Crystal structure of mono-β-alanine hydrochloride

Crystal structure of mono-β-alaninium chloride has been studied by single crystal X-ray diffraction. The compound crystallizes in the orthorhombic system. The space group is Pbca, with the following lattice constants: a = 9.7414(5) Å, b = 7.4671(6) Å, c = 16.5288(11) Å, V = 1202.31(14) Å3, Z = 8. The asymmetric unit contains one β-alaninium cation (+NH3CH2CH2COOH) and one chloride anion. The structure was shown to consist of layers stacked along the c-axis and connected with each other by weak van der Waals forces. Each layer consists of two halves linked by hydrogen bonds between carbonyl and NH3+ groups and, also, between NH3+ groups and Cl- anions. Fourier transform infrared spectrum of β-alaninium chloride was recorded and analyzed. The spectroscopic results were found to support the conclusions of the structural study

THE MECHANISM OF DEALING WITH OVERDUE AND BAD DEBTS (NON-PERFORMING LOANS)IN A RETAIL LOAN PORTFOLIO OF RUSSIAN BANKS

The article is about arrears in a retail credit portfolio of the Russian banks as one of the key indicators of its quality. An essence of the concepts "overdue" and "problem loan debt" (or a non-performing loan) are specified, the amount of these terms, borders of their application are denoted it the article. In particular positions of some leading financial institutions on the designated perspective are explained in this article. The main objective of this item consists in the description of the mechanism of the organization of high-quality work with arrears with an emphasis on a retail loans portfolio

THE MECHANISM OF DEALING WITH OVERDUE AND BAD DEBTS (NON-PERFORMING LOANS)IN A RETAIL LOAN PORTFOLIO OF RUSSIAN BANKS

The article is about arrears in a retail credit portfolio of the Russian banks as one of the key indicators of its quality. An essence of the concepts "overdue" and "problem loan debt" (or a non-performing loan) are specified, the amount of these terms, borders of their application are denoted it the article. In particular positions of some leading financial institutions on the designated perspective are explained in this article. The main objective of this item consists in the description of the mechanism of the organization of high-quality work with arrears with an emphasis on a retail loans portfolio

Some problems of precise measurements of heat transfer coefficients in glass melts : Part 1. Measurements of effective conductivity

In the paper the method of measurements of the so-called effective conductivity of glass melts basing on characteristic of temperature gradient in a molten glass inside a refractory tank is analyzed. For this purpose a computer model based on the solution of the radiative transfer equation in a semitransparent medium was used. Among the papers on effective conductivity measurements published so far, only two contained enough numerical information on the details of measurement which permitted to perform the corresponding calculations. The authors of the present paper show what particular defects of experimental procedure could be the reason of surprising results reported in these publications, namely that the measured effective conductivity coefficient of a number of glasses was found to be lower than the radiative conductivity alone

Experimental thermochemical verification of trends in thermodynamic stability of hybrid perovskite-type organic-inorganic halides

Hybrid perovskite-type methylammonium lead halides have received great attention in recent years due to high conversion efficiency obtained in solar cells based on such materials. Since the time of the first demonstration photovoltaic devices based on the hybrid perovskites CH3NH3PbX3 (X = Cl, Br, I) have showed huge progress in increase of conversion efficiency reaching currently 20.1%. However, despite very promising achievements fundamental chemistry and physics of hybrid organic-inorganic (HOIP) perovskites is far from being completely understood. In particular it is true for thermodynamic properties of HOIP perovskite-type halides ABX3 and A2BX4 (A=CH3NH3, formamidinium, Cs, Rb, etc; B=Sn, Pb, 3d-element; X = Cl, Br, I). Moreover, reported results of DFT calculations aiming at estimating the stability of these materials often give controversial results. In addition, some of the HOIP perovskites (for example, CH3NH3PbX3 (X = Cl, Br, I)) are known to be entropy-stabilized phases. Therefore experimental verification of the stability trends in HOIP perovskite-type halide systems is strongly required. This is especially important for assessment of the stability of these materials under particular working conditions. Therefore, the main aim of this work was to study the thermodynamics of formation of HOIP perovskite-type halides ABX3 and A2BX4 (A=CH3NH3, formamidinium, Cs, Rb, etc; B=Sn, Pb, 3d-element; X = Cl, Br, I). Their standard formation enthalpy at 298 K was measured by solution calorimetry. Heat capacity was measured in the temperature range 2-298 K using PPMS system. Standard entropy was obtained by integration of the Cp/T vs T curve. Standard Gibbs free energy of ABX3 and A2BX4 (A=CH3NH3, formamidinium, Cs, Rb, etc; B=Sn, Pb, 3d-element; X = Cl, Br, I) was evaluated using measured formation enthalpy and entropy. Trends in variation of the thermodynamic functions with chemical composition and crystal structure of HOIP perovskite-type halides were analyzed and compared with available results of DFT calculations. This work was supported by the Russian Science Foundation (grant No. 18-73-10059)

Relationship between Diffusion, Selfdiffusion and Viscosity

We investigate the experimental limits of validity of the Stokes-Einstein equation. There is an important difference between diffusion and self-diffusion. There are experimental evidences, that in the case of self-diffusion the product D /T is constant and the equation is still valid. However, comparison of existing experimental data on viscosity and diffusion coefficients D of small, fast moving ions unambiguously show that the product D /T depends strongly on temperature T. The temperature dependence of diffusion coefficient declines from that of viscosity. Therefore, the Stokes-Einstein equation is not valid in this case