Evaluation of thiamethoxam 70% WS as seed treatment against early sucking pests of tomato

The present investigation was carried out at Vegetable Research Centre, G. B. Pant University of Agriculture and Technology, Pantnagar, Uttarakhand during the 2013 and 2014 to evaluate the effectiveness of thiamethoxam, used as seed treatment against the sucking insects of tomato. The seed treatment with thiamethoxam protected tomato seedlings from aphids and thrips at the early season from the onset of seed planting. There was a fast initial effect against the pests then gradually decreased to reach a moderate effect. Data revealed that Thiamethoxam 70% WS @ 4.2 g a.i./kg of seed showed the significant pest reduction followed by Thiamethoxam 70% WS @ 3.85 g a.i./kg of seed. Highest yield was recorded by Thiamethoxam 70% WS @ 4.2 g a.i./kg of seed (28.25 t/ha) closely followed by Thiamethoxam 70% WS @ 3.85 g a.i./kg of seed (25.00 t/ha) as compared to untreated check (20.91t/ha). Percent increase in yield over control was highest (35.10%) in Thiamethoxam 70% WS @ 4.2 g a.i./kg of seed followed by Thiamethoxam 70% WS @ 3.85 g a.i./kg of seed (19.56%). The percent reductions of predators by Thiamethoxam, used as seed treatment, in both the seasons ranged from 1.65- 2.58% which was very minimum. Hence, it was concluded that the seed treatment of tomato with Thiamethoxam 70% WS @ 4.20 g a.i/kg of seed reduced the early season insect-pests (aphid and thrips) and had very less effect of natural enemies population ascompared to control and also increased the fruit yield significantly than other treatments

Tetramer Orbital-Ordering induced Lattice-Chirality in Ferrimagnetic, Polar MnTi2O4

Using density-functional theory calculations and experimental investigations on structural, magnetic and dielectric properties, we have elucidated a unique tetragonal ground state for MnTi2O4, a Ti^{3+} (3d^1)-ion containing spinel-oxide. With lowering of temperature around 164 K, cubic MnTi2O4 undergoes a structural transition into a polar P4_1 tetragonal structure and at further lower temperatures, around 45 K, the system undergoes a paramagnetic to ferrimagnetic transition. Magnetic superexchange interactions involving Mn and Ti spins and minimization of strain energy associated with co-operative Jahn-Teller distortions plays a critical role in stabilization of the unique tetramer-orbital ordered ground state which further gives rise to lattice chirality through subtle Ti-Ti bond-length modulations

Shear Thickening Behaviour of Composite Propellant Suspension under Oscillatory Shear

Composite propellant suspensions consist of highly filled polymeric system wherein solid particles of different sizes and shapes are dispersed in a polymeric matrix. The rheological behaviour of a propellant suspension is characterised by viscoplasticity and shear rate and time dependant viscosity. The behaviour of composite propellant suspension has been studied under amplitude sweep test where tests were performed by continuously varying strain amplitude (strain in %, γ) by keeping the frequency and temperature constant and results are plotted in terms of log γ (strain amplitude) vs logGʹ and logGʺ (Storage modulus and loss modulus, respectively). It is clear from amplitude sweep test that dynamic moduli and complex viscosity show marked increase at critical strain amplitude after a plateau region, infering a shear thickening behaviour

Chromospheric Velocities of a C-class Flare

We use high spatial and temporal resolution observations from the Swedish Solar Telescope to study the chromospheric velocities of a C-class flare originating from active region NOAA 10969. A time-distance analysis is employed to estimate directional velocity components in H-alpha and Ca II K image sequences. Also, imaging spectroscopy has allowed us to determine flare-induced line-of-sight velocities. A wavelet analysis is used to analyse the periodic nature of associated flare bursts. Time-distance analysis reveals velocities as high as 64 km/s along the flare ribbon and 15 km/s perpendicular to it. The velocities are very similar in both the H-alpha and Ca II K time series. Line-of-sight H-alpha velocities are red-shifted with values up to 17 km/s. The high spatial and temporal resolution of the observations have allowed us to detect velocities significantly higher than those found in earlier studies. Flare bursts with a periodicity of approximately 60 s are also detected. These bursts are similar to the quasi-periodic oscillations observed at hard X-ray and radio wavelength data. Some of the highest velocities detected in the solar atmosphere are presented. Line-of-sight velocity maps show considerable mixing of both the magnitude and direction of velocities along the flare path. A change in direction of the velocities at the flare kernel has also been detected which may be a signature of chromospheric evaporation.Comment: Accepted for publication in Astronomy and Astrophysics, 5 figure

Enhancing the bioconversion of winery and olive mill waste mixtures into lignocellulolytic enzymes and animal feed by Aspergillus uvarum using a packed-bed bioreactor

Wineries and olive oil industries are dominant agro-industrial activities in southern European regions. Olive pomace, exhausted grape marc and vine shoot trimmings are lignocellulosic residues generated by these industries, which could be valued biotechnologically. In the present work these residues were used as substrate to produce cellulases and xylanases through solid-state fermentation using Aspergillus uvarum. For that, two factorial designs (32) were first planned to optimize substrate composition, temperature and initial moisture level. Subsequently, the kinectics of cellulolytic enzymes production, fungal growth and fermented solid were characterized, Finally, the process was performed in a packed-bed bioreactor. The results showed that cellulase activity improved with the optimization processes, reaching 33.56 U/g, and with the packed-bed bioreactor aeration of 0.2 L/min, reaching 38.51 U/g. The composition of fermented solids indicated their potential use for animal feed because cellulose, hemicellulose, lignin and phenolic compounds were partially degraded 28.08, 10.78, 13.3 and 28.32% respectively, crude protein was increased from 8.47% to 17.08%, and, the mineral contents meet the requirements of main livestock.J.M.S. was supported by Grant SFRH/BPD/84440/2012 from Fundacao para a Ciencia e Tecnologia (FCT), Portugal. L.A. was supported by Grant Incentivo/EQB/LA0023/2014 from O Novo Norte (ON.2). We thank FCT Strategic Project PEst-OE/EQB/LA0023/2013 and the Project "BioInd - Biotechnology and Bioengineering for improved Industrial and Agro-Food processes, Rer. NORTE-07-0124-FEDER-000028" co-funded by the Programa Operacional Regional do Norte (ON.2), QREN, FEDE

Oxidation of benzoin catalyzed by oxovanadium (IV) schiff base complexes

BACKGROUND: The oxidative transformation of benzoin to benzil has been accomplished by the use of a wide variety of reagents or catalysts and different reaction procedures. The conventional oxidizing agents yielded mainly benzaldehyde or/and benzoic acid and only a trace amount of benzil. The limits of practical utilization of these reagents involves the use of stoichiometric amounts of corrosive acids or toxic metallic reagents, which in turn produce undesirable waste materials and required high reaction temperatures. In recent years, vanadium complexes have attracted much attention for their potential utility as catalysts for various types of reactions. RESULTS: Active and selective catalytic systems of new unsymmetrical oxovanadium(IV) Schiff base complexes for the oxidation of benzoin is reported. The Schiff base ligands are derived between 2-aminoethanol and 2-hydroxy-1- naphthaldehyde (H2L1) or 3-ethoxy salicylaldehyde (H2L3); and 2-aminophenol and 3-ethoxysalicylaldehyde (H2L2) or 2-hydroxy-1-naphthaldehyde (H2L4). The unsymmetrical Schiff bases behave as tridentate dibasic ONO donor ligands. Reaction of these Schiff base ligands with oxovanadyl sulphate afforded the mononuclear oxovanadium(IV) complexes (VIVOLx.H2O), which are characterized by various physico-chemical techniques. The catalytic oxidation activities of these complexes for benzoin were evaluated using H2O2 as an oxidant. The best reaction conditions are obtained by considering the effect of solvent, reaction time and temperature. Under the optimized reaction conditions, VOL4 catalyst showed high conversion (>99%) with excellent selectivity to benzil (~100%) in a shorter reaction time compared to the other catalysts considered. CONCLUSION: Four tridentate ONO type Schiff base ligands were synthesized. Complexation of these ligands with vanadyl(IV) sulphate leads to the formation of new oxovanadium(IV) complexes of type VIVOL.H2O. Elemental analyses and spectral data of the free ligands and their oxovanadium(IV) complexes were found to be in good agreement with their structures, indicating high purity of all the compounds. Oxovanadium complexes were screened for the oxidation of benzoin to benzil using H2O2 as oxidant. The effect of time, solvent and temperature were optimized to obtain maximum yield. The catalytic activity results demonstrate that these catalytic systems are both highly active and selective for the oxidation of benzoin under mild reaction conditions.Web of Scienc

Understanding our seas: National Institute of Oceanography, Goa

The present article summarizes the research done at the CSIR–National Institute of Oceanography in 2014 in ocean science, resources and technology. Significant research has been conducted on air–sea interactions and coastal circulation, biogeochemistry, biology, marine geophysics, palaeoceanography, marine fishery, gas hydrates and wave energy. Technological advances covered topics like oceanographic tools. Major strides have been made in marine resources research and evaluation

Understanding our seas: National Institute of Oceanography, Goa

The present article summarizes the research done at the CSIR–National Institute of Oceanography in 2014 in ocean science, resources and technology. Significant research has been conducted on air–sea interactions and coastal circulation, biogeochemistry, biology, marine geophysics, palaeoceanography, marine fishery, gas hydrates and wave energy. Technological advances covered topics like oceanographic tools. Major strides have been made in marine resources research and evaluation

A Dual Receptor Crosstalk Model of G-Protein-Coupled Signal Transduction

Macrophage cells that are stimulated by two different ligands that bind to G-protein-coupled receptors (GPCRs) usually respond as if the stimulus effects are additive, but for a minority of ligand combinations the response is synergistic. The G-protein-coupled receptor system integrates signaling cues from the environment to actuate cell morphology, gene expression, ion homeostasis, and other physiological states. We analyze the effects of the two signaling molecules complement factors 5a (C5a) and uridine diphosphate (UDP) on the intracellular second messenger calcium to elucidate the principles that govern the processing of multiple signals by GPCRs. We have developed a formal hypothesis, in the form of a kinetic model, for the mechanism of action of this GPCR signal transduction system using data obtained from RAW264.7 macrophage cells. Bayesian statistical methods are employed to represent uncertainty in both data and model parameters and formally tie the model to experimental data. When the model is also used as a tool in the design of experiments, it predicts a synergistic region in the calcium peak height dose response that results when cells are simultaneously stimulated by C5a and UDP. An analysis of the model reveals a potential mechanism for crosstalk between the Gαi-coupled C5a receptor and the Gαq-coupled UDP receptor signaling systems that results in synergistic calcium release

Counter-current chromatography for the separation of terpenoids: A comprehensive review with respect to the solvent systems employed

Copyright @ 2014 The Authors.This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.Natural products extracts are commonly highly complex mixtures of active compounds and consequently their purification becomes a particularly challenging task. The development of a purification protocol to extract a single active component from the many hundreds that are often present in the mixture is something that can take months or even years to achieve, thus it is important for the natural product chemist to have, at their disposal, a broad range of diverse purification techniques. Counter-current chromatography (CCC) is one such separation technique utilising two immiscible phases, one as the stationary phase (retained in a spinning coil by centrifugal forces) and the second as the mobile phase. The method benefits from a number of advantages when compared with the more traditional liquid-solid separation methods, such as no irreversible adsorption, total recovery of the injected sample, minimal tailing of peaks, low risk of sample denaturation, the ability to accept particulates, and a low solvent consumption. The selection of an appropriate two-phase solvent system is critical to the running of CCC since this is both the mobile and the stationary phase of the system. However, this is also by far the most time consuming aspect of the technique and the one that most inhibits its general take-up. In recent years, numerous natural product purifications have been published using CCC from almost every country across the globe. Many of these papers are devoted to terpenoids-one of the most diverse groups. Naturally occurring terpenoids provide opportunities to discover new drugs but many of them are available at very low levels in nature and a huge number of them still remain unexplored. The collective knowledge on performing successful CCC separations of terpenoids has been gathered and reviewed by the authors, in order to create a comprehensive document that will be of great assistance in performing future purifications. © 2014 The Author(s)