Graphene‐Based Materials Functionalization with Natural Polymeric Biomolecules

The use of 2D nanocarbon materials as scaffolds for the functionalization with different molecules has been rising as a result of their outstanding properties. This chapter describes the synthesis of graphene and its derivatives, particularly graphene oxide (GO) and reduced graphene oxide (rGO). Both GO and rGO represent a tunable alternative for applications with biomolecules due to the oxygenated moieties, which allow interactions in a either covalent or non‐covalent way. From here, other discussed topics are the biofunctionalization with keratin (KE) and chitosan (CS). The non‐covalent functionalization is based primarily on secondary interactions such as van der Waals forces, electrostatics interactions, or π–π stacking formed between KE or CS with graphenic materials. On the other hand, covalent functionalization with KE and CS is mainly based on the reaction among the functional groups present in those biomolecules and the graphenic materials. As a result of the functionalization, different applications have been proposed for these novel materials, which are reviewed in order to offer an overview about the possible fields of application of 2D nanocarbon materials. In a nutshell, the objective of this work is as follows: first, overhaul different aspects about the synthesis of graphene chemically obtained, and second, make a review of different approaches in the functionalization of 2D carbon materials with specific biomolecules

La familia y su organización en el cuidado de mayores en época post Covid en Zaragoza

El documento presente se trata de un Trabajo de Fin de Grado enfocado en conocer cómo es la organización de las familias en cuanto al cuidado de personas mayores en la provincia de Zaragoza, conociendo también los cambios y la influencia que ha tenido el Covid-19. La investigación se va a centrar en estudiar cómo se organizan los familiares de una persona mayor para proporcionarle los cuidados que necesita y los recursos que tienen para poder satisfacer sus necesidades, profundizando a su vez en las consecuencias que ha tenido la pandemia. Asimismo, el objetivo principal de este trabajo va a ser aproximarnos a la situación que viven estas familias encargadas del cuidado de una persona mayor conociendo sus inquietudes, las tareas que llevan a cabo y cómo se organizan, finalizando el trabajo con un análisis de los resultados obtenidos a partir de unas entrevistas realizadas a diferentes familias con estas características, conociendo su punto de vista sobre este tema para completar la investigación y relacionando este tema con el Trabajo Social. <br /

La familia y su organización en el cuidado de mayores en época post Covid en Zaragoza

El documento presente se trata de un Trabajo de Fin de Grado enfocado en conocer cómo es laorganización de las familias en cuanto al cuidado de personas mayores en la provincia de Zaragoza,conociendo también los cambios y la influencia que ha tenido el Covid-19. La investigación se va a centraren estudiar cómo se organizan los familiares de una persona mayor para proporcionarle los cuidados quenecesita y los recursos que tienen para poder satisfacer sus necesidades, profundizando a su vez en lasconsecuencias que ha tenido la pandemia. Asimismo, el objetivo principal de este trabajo va a seraproximarnos a la situación que viven estas familias encargadas del cuidado de una persona mayorconociendo sus inquietudes, las tareas que llevan a cabo y cómo se organizan, finalizando el trabajo con unanálisis de los resultados obtenidos a partir de unas entrevistas realizadas a diferentes familias con estascaracterísticas, conociendo su punto de vista sobre este tema para completar la investigación yrelacionando este tema con el Trabajo Social. <br /

Removal of Phenolic Compounds from Water by Adsorption and Photocatalysis

Phenolic compounds are important industrial wastes, and are classified as hazardous substances contaminating groundwater resources. Therefore, the removal or diminish of these organics compounds in order to reach the permitted levels before discharging becomes a challenging. Several processes have been developed to remove phenolic compounds from waters, including electrochemical oxidation, redox reactions, membrane separation and photocatalytic degradation. Recently, tendency of phenolic compounds removal involves adsorption and photocatalytic process, using synthetic or natural particles, such as carbon materials and clays. Actually, materials in nanometric scale play an important role in the processes previously mention due to their unique chemical and physical properties. In this book chapter, the first part shows the chemical properties of phenolic compounds that play an important role in the removal process. In the second part, different materials in macro, micro and nanosize used as adsorbents or photocatalysts are reviewed. In addition, other removal processes of phenolic compounds as electrochemistry and redox reactions are included. The removal conditions in these process, such as pH, adsorbate and adsorbent concentration are analyzed and discussed. Furthermore, special emphasis is included in micro and nanocarbon materials, used as adsorbents or photocatalyst to remove phenol from water in recently researches

Starch Modified With Chitosan and Reinforced With Feather Keratin Materials Produced by Extrusion Process: An Alternative to Starch Polymers

They also reached up to 3800% and 3150% in maximum strength, respectively, compared to the matrix. The lysozyme test showed relevant changes in the degradability rate, because the weight loss of the films at 3 weeks decreased from 53% for starch-chitosan matrix and up to 34% for composites with 5wt% of modified quill. The results corroborated that chicken feather materials can be useful for the development of a manufacturing process for starch composites, and the decomposition of starch-chitosan composites can be controlled depending on the content and type of keratin.Starch (potato), chitosan, and feather keratin are used for processing biodegradable films produced by extrusion. The morphology of the films is examined with a scanning electron microscope and showed the excellent dispersion of keratin. The dispersion is the result of compatibility between the polysaccharides and proteins, as well as the proper operation of the extrusion process. Water solubility of the starch-chitosan films decreased with an increase of keratin materials. The storage modulus increased up to 137% for the composites with unmodified ground quill, and by 192% for composites with modified ground quill. In a tensile test, the composites with unmodified and modified quill reached outstanding increments up to 8160 and 7250% in elastic modulus, respectively, compared to the matrixUniversidad Autonoma del Estado de Mexico Tecnologico Nacional de Mexico Universidad Nacional Autonoma de Mexico Universidad Autonoma de Cd. Juare

Analysis of qPCR reference genes stability determination methods and a practical approach for efficiency calculation on a turbot (Scphthalmus maximus) gonad dataset

Gene expression analysis by reverse transcription quantitative PCR (qPCR) is the most widely used method for analyzing the expression of a moderate number of genes and also for the validation of microarray results. Several issues are crucial for a successful qPCR study, particularly the selection of internal reference genes for normalization and efficiency determination. There is no agreement on which method is the best to detect the most stable genes neither on how to perform efficiency determination. In this study we offer a comprehensive evaluation of the characteristics of reference gene selection methods and how to decide which one is more reliable when they show discordant outcomes. Also, we analyze the current efficiency calculation controversy. Our dataset is composed by gonad samples of turbot at different development times reared at different temperatures. Turbot (Scophthalmus maximus) is a relevant marine aquaculture European species with increasing production in the incoming years. Since females largely outgrow males, identification of genes related to sex determination, gonad development and reproductive behavior, and analysis of their expression profiles are of primary importance for turbot industryVersión del edito

Effectiveness of Tysuacril in aphthous stomatitis

Introducción: el Tisuacryl es un biomaterial empleado en la cirugía general y bucal, así como en el tratamiento de la estomatitis aftosa, considerada un proceso multifactorial y actualmente la enfermedad ulcerosa más común de la cavidad oral.Objetivo: determinar la efectividad del Tisuacryl con respecto a la terapia convencional en el tratamiento de la estomatitis aftosa en Consolación del Sur, Pinar del Río, en el período comprendido entre septiembre 2018 y marzo 2020.Métodos: se realizó un estudio observacional analítico de casos y controles a 90 pacientes con estomatitis aftosa en Consolación del Sur, Pinar del Río, en el período comprendido entre septiembre 2018 y marzo 2020. La información se obtuvo de las historias clínicas individuales de Periodoncia al obtener el consentimiento oral y escrito de los pacientes o sus tutores. Los resultados se obtuvieron por análisis estadístico que incluyó el porciento y la prueba no paramétrica de Cochran Q.Resultados: predominó el sexo femenino y el grupo etario de 10 a 19 años para el 46,7 % en grupo estudio y el 42,2 % en grupo control; la disminución del dolor y la cicatrización iniciaron en el mayor número de pacientes a las 72 horas de tratamiento con Tisuacryl para el 91,1 % y el 55,6 % respectivamente; a los cinco días de aplicación del medicamento la totalidad de ellos estaban asintomáticos y casi todas las aftas bucales cicatrizadas.Conclusiones: las lesiones aftosas en la cavidad bucal evolucionaron satisfactoriamente con la aplicación del Tisuacryl al ser esta una alternativa efectiva de tratamiento en comparación con la terapia convencional.Introduction: Tisuacryl is a biomaterial used in general and oral surgery, as well as in the treatment of aphthous stomatitis, considered a multifactorial process and currently the most common ulcerative disease of the oral cavity.Objective: to determine the effectiveness of Tisuacryl with respect to conventional therapy in the treatment of aphthous stomatitis in Consolación del Sur, Pinar del Río, in the period from September 2018 to March 2020.Methods: an analytical observational case-control study was conducted on 90 patients with aphthous stomatitis in Consolación del Sur, Pinar del Río, in the period from September 2018 to March 2020. Information was obtained from individual Periodontics medical records by obtaining oral and written consent from patients or their guardians. Results were obtained by statistical analysis including percent and Cochran Q nonparametric test.Results: female sex and age group from 10 to 19 years old predominated for 46,7 % in the study group and 42,2 % in the control group; the decrease of pain and healing started in most patients 72 hours after treatment with Tisuacryl for 91,1 % and 55,6 % respectively; being five days after application of the drug all of them asymptomatic and almost all the oral aphthae healed.Conclusions: aphthous lesions in the oral cavity evolved satisfactorily with the application of Tisuacryl being an effective treatment alternative in comparison with conventional therapy