Particle density and non-local kinetic energy density functional for two-dimensional harmonically confined Fermi vapors

We evaluate analytically some ground state properties of two-dimensional harmonically confined Fermi vapors with isotropy and for an arbitrary number of closed shells. We first derive a differential form of the virial theorem and an expression for the kinetic energy density in terms of the fermion particle density and its low-order derivatives. These results allow an explicit differential equation to be obtained for the particle density. The equation is third-order, linear and homogeneous. We also obtain a relation between the turning points of kinetic energy and particle densities, and an expression of the non-local kinetic energy density functional.Comment: 7 pages, 2 figure

Preferred orientation of n-hexane crystallized in silicon nanochannels: A combined x-ray diffraction and sorption isotherm study

We present an x-ray diffraction study on n-hexane in tubular silicon channels of approximately 10 nm diameter both as a function of the filling fraction f of the channels and as a function of temperature. Upon cooling, confined n-hexane crystallizes in a triclinic phase typical of the bulk crystalline state. However, the anisotropic spatial confinement leads to a preferred orientation of the confined crystallites, where the crystallographic direction coincides with the long axis of the channels. The magnitude of this preferred orientation increases with the filling fraction, which corroborates the assumption of a Bridgman-type crystallization process being responsible for the peculiar crystalline texture. This growth process predicts for a channel-like confinement an alignment of the fastest crystallization direction parallel to the long channel axis. It is expected to be increasingly effective with the length of solidifying liquid parcels and thus with increasing f. In fact, the fastest solidification front is expected to sweep over the full silicon nanochannel for f=1, in agreement with our observation of a practically perfect texture for entirely filled nanochannels

Statistical Description of Hydrodynamic Processes in Ionic Melts with taking into account Polarization Effects

Statistical description of hydrodynamic processes for ionic melts is proposed with taking into account polarization effects caused by the deformation of external ionic shells. This description is carried out by means of the Zubarev nonequilibrium statistical operator method, appropriate for investigations of both strong and weak nonequilibrium processes. The nonequilibrium statistical operator and the generalized hydrodynamic equations that take into account polarization processes are received for ionic-polarization model of ionic molten salts when the nonequilibrium averaged values of densities of ions number, their momentum, dipole momentum and total energy are chosen for the reduced description parameters. A spectrum of collective excitations is investigated within the viscoelastic approximation for ion-polarization model of ionic melts.Comment: 24 pages, RevTex4.1-format, no figure

Practical dispersion relations for strongly coupled plasma fluids

Very simple explicit analytical expressions are discussed, which are able to describe the dispersion relations of longitudinal waves in strongly coupled plasma systems such as one-component plasma and weakly screened Yukawa fluids with a very good accuracy. Applications to other systems with soft pairwise interactions are briefly discussed.Comment: 11 pages, 3 figures; Related to arXiv:1711.0615

Power, norms and institutional change in the European Union: the protection of the free movement of goods

How do institutions of the European Union change? Using an institutionalist approach, this article highlights the interplay between power, cognitive limits, and the normative order that underpins institutional settings and assesses their impact upon the process of institutional change. Empirical evidence from recent attempts to reinforce the protection of the free movement of goods in the EU suggests that, under conditions of uncertainty, actors with ambiguous preferences assess attempts at institutional change on the basis of the historically defined normative order which holds a given institutional structure together. Hence, path dependent and incremental change occurs even when more ambitious and functionally superior proposals are on offer

Ab initio wavefunction based methods for excited states in solids: correlation corrections to the band structure of ionic oxides

Ab initio wavefunction based methods are applied to the study of electron correlation effects on the band structure of oxide systems. We choose MgO as a prototype closed-shell ionic oxide. Our analysis is based on a local Hamiltonian approach and performed on finite fragments cut from the infinite solid. Localized Wannier functions and embedding potentials are obtained from prior periodic Hartree-Fock (HF) calculations. We investigate the role of various electron correlation effects in reducing the HF band gap and modifying the band widths. On-site and nearest-neighbor charge relaxation as well as long-range polarization effects are calculated. Whereas correlation effects are essential for computing accurate band gaps, we found that they produce smaller changes on the HF band widths, at least for this material. Surprisingly, a broadening effect is obtained for the O 2p valence bands. The ab initio data are in good agreement with the energy gap and band width derived from thermoreflectance and x-ray photoemission experiments. The results show that the wavefunction based approach applied here allows for well controlled approximations and a transparent identification of the microscopic processes which determine the electronic band structure

Temperature dependence of density profiles for a cloud of non-interacting fermions moving inside a harmonic trap in one dimension

We extend to finite temperature a Green's function method that was previously proposed to evaluate ground-state properties of mesoscopic clouds of non-interacting fermions moving under harmonic confinement in one dimension. By calculations of the particle and kinetic energy density profiles we illustrate the role of thermal excitations in smoothing out the quantum shell structure of the cloud and in spreading the particle spill-out from quantum tunnel at the edges. We also discuss the approach of the exact density profiles to the predictions of a semiclassical model often used in the theory of confined atomic gases at finite temperature.Comment: 7 pages, 4 figure

Information entropy and nucleon correlations in nuclei

The information entropies in coordinate and momentum spaces and their sum ($S_r$, $S_k$, $S$) are evaluated for many nuclei using "experimental" densities or/and momentum distributions. The results are compared with the harmonic oscillator model and with the short-range correlated distributions. It is found that $S_r$ depends strongly on $\ln A$ and does not depend very much on the model. The behaviour of $S_k$ is opposite. The various cases we consider can be classified according to either the quantity of the experimental data we use or by the values of $S$, i.e., the increase of the quality of the density and of the momentum distributions leads to an increase of the values of $S$. In all cases, apart from the linear relation $S=a+b\ln A$, the linear relation $S=a_V+b_V \ln V$ also holds. V is the mean volume of the nucleus. If $S$ is considered as an ensemble entropy, a relation between $A$ or $V$ and the ensemble volume can be found. Finally, comparing different electron scattering experiments for the same nucleus, it is found that the larger the momentum transfer ranges, the larger the information entropy is. It is concluded that $S$ could be used to compare different experiments for the same nucleus and to choose the most reliable one.Comment: 14 pages, 4 figures, 2 table

Correlations in a two-dimensional Bose gas with long range interactions

We study the correlations of two-dimensional dipolar excitons in coupled quantum wells with a dipole -- dipole repulsive interaction. We show that at low concentrations, the Bose degeneracy of the excitons is accompanied by strong multi-particle correlations and the system behaves as a Bose liquid. At high concentration the particles interaction suppresses quantum coherence and the system behaves similar to a classical liquid down to a temperature lower than typical for a Bose gas. We evaluate the interaction energy per particle and the resulting blue shift of the exciton luminescence that is a direct tool to measure the correlations. This theory can apply to other systems of bosons with extended interaction.Comment: 11 pages including 2 figure

Dynamical generalization of a solvable family of two-electron model atoms with general interparticle repulsion

Holas, Howard and March [Phys. Lett. A {\bf 310}, 451 (2003)] have obtained analytic solutions for ground-state properties of a whole family of two-electron spin-compensated harmonically confined model atoms whose different members are characterized by a specific interparticle potential energy u($r_{12}$). Here, we make a start on the dynamic generalization of the harmonic external potential, the motivation being the serious criticism levelled recently against the foundations of time-dependent density-functional theory (e.g. [J. Schirmer and A. Dreuw, Phys. Rev. A {\bf 75}, 022513 (2007)]). In this context, we derive a simplified expression for the time-dependent electron density for arbitrary interparticle interaction, which is fully determined by an one-dimensional non-interacting Hamiltonian. Moreover, a closed solution for the momentum space density in the Moshinsky model is obtained.Comment: 5 pages, submitted to J. Phys.