CO2 storage monitoring: leakage detection and measurement in subsurface volumes from 3D seismic data at Sleipner

Demonstrating secure containment is a key plank of CO2 storage monitoring. Here we use the time-lapse 3D seismic surveys at the Sleipner CO2 storage site to assess their ability to provide robust and uniform three-dimensional spatial surveillance of the Storage Complex and provide a quantitative leakage detection tool. We develop a spatial-spectral methodology to determine the actual detection limits of the datasets which takes into account both the reflectivity of a thin CO2 layer and also its lateral extent. Using a tuning relationship to convert reflectivity to layer thickness, preliminary analysis indicates that, at the top of the Utsira reservoir, CO2 accumulations with pore volumes greater than about 3000 m3 should be robustly detectable for layer thicknesses greater than one metre, which will generally be the case. Making the conservative assumption of full CO2 saturation, this pore volume corresponds to a CO2 mass detection threshold of around 2100 tonnes. Within the overburden, at shallower depths, CO2 becomes progressively more reflective, less dense, and correspondingly more detectable, as it passes from the dense phase into a gaseous state. Our preliminary analysis indicates that the detection threshold falls to around 950 tonnes of CO2 at 590 m depth, and to around 315 tonnes at 490 m depth, where repeatability noise levels are particularly low. Detection capability can be equated to the maximum allowable leakage rate consistent with a storage site meeting its greenhouse gas emissions mitigation objective. A number of studies have suggested that leakage rates around 0.01% per year or less would ensure effective mitigation performance. So for a hypothetical large-scale storage project, the detection capability of the Sleipner seismics would far exceed that required to demonstrate the effective mitigation leakage limit. More generally it is likely that well-designed 3D seismic monitoring systems will have robust 3D detection capability significantly superior to what is required to prove greenhouse gas mitigation efficacy

Changes in groundwater drought associated with anthropogenic warming

Here we present the first empirical evidence for changes in groundwater drought associated with anthropogenic warming in the absence of long-term changes in precipitation. Analysing standardised indices of monthly groundwater levels, precipitation and temperature, using two unique groundwater level data sets from the Chalk aquifer, UK, for the period 1891 to 2015, we show that precipitation deficits are the main control on groundwater drought formation and propagation. However, long-term changes in groundwater drought are shown to be associated with anthropogenic warming over the study period. These include increases in the frequency and intensity of individual groundwater drought months, and increases in the frequency, magnitude and intensity of episodes of groundwater drought, as well as an increasing tendency for both longer episodes of groundwater drought and for an increase in droughts of less than 1 year in duration. We also identify a transition from a coincidence of episodes of groundwater drought with precipitation droughts at the end of the 19th century, to an increasing coincidence with both precipitation droughts and with hot periods in the early 21st century. In the absence of long-term changes in precipitation deficits, we infer that the changing nature of groundwater droughts is due to changes in evapotranspiration (ET) associated with anthropogenic warming. We note that although the water tables are relatively deep at the two study sites, a thick capillary fringe of at least 30 m in the Chalk means that ET should not be limited by precipitation at either site. ET may be supported by groundwater through major episodes of groundwater drought and, hence, long-term changes in ET associated with anthropogenic warming may drive long-term changes in groundwater drought phenomena in the Chalk aquifer. Given the extent of shallow groundwater globally, anthropogenic warming may widely effect changes to groundwater drought characteristics in temperate environments

Estimating organic surface horizon depth for peat and peaty soils across a Scottish upland catchment using linear mixed models with topographic and geological covariates

In order to evaluate and protect ecosystem services provided by peat and peaty soils, accurate estimations for the depth of the surface organic horizon are required. This study uses linear mixed models (LMMs) to test how topographic (elevation, slope, aspect) and superficial geology parameters can contribute to improved depth estimates across a Scottish upland catchment. Mean (n = 5) depth data from 283 sites (representing full covariate ranges) were used to calibrate LMMs, which were tested against a validation dataset. Models were estimated using maximum likelihood, and the Akaike Information Criterion was used to test whether the iterative addition of covariates to a model with constant fixed effects was beneficial. Elevation, slope and certain geology classes were all identified as useful covariates. Upon addition of the random effects (i.e. spatial modelling of residuals), the RMSE for the model with constant‐only fixed effects reduced by 24%. Addition of random effects to a model with topographic covariates (fixed effects = constant, slope, elevation) reduced the RMSE by 13%, whereas the addition of random effects to a model with topographic and geological covariates (fixed effects = constant, slope, elevation, certain geology classes) reduced the RMSE by only 3%. Therefore, much of the spatial pattern in depth was explained by the fixed effects in the latter model. The study contributes to a growing research base demonstrating that widely available topographic (and also here geological) datasets, which have national coverage, can be included in spatial models to improve organic horizon depth estimations

Combinatorial microfluidic droplet engineering for biomimetic material synthesis

Although droplet-based systems are used in a wide range of technologies, opportunities for systematically customizing their interface chemistries remain relatively unexplored. This article describes a new microfluidic strategy for rapidly tailoring emulsion droplet compositions and properties. The approach utilizes a simple platform for screening arrays of droplet-based microfluidic devices and couples this with combinatorial selection of the droplet compositions. Through the application of genetic algorithms over multiple screening rounds, droplets with target properties can be rapidly generated. The potential of this method is demonstrated by creating droplets with enhanced stability, where this is achieved by selecting carrier fluid chemistries that promote titanium dioxide formation at the droplet interfaces. The interface is a mixture of amorphous and crystalline phases, and the resulting composite droplets are biocompatible, supporting in vitro protein expression in their interiors. This general strategy will find widespread application in advancing emulsion properties for use in chemistry, biology, materials and medicine

Improved understanding of spatio-temporal controls on regional scale groundwater flooding using hydrograph analysis and impulse response functions

Controls on the spatiotemporal extent of groundwater flooding are poorly understood, despite the long duration of groundwater flood events and distinct social and economic impacts. We developed a novel approach using statistical analysis of groundwater level hydrographs and impulse response functions (IRFs) and applied it to the 2013/14 Chalk groundwater flooding in the English Lowlands. We proposed a standardised index of groundwater flooding which we calculated for monthly groundwater levels for 26 boreholes in the Chalk. We grouped these standardised series using k-means cluster analysis and cross-correlated the cluster centroids with the Standardised Precipitation Index (SPI) accumulated over time intervals between 1 and 60 months. This analysis reveals two spatially coherent groups of standardised hydrographs which responded to precipitation over different timescales. We estimated IRF models of the groundwater level response to effective precipitation for three boreholes in each group. The IRF models corroborate the SPI analysis showing different response functions between the groups. We applied identical effective precipitation inputs to each of the IRF models and observed differences between the hydrographs from each group. It is suggested this is due to the hydrogeological properties of the Chalk and of overlying relatively low permeability superficial deposits (recent unconsolidated sediments overlying the bedrock, such as clays and tills), which are extensive over one of the groups. The overarching controls on groundwater flood response are concluded to be a complex combination of antecedent conditions, rainfall and catchment hydrogeological properties. These controls should be taken into consideration when anticipating and managing future groundwater flood events. The approach presented is generic and parsimonious and can be easily applied where sufficient groundwater level and rainfall data are available

“Dogged” Search of Fresh Nakhla Surfaces Reveals New Alteration Textures

Special Issue: 74th Annual Meeting of the Meteoritical Society, August 8-12, 2011, London, U.K.International audienceCarbonaceous chondrites are considered as amongst the most primitive Solar System samples available. One of their primitive characteristics is their enrichment in volatile elements.This includes hydrogen, which is present in hydrated and hydroxylated minerals. More precisely, the mineralogy is expected to be dominated by phyllosilicates in the case of CM chondrites, and by Montmorillonite type clays in the case of CI. Here, in order to characterize and quantify the abundance of lowtemperature minerals in carbonaceous chondrites, we performed thermogravimetric analysis of matrix fragments of Tagish Lake, Murchison and Orgueil

Mechanisms of SARS-CoV-2 neutralization by shark variable new antigen receptors elucidated through X-ray crystallography

Acknowledgements This work was supported by the Chief Scientist Office, Scottish Government, Grant COV/ABN/20/01 (Elasmogen, Ltd.), a 2018 Prostate Cancer Foundation Challenge Award (AML), a 2013 Prostate Cancer Foundation Young Investigator Award (AML), NCI R01s CA237272, CA233562, and CA245922 (AML). WEM was supported by the NIH T32 HL007741 and JMT by the NIH T32 AI055433. JSM was funded by NIGMS R01 GM088790. HA was funded by NIGMS R35 GM118047 and NCI P01 CA234228. X-ray diffraction data were collected at the Northeastern Collaborative Access Team beamlines, which are funded by the US National Institutes of Health (NIGMS P30 GM124165). The Pilatus 6M detector on 24-ID-C beamline is funded by a NIH-ORIP HEI grant (S10 RR029205). We thank the Marco Pravetoni lab for providing training and access to the OctetRED96e for BLI experiments.Peer reviewedPublisher PD

Recommendations for Nanomedicine Human Subjects Research Oversight: An Evolutionary Approach for an Emerging Field

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/96363/1/j.1748-720X.2012.00703.x.pd

Understanding How Social Entrepreneurs Fit into the Tourism Discourse

This chapter discusses how social entrepreneurs fit into the existing tourism discourse. It examines four areas of literature in particular, tourism entrepreneurs, sustainability, destination development and intrapreneurship, and analyzes how introducing the concept of social entrepreneurs into these discussions is useful, and contributes to our understanding. Furthermore the paper illustrates that as social entrepreneurs are relevant to a broad range of issues in the tourism literature this should prevent the development of research silos where social entrepreneurship scholars seek out their own vein of research. The nexus of common ground and interests, as displayed in this chapter, should enhance the development of research, thought and understanding of social entrepreneurs within the field as a whole The key argument is that research on social entrepreneurs is not just relevant for those interested in entrepreneurs it also effects our thinking on issues such as destination development, relationships between stakeholders, tourism policy and sustainability. The chapter concludes with a wide range of questions for further research