike are discussed. Then details are given on ways to protect electronic systems, generating and power equipment, blades, and mechanical components from direct and nearby lightning strikes

    Statistical Model of Heavy-Ion Fusion-Fission Reactions

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    Cross-section and neutron-emission data from heavy-ion fusion-fission reactions are consistent with the fission of fully equilibrated systems with fission lifetime estimates obtained via a Kramers-modified statistical model which takes into account the collective motion of the system about the ground state, the temperature dependence of the location and height of fission transition points, and the orientation degree of freedom. If the standard techniques for calculating fission lifetimes are used, then the calculated excitation-energy dependence of fission lifetimes is incorrect. We see no evidence to suggest that the nuclear viscosity has a temperature dependence. The strong increase in the nuclear viscosity above a temperature of approximately 1.3 MeV deduced by others is an artifact generated by an inadequate fission model.Comment: Full paper submitted to PRC to accompany our recently published Phys. Rev. Lett. 101, 032702 (2008

    Exploring the Zone of Tolerance for Internal Customers in IT-Enabled Call Centers

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    Today, call center employees’ service encounters with external customers are extensively supported with modern information technology (IT). However, prior research on service quality and zone of tolerance (ZOT) focuses primarily on external customers with little attention paid to how internal customers (e.g., service employees) respond to services provided by internal functions, particularly IT function that supports employees’ IT use. Drawing on theory of administrative behavior and IT success literature, we conducted a study at a call center of a telecommunications firm and found that the impact of internal IT service quality (ITSQ) on employees’ service quality (ESQ) to external customers, as well as on their satisfaction with and use of the deployed technology, exhibits a positive diminishing pattern as ITSQ increases from below to within and to above the ZOT. We also found that ITSQ’s impact on ESQ employees\u27 satisfaction with technology changes more dramatically around adequate service level than desired service level. Finally, we show that call center employees’ satisfaction with technology partially mediates ITSQ’s impact on ESQ. Besides adding to the service and IT literature, our findings suggest that managers should understand internal customers’ different levels of expectations toward internal IT service and the differential performance impacts of those levels

    Regional Adoption of Business-to-Business Electronic Commerce in China: Role of E-Readiness

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    Adoption of B2B e-commerce is a powerful driver of economic success in developed and developing countries. However, adoption rates in developing countries lag far behind. This paper draws on the Perceived eReadiness Model and research on the influence of inter-organizational relationships and economic-cultural contexts to explain the importance of three factors—inter-organizational power dependence, cooperativeness, and regional economic-cultural differences—for achieving higher levels of Internet-based Electronic Data Interchange (EDI) in the developing country of China. We employ survey data to empirically test both the individual and joint influence of these factors. The findings suggest that beyond intra-organizational and external factors, managers and policy makers wanting to promote Internet-based EDI adoption in developing countries must also account for the inter-organizational relationships of firms and the economic and cultural circumstances of the regions in which they operate

    Managing uncertainty: a review of food system scenario analysis and modelling

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    Complex socio-ecological systems like the food system are unpredictable, especially to long-term horizons such as 2050. In order to manage this uncertainty, scenario analysis has been used in conjunction with food system models to explore plausible future outcomes. Food system scenarios use a diversity of scenario types and modelling approaches determined by the purpose of the exercise and by technical, methodological and epistemological constraints. Our case studies do not suggest Malthusian futures for a projected global population of 9 billion in 2050; but international trade will be a crucial determinant of outcomes; and the concept of sustainability across the dimensions of the food system has been inadequately explored so far. The impact of scenario analysis at a global scale could be strengthened with participatory processes involving key actors at other geographical scales. Food system models are valuable in managing existing knowledge on system behaviour and ensuring the credibility of qualitative stories but they are limited by current datasets for global crop production and trade, land use and hydrology. Climate change is likely to challenge the adaptive capacity of agricultural production and there are important knowledge gaps for modelling research to address

    Cation insertion to break the activity/stability relationship for highly active oxygen evolution reaction catalyst

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    The production of hydrogen at a large scale by the environmentally-friendly electrolysis process is currently hampered by the slow kinetics of the oxygen evolution reaction (OER). We report a solid electrocatalyst α-Li2IrO3 which upon oxidation/delithiation chemically reacts with water to form a hydrated birnessite phase, the OER activity of which is five times greater than its non-reacted counterpart. This reaction enlists a bulk redox process during which hydrated potassium ions from the alkaline electrolyte are inserted into the structure while water is oxidized and oxygen evolved. This singular charge balance process for which the electrocatalyst is solid but the reaction is homogeneous in nature allows stabilizing the surface of the catalyst while ensuring stable OER performances, thus breaking the activity/stability tradeoff normally encountered for OER catalysts

    An oxalate cathode for lithium ion batteries with combined cationic and polyanionic redox

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    Authors acknowledge financial support from the National Natural Science Foundation of China (51822210), the Australian Research Council (ARC) for its support through Discover Project (DP 140100193),Shenzhen Peacock Plan (KQJSCX20170331161244761), the Program for Guangdong Innovative and Entrepreneurial Teams (No. 2017ZT07C341), and the Development and Reform Commission of Shenzhen Municipality for the development of the “Low-Dimensional Materials and Devices” discipline.The growing demand for advanced lithium-ion batteries calls for the continued development of high-performance positive electrode materials. Polyoxyanion compounds are receiving considerable interest as alternative cathodes to conventional oxides due to their advantages in cost, safety and environmental friendliness. However, polyanionic cathodes reported so far rely heavily upon transition-metal redox reactions for lithium transfer. Here we show a polyanionic insertion material, Li2Fe(C2O4)2, in which in addition to iron redox activity, the oxalate group itself also shows redox behavior enabling reversible charge/discharge and high capacity without gas evolution. The current study gives oxalate a role as a family of cathode materials and suggests a direction for the identification and design of electrode materials with polyanionic frameworks.Publisher PDFPeer reviewe

    Oxygen redox chemistry without excess alkali-metal ions in Na2/3_{2/3}[Mg0.28_{0.28}Mn0.72_{0.72}]O2_2

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    The search for improved energy-storage materials has revealed Li- and Na-rich intercalation compounds as promising high-capacity cathodes. They exhibit capacities in excess of what would be expected from alkali-ion removal/reinsertion and charge compensation by transition-metal (TM) ions. The additional capacity is provided through charge compensation by oxygen redox chemistry and some oxygen loss. It has been reported previously that oxygen redox occurs in O 2pp orbitals that interact with alkali ions in the TM and alkali-ion layers (that is, oxygen redox occurs in compounds containing Li+^+–O(2pp)–Li+^+ interactions). Na2/3_{2/3}[Mg0.28_{0.28}Mn0.72_{0.72}]O2_2 exhibits an excess capacity and here we show that this is caused by oxygen redox, even though Mg2+^{2+} resides in the TM layers rather than alkali-metal (AM) ions, which demonstrates that excess AM ions are not required to activate oxygen redox. We also show that, unlike the alkali-rich compounds, Na2/3_{2/3}[Mg0.28_{0.28}Mn0.72_{0.72}]O2_2 does not lose oxygen. The extraction of alkali ions from the alkali and TM layers in the alkali-rich compounds results in severely underbonded oxygen, which promotes oxygen loss, whereas Mg2+^{2+} remains in Na2/3_{2/3}[Mg0.28_{0.28}Mn0.72_{0.72}]O2_2, which stabilizes oxygen
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