9,355 research outputs found
On the hydraulic and structural design of fluid and gas filled inflatable dams to control water flow in rivers
The German Federal Waterways and Shipping Administration operates about 280 weirs, half of which are more than 50 years old. Many of these weirs will therefore need to be refurbished in the near future, even though budget resources are shrinking. An inflatable dam is a relatively new gate type, which enables savings to be made on the capital spending and maintenance costs. It consists of a multi-ply rubber membrane (Figure 1), is filled with air or water and clamped to the weir body with one or two fixing bars (Figure 2). Inflatable dams
have a number of advantages when compared with steel gates [2]:
- The design is simple and does not include any moving parts (hinges, bearings); there are no problems due to corrosion or sealing and no lubricants used, which might be harmful to the environment. Inflatable dams are not affected by settlements or earthquakes.
- Drive mechanisms, such as hydraulic cylinders, electrical actuators or chains, which require a great amount of maintenance are not needed. Inflatable dams are controlled by inflating or deflating by injecting and discharging air or water.
- The cost of recesses and reinforcement is low and the transfer of forces into the weir sill is evenly distributed. Major refurbishments are thus facilitated considerably, especially if the existing concrete structure has to be included.
- Inflatable dams can be operated safely and can always be deflated to prevent blocking. The membranes can be installed or replaced within a few weeks so that the construction times and periods for inspection and refurbishment are considerably reduced
Interfacial charge rearrangement and intermolecular interactions: Density-functional theory study of free-base porphine adsorbed on Ag(111) and Cu(111)
We employ dispersion-corrected density-functional theory to study the adsorption of tetrapyrrole 2H-porphine (2H-P) at Cu(111) and Ag(111). Various contributions to adsorbate-substrate and adsorbate-adsorbate interactions are systematically extracted to analyze the self-assembly behavior of this basic building block to porphyrin-based metal-organic nanostructures. This analysis reveals a surprising importance of substrate-mediated van der Waals interactions between 2H-P molecules, in contrast to negligible direct dispersive interactions. The resulting net repulsive interactions rationalize the experimentally observed tendency for single molecule adsorption
Interpretation of x-ray absorption spectroscopy in the presence of surface hybridization
X-ray absorption spectroscopy (XAS) yields direct access to the electronic and geometric structure of hybrid inorganic-organic interfaces formed upon adsorption of complex molecules at metal surfaces. The unambiguous interpretation of corresponding spectra is challenged by the intrinsic geometric flexibility of the adsorbates and the chemical interactions with the interface. Density-functional theory (DFT) calculations of the extended adsorbate-substrate system are an established tool to guide peak assignment in X-ray photoelectron spectroscopy of complex interfaces. We extend this to the simulation and interpretation of XAS data in the context of functional organic molecules on metal surfaces using dispersion-corrected DFT calculations within the transition potential approach. For the prototypical case of 2H-porphine adsorbed on Ag(111) and Cu(111) substrates, we follow the two main effects of the molecule/surface interaction onto the X-ray absorption signatures: (1) the substrate-induced chemical shift of the 1s core levels that dominates in physisorbed systems and (2) the hybridization-induced broadening and loss of distinct resonances that dominate in more chemisorbed systems
Advances in three-dimensional geoelectric forward solver techniques
Modern geoelectrical data acquisition systems allow large amounts of data to be collected in a short time. Inversions of such data sets require powerful forward solvers for predicting the electrical potentials. State-of-the-art solvers are typically based on finite elements. Recent developments in numerical mathematics led to direct matrix solvers that allow the equation systems arising from such finite element problems to be solved very efficiently. They are particularly useful for 3-D geoelectrical problems, where many electrodes are involved. Although modern direct matrix solvers include optimized memory saving strategies, their application to realistic, large-scale 3-D problems is still somewhat limited. Therefore, we present two novel techniques that allow the number of gridpoints to be reduced considerably, while maintaining a high solution accuracy. In the areas surrounding an electrode array we attach infinite elements that continue the electrical potentials to infinity. This does not only reduce the number of gridpoints, but also avoids the artificial Dirichlet or mixed boundary conditions that are well known to be the cause of numerical inaccuracies. Our second development concerns the singularity removal in the presence of significant surface topography. We employ a fast multipole boundary element method for computing the singular potentials. This renders unnecessary mesh refinements near the electrodes, which results in substantial savings of gridpoints of up to more than 50 per cent. By means of extensive numerical tests we demonstrate that combined application of infinite elements and singularity removal allows the number of gridpoints to be reduced by a factor of ≈6-10 compared with traditional finite element methods. This will be key for applying finite elements and direct matrix solver techniques to realistic 3-D inversion problem
Tomographic Quantum Cryptography: Equivalence of Quantum and Classical Key Distillation
The security of a cryptographic key that is generated by communication
through a noisy quantum channel relies on the ability to distill a shorter
secure key sequence from a longer insecure one. For an important class of
protocols, which exploit tomographically complete measurements on entangled
pairs of any dimension, we show that the noise threshold for classical
advantage distillation is identical with the threshold for quantum entanglement
distillation. As a consequence, the two distillation procedures are equivalent:
neither offers a security advantage over the other.Comment: 4 pages, 1 figur
Slow Release of Ions from Internalized Silver Nanoparticles Modifies the Epidermal Growth Factor Signaling Response
Due to their distinctive physiochemical properties, including a robust antibacterial activity and plasmonic capability, hundreds of consumer and medical products contain colloidal silver nanoparticles (AgNPs). However, even at sub-toxic dosages, AgNPs are able to disrupt cell functionality, through a yet unknown mechanism. Moreover, internalized AgNPs have the potential to prolong this disruption, even after the removal of excess particles. In the present study, we evaluated the impact, mechanism of action, and continual effects of 50 nm AgNP exposure on epidermal growth factor (EGF) signal transduction within a human keratinocyte (HaCaT) cell line. After AgNP expose, EGF signaling was initially obstructed due to the dissolution of particles into silver ions. However, at longer durations, the internalized AgNPs increased EGF signaling activity. This latter behavior correlated to sustained HaCaT stress, believed to be maintained through the continual dissolution of internalized AgNPs. This study raises concerns that even after exposure ceases, the retained nanomaterials are capable of acting as a slow-release mechanism for metallic ions; continually stressing and modifying normal cellular functionality
Ultrasound Investigations of Orbital Quadrupolar Ordering in UPd_3
For a high-quality single crystal of UPd_3 we present the relevant elastic
constants and ultrasonic attenuation data. In addition to the magnetic phase
transition at T_2=4.4 +/- 0.1K and the quadrupolar transition at T_1~6.8K, we
find orbital ordering at T_0=7.6 +/- 0.1K concomitant with a symmetry change
from hexagonal to orthorhombic. A striking feature is the splitting of the
phase transition at T_1 into a second-order transition at T_{+1}=6.9 +/- 0.05K
and a first-order transition at T_{-1}=6.7 +/- 0.05K. For the four phase
transitions, the quadrupolar order parameters and the respective symmetry
changes are specified.Comment: 14 pages (RevTex), 3 eps-figures, accepted by PR
Differential Dynamic Microscopy to characterize Brownian motion and bacteria motility
We have developed a lab work module where we teach undergraduate students how
to quantify the dynamics of a suspension of microscopic particles, measuring
and analyzing the motion of those particles at the individual level or as a
group. Differential Dynamic Microscopy (DDM) is a relatively recent technique
that precisely does that and constitutes an alternative method to more
classical techniques such as dynamics light scattering (DLS) or video particle
tracking (VPT). DDM consists in imaging a particle dispersion with a standard
light microscope and a camera. The image analysis requires the students to code
and relies on digital Fourier transform to obtain the intermediate scattering
function, an autocorrelation function that characterizes the dynamics of the
dispersion. We first illustrate DDM on the textbook case of colloids where we
measure the diffusion coefficient. Then we show that DDM is a pertinent tool to
characterize biologic systems such as motile bacteria i.e.bacteria that can
self propel, where we not only determine the diffusion coefficient but also the
velocity and the fraction of motile bacteria. Finally, so that our paper can be
used as a tutorial to the DDM technique, we have joined to this article movies
of the colloidal and bacterial suspensions and the DDM algorithm in both Matlab
and Python to analyze the movies
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