New palaeobotanical data from Carboniferous Culm deposits constrain the age of the Variscan deformation in the eastern Pyrenees

The pre-Variscan rocks of the Pyrenees exhibit a polyphase deformation linked to the Variscan crustal shortening and a low-pressure–high-temperature metamorphism. However, there is scarce chronostratigraphic evidence of this Variscan deformation. In the Pyrenean low-grade metamorphic domains, maximum ages have been provided by the synorogenic Carboniferous Culm deposits. In medium- to high-grade metamorphic areas, the Variscan regional metamorphism or intrusive magmatic bodies constrain the age of the main Variscan deformation structures. However, these data usually provide a minimum age. Here, we present new palaeobotanical records that assign a Namurian age to the base of the Culm deposits of la Cerdanya in the eastern Pyrenees. This dating is based on the co-occurrence of the sphenopsids Archaeocalamites radiatus, Mesocalamites cistiiformis and the seed of Cardiocarpus sp. The plant remains were found in sandstone facies produced by high-density turbidity flows of a deep-sea fan system. The new biostratigraphic information constrains the age of the Carboniferous Culm succession in the eastern Pyrenees

Revision of the Maastrichtian-Palaeocene charophyte biostratigraphy of the Fontllonga reference section (southern Pyrenees, Catalonia, Spain)

The Fontllonga section is one of the best-known stratigraphic sections wordwide for the study of charophyte biostratigraphy of the Maastrichtian and lower Palaeocene. An updated proposal for the charophyte biostratigraphy of this section is presented after summarizing previous knowledge. The zone of Peckichara cancellata allows the upper Campanian–lowermost Maastrichtian to be characterised in the base of the section (La Maçana Formation). The Microchara punctata biozone represents most of the Maastrichtian (Figuerola Formation). Within this biozone, a Clavator ultimus subzone is proposed to improve characterisation of the lower and middle Maastrichtian. Both the upper and lower boundaries of the Microchara punctata biozone proposed in previous studies are modified based on new occurrences of the index species. A charophyte assemblage belonging to the Dughiella bacillaris biozone is reported for the first time from the middle of the section (Perauba Complex) and provides an age for this unit ranging from the upper Danian to lower Thanetian. A foraminifer assemblage found in the basal marine deposits above the non-marine succession of the Fontllonga section provides new biostratigraphic data to locate the upper boundary of the non-marine succession at least within the upper Thanetian

The Iberian Chain: tertiary inversion of a mesozoic intraplate basin

The Mesozoic Iberian basin developed inside the Iberian plate in the eastern end of the Tethys sea. As a result of the Tertiary convergence between the Iberian plate with the European and African plates, the Iberian basin was contractionally inverted, giving rise to the Iberian and Catalan Coastal chains and the surrounding Tertiary basins. The Bouguer anomaly map of the area shows that the Iberian Chain has crustal roots which would have produced during the Tertiary contractional period

Calcareous algae (dasycladales and charophytes), essential for the sedimentological interpretation of ancient coastal-lakes systems. The Barremian-Aptian Leza Fm., Cameros Basin, N Spain

Depto. de Geodinámica, Estratigrafía y PaleontologíaFac. de Ciencias GeológicasTRUEpu

Estratigrafía del Cretácico inferior continental de la Cordillera Ibérica Central

Continental sedimentation during early Cretaceous in the Central part of the Iberian basin took place in two sedimentary sub-basins, the Oliete and Aguilón sub-basins. The stratigraphic analysis carried out in these units allows us to define new lithostratigraphical units. The biostratigraphy analysis of these units was based on charophytes. The identification of regional unconformities allows to define three depositional sequences. These sequences span from the Valanginian or Hauterivian to the Early Barremian, and may be correlated to sequences K1.2 or K1.3, K1.4 and K1.5 or K1.6 D.S., previously defined by Salas et al. (1991) and Salas & Casas (1993) in the eastem Maestrazgo basin. These results indicate that the stratigraphic record of the central part of the Iberian basin is as completed as that of the margin of the neighbouring Maestrazgo, Aliaga-Peñagolosa and Cameros basins.El Cretácico inferior continental de la Cordillera Ibérica Central está representado en dos subcuencas de sedimentación: las Cubetas de Aguilón y Oliete. Los estudios realizados sobre estos materiales han permitido definir nuevas unidades litoestratigráficas, cuya caracterización bioestratigráfica se realiza a partir de su contenido en carofitas. La identificación de discontinuidades significativas permiten definir tres secuencias de depósito que abarcan el intervalo temporal Valanguniense y/o Hauteriviense-Barremiense inferior y que son correlacionables con las S.D.K1.2 y/o K1.3, K1.4 YK1.5 y/o K1.6 definidas en Salas et al. (1991) y Salas y Casas (1993) para la Cuenca del Maestrazgo. Estos resultados ponen de manifiesto que el registro estratigráfico de la zona central de la Cordillera Ibérica tiene una entidad similar al de los márgenes de las Cuencas del Maestrazgo, Aliaga- Peñagolosa y Cameros

Clayey materials from the Sierra de la Demanda Range (Spain): their potential as raw materials for the building ceramics industry

This work describes the possible use of thick Early Cretaceous clay deposits, which occur in the southern sector of the Sierra de la Demanda range, as raw materials in the manufacture of ceramic articles. The global mineralogical composition is characterized by high proportions of phyllosilicates and quartz with variable quantities of feldspars, carbonates and hematite. The clay mineralogy differentiates two types of raw materials: illitic clay and kaolinitic-illitic clay. A granulometric distribution in the 2ÿ60 mm fraction, good behaviour during the drying stage and acceptable results in firing tests confirmed that most samples can be utilized as raw material in the building ceramics industry. The range of suitable firing temperatures for these materials is 950ÿ1000ëC, a temperature which needs to be raised for samples with a high percentage of kaolinite and quartz. Moreover, other materials with abundant calcite (20ÿ30%) are suitable for use as modifiers of some properties or colour

Critical evaluation of starch-based antibacterial nanocomposites as agricultural mulch films: Study on their interactions with water and light

In order to evaluate the potentiality of novel formulations based on starch to be used as agricultural mulch films, native and oxidized corn starch nanocomposites were prepared by extrusion using natural (Bent) and chitosan-modified bentonite (Bent-CS) fillers. The nanocomposite interactions with water were studied by means of moisture content (MC) determination, water solubility (WS), water vapor permeability (WVP), and contact angle (CA). The light transmission spectra were analyzed in order to determine the transparency and radiometric properties of films. Mechanical properties are also included and related with the cryo-fractured surface morphology observed by scanning electron microscopy (SEM). Finally, the antimicrobial action of developed nanocomposites was investigated against the phytopathogen bacterium Pseudomonas syringae pv tomato DC3000 (Psy). Results suggest that starch oxidation leads to a reduction in polarity and transparency. The incorporation of nanoclays improved water resistance but did not produce a significant effect in WVP and mechanical properties, and new strategies are required to improve the nanocomposite performance. However, the incorporation of Bent-CS exerted antibacterial activity on nanocomposites, which is an encouraging result.Fil: Merino, Danila. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Gutiérrez Carmona, Tomy José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Mansilla, Andrea Yamila. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Biológicas. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Biológicas; ArgentinaFil: Casalongue, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Biológicas. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Biológicas; ArgentinaFil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentin

Tafonomía y paleoecología del ecosistema acuático de Las Hoyas (Barremiense superior, Serranía de Cuenca).

The freshwater ecosystem of Las Hoyas contains one of the most significant records of aquatic organisms described from the Early Cretaceous worldwide. The benthos was formed by a diverse assemblage of animals such as aquatic insects, ostracods, cray-fishes, and juvenile and small adult fishes, which depended on the ground cover of charophytes and aquatic angiosperms for shelter and food. The nekton was mainly composed o f crustaceans and a large variety of fishes. Phytoplankton is represented by two chlorophytes and zooplankton is represented by planktonic pupae of dipterans. Cheirolepidiaceous conifers, matoniaceous tree-ferns and herbaceous schizaeacean ferns were growing in swamps. Among tetrapods with aquatic habitats modern amphibians and reptiles were found. In spite of the exceptional preservation, the fossil record of Las Hoyas includes sedimentological, taphonomic and palaeoecological biases. Form the palaeoecological point o f view, mass mortality levels contain thousands of individuals of crayfish associated with freshwater plant remains. These levels are attributed to eutrophication events of the otherwise oligotrophic lake. Other mass-mortality levels include hundreds of juvenile teleostean individuals associated with small shrimps. Changes in the water-table and related temperature changes, variation of acidity or input of toxic substances may account for this type of mass mortality