Potentiometric Determination of the Stability Constants of 2-, 3- and 4-Hydroxybutyrato Complexes of Cobalt(II), Nickel(II), Cadmium(II) and Lead(II)

The stability constants of the title complexes were determined potentiometrically using a quinhydrone electrode at (298.2 ± 0.1) K in buffer solutions of ionic strength 2 mol dm-3 adjusted by addition of NaC104• The numerical values of stability constants were evaluated from experimental data by computer program based on a weighted least squares method

Global torques and stochasticity as the drivers of massive black hole pairing in the young Universe

The forthcoming Laser Interferometer Space Antenna (LISA) will probe the population of coalescing massive black hole (MBH) binaries up to the onset of structure formation. Here we simulate the galactic-scale pairing of $\sim10^6 M_\odot$ MBHs in a typical, non-clumpy main-sequence galaxy embedded in a cosmological environment at $z = 7-6$. In order to increase our statistical sample, we adopt a strategy that allows us to follow the evolution of six secondary MBHs concomitantly. We find that the magnitude of the dynamical-friction induced torques is significantly smaller than that of the large-scale, stochastic gravitational torques arising from the perturbed and morphologically evolving galactic disc, suggesting that the standard dynamical friction treatment is inadequate for realistic galaxies at high redshift. The dynamical evolution of MBHs is very stochastic, and a variation in the initial orbital phase can lead to a drastically different time-scale for the inspiral. Most remarkably, the development of a galactic bar in the host system either significantly accelerates the inspiral by dragging a secondary MBH into the centre, or ultimately hinders the orbital decay by scattering the MBH in the galaxy outskirts. The latter occurs more rarely, suggesting that galactic bars overall promote MBH inspiral and binary coalescence. The orbital decay time can be an order of magnitude shorter than what would be predicted relying on dynamical friction alone. The stochasticity, and the important role of global torques, have crucial implications for the rates of MBH coalescences in the early Universe: both have to be accounted for when making predictions for the upcoming LISA observatory.Comment: Accepted for publication in MNRAS; 15 pages, 10 Figures, 2 Table

The final COS-B database: In-flight calibration of instrumental parameters

A method for the determination of temporal variation of sensitivity is designed to find a set of parameters which lead to maximum consistency between the intensities derived from different observation periods. This method is briefly described and the resulting sensitivity and background variations presented

Swiss ethnoveterinary knowledge on medicinal plants - a within-country comparison of Italian speaking regions with north-western German speaking regions

BACKGROUND: Ethnoveterinary knowledge in Europe may play an important role as a basis for sustainable treatment options for livestock. Aims of our study were (a) to compare the ethnoveterinary practices of two culturally and sociodemographically different regions of Switzerland, (b) to compare results with earlier ethnoveterinary studies conducted in Switzerland and in adjacent Italian regions and, (c) to evaluate possible reasons for regional differences in European ethnoveterinary medicine. METHODS: 25 interviews were conducted in 2014 in all Italian speaking regions (ItR) of Switzerland, and 31 interviews were held in five north-western German speaking Cantons (GeC). Semi-structured questionnaires were used to collect detailed information regarding plant species, mode of preparation, dosage, route of administration, category of use, origin of knowledge, frequency of use, and satisfaction with outcomes of the treatments. RESULTS: A total of 162 homemade remedies in ItR and 219 in GeC were reported, out of which 125 and 145, respectively, were reported to contain only one plant species (homemade single species herbal remedy report, HSHR). 44 ItR and 43 GeC plant species were reported to treat livestock, of which only a half were used in both regions. For each HSHR, we classified the treatment intention of all use reports (UR), leading to a total of 205 and 219 UR in ItR and GeC respectively. While cattle were the most often treated livestock species in both study regions, in ItR 40% of UR were administered to small ruminants. Main indications in both regions were gastrointestinal diseases and skin afflictions, but in ItR a high number of URs were reported as antiparasitics. URs were mainly handed down from the past generation, but in GeC the source of knowledge for 20% of URs were from courses. Regarding the used plant species, ItR showed a higher concordance with Swiss than Italian studies, but with some differences to all regions. A total of 22 (14 ItR; 8 GeC) plant species in this study have not been reported before in ethnoveterinary studies of Swiss and Italian alpine regions. CONCLUSIONS: ItR and GeC, show differences and similarities with respect to their own ethnoveterinary practices and earlier Swiss and Italian ethnoveterinary studies. Linguistic, geographical, as well as social and farm-structural conditions influence the regional ethnoveterinary knowledge. However, political borders seem to be more important than language or geographical barriers

Non-perturbative Interband Response of InSb Driven Off-resonantly by Few-cycle Electromagnetic Transients

Intense multi-THz pulses are used to study the coherent nonlinear response of bulk InSb by means of field-resolved four-wave mixing spectroscopy. At amplitudes above 5 MV/cm the signals show a clear temporal substructure which is unexpected in perturbative nonlinear optics. Simulations based on a two-level quantum system demonstrate that in spite of the strongly off-resonant character of the excitation the high-field pulses drive the interband resonances into a non-perturbative regime of Rabi flopping.Comment: 4 pages, 4 figure

Self-Energy Correction to the Two-Photon Decay Width in Hydrogenlike Atoms

We investigate the gauge invariance of the leading logarithmic radiative correction to the two-photon decay width in hydrogenlike atoms. It is shown that an effective treatment of the correction using a Lamb-shift "potential" leads to equivalent results in both the length as well as the velocity gauges provided all relevant correction terms are taken into account. Specifically, the relevant radiative corrections are related to the energies that enter into the propagator denominators, to the Hamiltonian, to the wave functions, and to the energy conservation condition that holds between the two photons; the form of all of these effects is different in the two gauges, but the final result is shown to be gauge invariant, as it should be. Although the actual calculation only involves integrations over nonrelativistic hydrogenic Green functions, the derivation of the leading logarithmic correction can be regarded as slightly more complex than that of other typical logarithmic terms. The dominant radiative correction to the 2S two-photon decay width is found to be -2.020536 (alpha/pi) (Zalpha)^2 ln[(Zalpha)^-2] in units of the leading nonrelativistic expression. This result is in agreement with a length-gauge calculation [S. G. Karshenboim and V. G. Ivanov, e-print physics/9702027], where the coefficient was given as -2.025(1).Comment: 9 pages, RevTe

HD 152246 - a new high-mass triple system and its basic properties

Analyses of multi-epoch, high-resolution (R ~ 50.000) optical spectra of the O-type star HD 152246 (O9 IV according to the most recent classification), complemented by a limited number of earlier published radial velocities, led to the finding that the object is a hierarchical triple system, where a close inner pair (Ba-Bb) with a slightly eccentric orbit (e = 0.11) and a period of 6.0049 days revolves in a 470-day highly eccentric orbit (e = 0.865) with another massive and brighter component A. The mass ratio of the inner system must be low since we were unable to find any traces of the secondary spectrum. The mass ratio A/(Ba+Bb) is 0.89. The outer system has recently been resolved using long-baseline interferometry on three occasions. The interferometry confirms the spectroscopic results and specifies elements of the system. Our orbital solutions, including the combined radial-velocity and interferometric solution indicate an orbital inclination of the outer orbit of 112{\deg} and stellar masses of 20.4 and 22.8 solar masses. We also disentangled the spectra of components A and Ba and compare them to synthetic spectra from two independent programmes, TLUSTY and FASTWIND. In either case, the fit was not satisfactory and we postpone a better determination of the system properties for a future study, after obtaining observations during the periastron passage of the outer orbit (the nearest chance being March 2015). For the moment, we can only conclude that component A is an O9 IV star with v*sin(i) = 210 +\- 10 km/s and effective temperature of 33000 +\- 500 K, while component Ba is an O9 V object with v*sin(i) = 65 +/- 3 km/s and T_eff = 33600 +\- 600 K.Comment: 9 pages, 6 figures, accepted for publication in Astronomy and Astrophysic

Failure of Effective Potential Approach: Nucleus-Electron Entanglement in the He-Ion

Entanglement may be considered a resource for quantum-information processing, as the origin of robust and universal equilibrium behaviour, but also as a limit to the validity of an effective potential approach, in which the influence of certain interacting subsystems is treated as a potential. Here we show that a closed three particle (two protons, one electron) model of a He-ion featuring realistic size, interactions and energy scales of electron and nucleus, respectively, exhibits different types of dynamics depending on the initial state: For some cases the traditional approach, in which the nucleus only appears as the center of a Coulomb potential, is valid, in others this approach fails due to entanglement arising on a short time-scale. Eventually the system can even show signatures of thermodynamical behaviour, i.e. the electron may relax to a maximum local entropy state which is, to some extent, independent of the details of the initial state.Comment: Submitted to Europhysics Letter