High-temperature synthesis, single-crystal X-ray and neutron powder diffraction, and materials properties of Sr3Ln10Si18Al12O18N36 (Ln = Ce, Pr, Nd)

The novel oxonitridoaluminosilicates (sialons) Sr3Ln10Si18Al12O18N36 (Ln = Ce, Pr, Nd) were obtained by the reaction of the respective lanthanide metals with Si(NH)2, SrCO3, and AlN using a radiofrequency furnace at temperatures between 1550–1650°C. The crystal structures of the isotypic sialons were determined by single-crystal X-ray investigations (Sr3Ce10Si18Al12O18N36: I3m, Z = 2, a = 1338.2(2) pm, R1 = 0.0333; Sr3Pr10Si18Al12O18N36: a = 1334.54(6) pm, R1 = 0.0296; Sr3Nd10Si18Al12O18N36: a = 1332.85(6) pm, R1 = 0.0271) and in the case of Sr3Pr10Si18Al12O18N36 with powder neutron diffraction as well. The three-dimensional sialon network is built up by SiON3, SiN4, and AlON3 tetrahedra. Besides the bridging O and N atoms of the sialon network there are isolated O2− which are tetrahedrally coordinated by Sr and Ln. The crystallographic differentiation of Si/Al and O/N seemed to be possible by a careful evaluation of the single-crystal X-ray diffraction data combined with lattice energy calculations using the MAPLE concept (Madelung Part of Lattice Energy). In the case of Sr3Pr10Si18Al12O18N36 the differentiation of O and N and the proposed ordering was completely confirmed by powder neutron diffraction

The Effects of Diffuse Ionized Gas and Spatial Resolution on Metallicity Gradients: TYPHOON Two-Dimensional Spectrophotometry of M83

We present a systematic study of the diffuse ionized gas (DIG) in M83 and its effects on the measurement of metallicity gradients at varying resolution scales. Using spectrophotometric data cubes of M83 obtained at the 2.5m duPont telescope at Las Campanas Observatory as part of the TYPHOON program, we separate the HII regions from the DIG using the [SII]/H$\alpha$ ratio, HIIphot (HII finding algorithm) and the H$\alpha$ surface brightness. We find that the contribution to the overall H$\alpha$ luminosity is approximately equal for the HII and DIG regions. The data is then rebinned to simulate low-resolution observations at varying resolution scales from 41 pc up to 1005 pc. Metallicity gradients are measured using five different metallicity diagnostics at each resolution. We find that all metallicity diagnostics used are affected by the inclusion of DIG to varying degrees. We discuss the reasons of why the metallicity gradients are significantly affected by DIG using the HII dominance and emission line ratio radial profiles. We find that applying the [SII]/H$\alpha$ cut will provide a closer estimate of the true metallicity gradient up to a resolution of 1005 pc for all metallicity diagnostics used in this study.Comment: 26 pages, 12 figures + Appendix/Supplementary Material, accepted for publication by MNRA

Starburst-AGN mixing: TYPHOON observations of NGC 1365, NGC 1068, and the effect of spatial resolution on the AGN fraction

We demonstrate a robust method of resolving the star-formation and AGN contributions to emission lines using two very well known AGN systems: NGC 1365, and NGC 1068, using the high spatial resolution data from the TYPHOON/PrISM survey. We expand the previous method of calculating the AGN fraction by using theoretical-based model grids rather than empirical points. The high spatial resolution of the TYPHOON/PrISM observations show evidence of both star formation and AGN activity occurring in the nuclei of the two galaxies. We rebin the data to the lower resolutions, typically found in other integral field spectroscopy surveys such as SAMI, MaNGA, and CALIFA. The results show that when rebinned from the native resolution of TYPHOON (< 200 pc/pixel) to 1 kpc/pixel, the effects include a roughly 3 kpc increase in the radius of measured AGN activity, and a factor of 2 to 7 increase in the detection of low surface brightness features such as shocks. All of this information is critical, because information on certain physical processes may be lost at varying resolutions. We make recommendations for analysing data at current IFU survey resolutions.Comment: 30 pages, 28 figures, accepted for publication by MNRA

The Stellar Populations and Evolution of Lyman Break Galaxies

Using deep near-IR and optical observations of the HDF-N from the HST NICMOS and WFPC2 and from the ground, we examine the spectral energy distributions (SEDs) of Lyman break galaxies (LBGs) at 2.0 < z < 3.5. The UV-to-optical rest-frame SEDs of the galaxies are much bluer than those of present-day spiral and elliptical galaxies, and are generally similar to those of local starburst galaxies with modest amounts of reddening. We use stellar population synthesis models to study the properties of the stars that dominate the light from LBGs. Under the assumption that the star-formation rate is continuous or decreasing with time, the best-fitting models provide a lower bound on the LBG mass estimates. LBGs with ``L*'' UV luminosities are estimated to have minimum stellar masses ~ 10^10 solar masses, or roughly 1/10th that of a present-day L* galaxy. By considering the effects of a second component of maximally-old stars, we set an upper bound on the stellar masses that is ~ 3-8 times the minimum estimate. We find only loose constraints on the individual galaxy ages, extinction, metallicities, initial mass functions, and prior star-formation histories. We find no galaxies whose SEDs are consistent with young (< 10^8 yr), dust-free objects, which suggests that LBGs are not dominated by ``first generation'' stars, and that such objects are rare at these redshifts. We also find that the typical ages for the observed star-formation events are significantly younger than the time interval covered by this redshift range (~ 1.5 Gyr). From this, and from the relative absence of candidates for quiescent, non-star-forming galaxies at these redshifts in the NICMOS data, we suggest that star formation in LBGs may be recurrent, with short duty cycles and a timescale between star-formation events of < 1 Gyr. [Abridged]Comment: LaTeX, 37 pages, 21 figures. Accepted for publication in the Astrophysical Journa

Repetitive Segmental Structure of the Transducin β Subunit: Homology with the CDC4 Gene and Identification of Related mRNAs

Retinal transducin, a guanine nucleotide regulatory protein (referred to as a G protein) that activates a cGMP phosphodiesterase in photoreceptor cells, is comprised of three subunits. We have identified and analyzed cDNA clones of the bovine transducin β subunit that may be highly conserved or identical to that in other G proteins. From the cDNA nucleotide sequence of the entire coding region, the primary structure of a 340-amino acid protein was deduced. The encoded β subunit has a Mr of 37,375 and is comprised of repetitive homologous segments arranged in tandem. Furthermore, significant homology in primary structure and segmental sequence exists between the β subunit and the yeast CDC4 gene product. The Mr 37,375 β subunit polypeptide is encoded by a 2.9-kilobase (kb) mRNA. However, there exists in retina other β-related mRNAs that are divergent from the 2.9-kb mRNA on the basis of oligonucleotide and primer-extended probe hybridizations. All mammalian tissues and clonal cell lines that have been examined contain at least two β-related mRNAs, usually 1.8 and 2.9 kb in length. These results suggest that the mRNAs are the processed products of a small number of closely related genes or of a single highly complex β gene

Integrating Cognitive Science with Innovative Teaching in STEM Disciplines

This volume collects the ideas and insights discussed at a novel conference, the Integrating Cognitive Science with Innovative Teaching in STEM Disciplines Conference, which was held September 27-28, 2012 at Washington University in St. Louis. With funding from the James S. McDonnell Foundation, the conference was hosted by Washington University’s Center for Integrative Research on Cognition, Learning, and Education (CIRCLE), a center established in 2011. Available for download as a PDF. Titles of individual chapters can be found at http://openscholarship.wustl.edu/circle_book/.https://openscholarship.wustl.edu/books/1009/thumbnail.jp

Observations of Binary Stars with the Differential Speckle Survey Instrument. V. Toward an Empirical Metal-Poor Mass-Luminosity Relation

In an effort to better understand the details of the stellar structure and evolution of metal poor stars, the Gemini North telescope was used on two occasions to take speckle imaging data of a sample of known spectroscopic binary stars and other nearby stars in order to search for and resolve close companions. The observations were obtained using the Differential Speckle Survey Instrument, which takes data in two filters simultaneously. The results presented here are of 90 observations of 23 systems in which one or more companions was detected, and 6 stars where no companion was detected to the limit of the camera capabilities at Gemini. In the case of the binary and multiple stars, these results are then further analyzed to make first orbit determinations in five cases, and orbit refinements in four other cases. Mass information is derived, and since the systems span a range in metallicity, a study is presented that compares our results with the expected trend in total mass as derived from the most recent Yale isochrones as a function of metal abundance. These data suggest that metal-poor main-sequence stars are less massive at a given color than their solar-metallicity analogues in a manner consistent with that predicted from the theory

The Stretched Lens Array SquareRigger (SLASR) for Space Power

For the past three years, our team has been developing, refining, and maturing a unique solar array technology known as Stretched Lens Array SquareRigger (SLASR). SLASR offers an unprecedented portfolio of state-of-the-art performance metrics, including areal power density, specific power, stowed power density, high-voltage capability, radiation hardness, modularity, scalability, mass-producibility, and cost-effectiveness. SLASR is particularly well suited to high-power space missions, including solar electric propulsion (SEP) space tugs, major exploration missions to the Moon and Mars, and power-intensive military spacecraft. SLASR is also very well suited to high-radiation missions, since the cell shielding mass penalty is 85% less for the SLASR concentrator array than for one-sun planar arrays. The paper describes SLASR technology and presents significant results of developments to date in a number of key areas, from advances in the key components to full-scale array hardware fabrication and evaluation. A summary of SLASR s unprecedented performance metrics, both near-term and longer term, will be presented. Plans for future SLASR developments and near-term space applications will also be outlined

Charge order at the frontier between the molecular and solid states in Ba3NaRu2O9

We show that the valence electrons of Ba3NaRu2O9, which has a quasi-molecular structure, completely crystallize below 210 K. Using an extended Hubbard model, we show that the charge ordering instability results from long-range Coulomb interactions. However, orbital ordering, metal-metal bonding and formation of a partial spin gap enforce the magnitude of the charge separation. The striped charge order and frustrated hcp lattice of Ru2O9 dimers lead to competition with a quasi-degenerate charge-melted phase under photo-excitation at low temperature. Our results establish a broad class of simple metal oxides as models for emergent phenomena at the border between the molecular and solid states.Comment: Minor changes, with supporting information. To appear in Phys. Rev. Let

New Constraints on the Lyman Continuum Escape Fraction at z~1.3

We examine deep far-ultraviolet (1600 Angstrom) imaging of the Hubble Deep Field-North (HDFN) and the Hubble Ultra Deep Field (HUDF) to search for leaking Lyman continuum radiation from starburst galaxies at z~1.3. There are 21 (primarily sub-L*) galaxies with spectroscopic redshifts between 1.1<z<1.5 and none are detected in the far-UV. We fit stellar population templates to the galaxies' optical/near-infrared SEDs to determine the starburst age and level of dust attenuation, giving an accurate estimate of the intrinsic Lyman continuum ratio, f_1500/f_700, and allowing a conversion from f_700 limits to relative escape fractions. We show that previous high-redshift studies may have underestimated the amplitude of the Lyman Break, and thus the relative escape fraction, by a factor of ~2. Once the starburst age and intergalactic HI absorption are accounted for, 18 galaxies in our sample have limits to the relative escape fraction, f_esc,rel < 1.0 with some limits as low as f_esc,rel < 0.10 and a stacked limit of f_esc,rel < 0.08. This demonstrates, for the first time, that most sub-L* galaxies at high redshift do not have large escape fractions. When combined with a similar study of more luminous galaxies at the same redshift we show that, if all star-forming galaxies at z~1 have similar relative escape fractions, the value must be less than 0.14 (3 sigma). We also show that less than 20% (3 sigma) of star-forming galaxies at z~1 have relative escape fractions near unity. These limits contrast with the large escape fractions found at z~3 and suggest that the average escape fraction has decreased between z~3 and z~1. (Abridged)Comment: Accepted for publication in ApJ. aastex format. 39 pages, 11 figure