Ventilation and cave air PCO2 in the Bunker-Emst Cave System (NW Germany): implications for speleothem proxy data

Cave air pCO2 (carbon dioxide partial pressure) is, along with drip rate, one of the most important factors controlling speleothem carbonate precipitation. As a consequence, pCO2 has an indirect but important control on speleothem proxy data (e.g., elemental concentrations, isotopic values). The CO2 concentration of cave air depends on CO2 source(s) and productivity, CO2 transport through the epikarst and karst zone, and cave air ventilation. To assess ventilation patterns in the Bunker-Emst Cave (BEC) System, we monitored the pCO2 value approximately 100 m from the lower entrance (Bunker Cave) at bi-hourly resolution between April 2012 and February 2014. The two entrances of the BEC system were artificially opened between 1860?1863 (Emst Cave) and 1926 (Bunker Cave). Near-atmospheric minimum pCO2dynamics of 408 ppmv are measured in winter, and up to 811 ppmv are recorded in summer. Outside air contributes the highest proportion to cave air CO2, while soil, and possibly also ground air, provide a far smaller proportion throughout the whole year. Cave air pCO2 correlates positively with the temperature difference between surface and cave air during summer and negatively in winter, with no clear pattern for spring and autumn. Dynamic ventilation is driven by temperature and resulting density differences between cave and surface air. In summer, warm atmospheric air is entrained through the upper cave entrance where it cools. With increasing density, the cooled air flows toward the lower entrance. In winter, this pattern is reversed, due to cold, atmospheric air entering the cave via the lower entrance, while relatively warm cave air rises and exits the cave via the upper entrance. The situation is further modulated by preferential south-southwestern winds that point directly on both cave entrances. Thus, cave ventilation is frequently disturbed, especially during periods with higher wind speed. Modern ventilation of the BEC system-induced by artificially openings-is not a direct analogue for pre-1860 ventilation conditions. The artificial change of ventilation resulted in a strong increase of ?13Cspeleothem values. Prior to the cave opening in 1860, Holocene ?13Cspeleothem values were significantly lower, probably related to limited ventilation due to the lack of significant connections between the surface and cave. Reduced ventilation led to significantly higher pCO2 values, minimal CO2 degassing from drip water and low kinetic isotope fractionation. Both modern and fossil speleothem precipitation rates are driven by water supply and carbonate saturation, and not by cave air pCO2. Today, pCO2 variability is too small to affect carbonate precipitation rates and the same is likely true for pCO2 variability prior to artificial opening of the cave. Thus, fossil speleothems from BEC System are likely more sensitive to temperature and infiltration dynamics. The Bunker-Emst Cave System, therefore, represents different ventilation patterns and their influence on speleothem proxy data in an exemplary manner, and it may serve as a template for other cave systems

Hipóteses de revisão da sentença inconstitucional e a aplicabilidade da súmula 343 do STF

Orientador: Clayton de Albuquerque MaranhãoMonografia (graduação) - Universidade Federal do Paraná, Setor de Ciências Jurídicas, Curso de Graduação em DireitoResumo: Nos últimos anos um complexo fenômeno tem agitado a prática forense nos tribunais brasileiro: o manejo de ações rescisórias, sob o fundamento de literal violação à disposição de lei (art. 485, V, do CPC), quando o Supremo Tribunal Federal, em sede de controle de constitucionalidade, profere decisão em sentido contrário a decisão que está sendo objeto de rescisão. A jurisprudência passou a não aplicar a Súmula 343 do STF quando se tratar de matéria constitucional, de modo que seria possível o uso de ação rescisória no caso de mudança na interpretação jurisdicional. Essa corrente passou a ser combatida, sendo que recentemente o Supremo Tribunal Federal na ocasião do julgamento do Recurso Extraordinário n° 590.809, submetido ao rito da repercussão geral, consignou que não cabe ação rescisória em caso de mudança na orientação jurisprudencia

Carbonate precipitation, U-series dating and U-isotopic variations in a Holocene travertine platform at Bad Langensalza - Thuringia Basin, Germany

Travertine and calcareous tufa deposits, are important archives for Quaternary continental climate and archaeology. Here we present a comprehensive study on Holocene travertine deposition in the Thuringia basin based on a detailed survey of U-series measurements and dating that demonstrates rapid accumulation of carbonate during the early Holocene until 8000 years (up to 8 mm yr–1) followed by significant change in travertine accumulation that ended around 5800 years BP at the investigated site. We further demonstrate that systematic changes of the U-isotopic composition through time occur in agreement with major changes in travertine accumulation and texture, which are likely to reflect changes of spring water U-isotopic composition rather than U-series system opening or contamination with non-carbonate particles.Les travertins et les tufs calcaires constituent des archives importantes pour les études sur le climat continental quaternaire et l’Archéologie. Nous présentons l’étude de la formation d’un travertin holocène du bassin de Thuringe, basée sur un exposé détaillé des données uranium-thorium et des âges U-Th obtenus, qui démontrent une accumulation rapide du carbonate pendant le début de l’Holocène jusque vers 8000 ans (jusqu’à 8 mm par an) suivie par un changement significatif dans le rythme d’accumulation du travertin qui s’achève vers 5800 ans BP sur le site étudié. Nous démontrons ensuite que les changements systématiques dans la composition isotopique de l’uranium au cours du temps sont en accord avec les variations majeures de texture et d’accumulation du travertin et reflètent les changements de composition isotopique de l’uranium des eaux de source plutôt qu’une ouverture du système des séries de l’uranium voire une contamination par des particules non carbonatées

Sensitivity of Bunker Cave to climatic forcings highlighted through multi-annual monitoring of rain-, soil-, and dripwaters

The last two decades have seen a considerable increase in studies using speleothems as archives of past climate variability. Caves under study are now monitored for a wide range of environmental parameters and results placed in context with speleothem data. The present study investigates trends from a seven year long monitoring of Bunker Cave, northwestern Germany, in order to assess the hydraulic response and transfer time of meteoric water from the surface to the cave. Rain-, soil-, and dripwater were collected from August 2006 to August 2013 at a monthly to bimonthly resolution and their oxygen and hydrogen isotope composition was measured. Furthermore, drip rates were quantified. Due to different drip characteristics, annual mean values were calculated for the drip rates of each drip site. Correlations of the annual mean drip rate of each site with precipitation and infiltration demonstrate that the annual infiltration, and thus the annual precipitation control the inter-annual drip-rate variability for all except one site. The hydraulic response is not delayed on an annual basis. All drip sites display identical long-term trends, which suggests a draining of a common karst reservoir over these seven years of monitoring. Correlations of soil- and dripwater monthly δ18O and δD values with atmospheric temperature data reveal water transfer times of 3 months to reach a depth of 40 cm (soilwater at site BW 2) and 4 months for 70 cm depth (soilwater at site BW 1). Finally, the water reaches the cave chambers (15 to 30 m below land surface) after ca. 2.5 years. Consequently, a temporal offset of 29 to 31 months (ca. 2.5 years) between the hydraulic response time (no time lag on annual basis) and the water transfer time (time lag of 29 to 31 months) was found, which is negligible with regard to Bunker Cave speleothems because of their slow growth rates. Here, proxies recording precipitation/infiltration and temperature are registered on a decadal scale. Variations in drip rate and thus precipitation and infiltration are recorded by δ13C and Mg/Ca ratios in speleothem calcite. Speleothem δ18O values reflect both temperature and precipitation signals due to drip rate-related fractionation processes. We document that long-term patterns in temperature and precipitation are recorded in dripwater patterns of Bunker Cave and that these are linked to the North Atlantic Oscillation (NAO)

Untersuchungen zur Chronostratigraphie mariner Terrassen in Mittelitalien—230Th/234U- und ESR-Datierungen an fossilen Mollusken

Durch die ESR-Altersbestimmungsmethode (Elektronenspin Resonanz) sowie die 230Th/234U-Datierung fossiler Muscheln bei Tarquinia (Latium) konnte die stratigraphische Einordnung tektonisch verstellter thyrrenzeitlicher mariner Terrassen geklärt werden. Zwischen den Flüssen Mignone und Marta liegt die Terrasse des Euthyrren I (100 000—120 000 BP) heute in einer Höhe von 40—45 m ü. M. und die Küstenlinie des Euthyrren II (200 000—220 000 BP) ca. 65m ü. M. Sie liegen damit deutlich höher als alle bisher gefundenen euthyrrenzeitlichen Terrassen in Mittelitalien.researc

Human adaptation strategies to abrupt climate change in Puerto Rico ca. 3.5 ka

The connection between climatic change and social response is complex because change articulates a number of inter-related factors. Human decisions are filtered by social buffers – including social memory, risk perception, and cultural priorities – and the rate and scale of climate change is usually much larger than the scale of human decision-making. In this article, we provide information on climate change based on precisely dated speleothems with the response evident in archaeological sites that have radiocarbon date ranges within the same time frame. A stalagmite recovered from within the catchment area for aquifer recharge of the Pre-Arawak site of Angostura in Barceloneta, Puerto Rico, shows that a significant wet period occurred between 3.9 and 3.1 ka (primarily centered at 3.5 ka). We investigate the effect that this increase in precipitation had on the earliest occupations on the island in the context of palaeoenvironmental, geoarchaeological, and archaeological records from Angostura, Maruca, and Paso del Indio. Our analysis suggests the presence of two different adaptation strategies: settlement relocation and microlandscape modification. Our study concludes that the social response to change cannot be seen as monolithic given that human behavior, even within the same period, addresses the needs of individual groups with different priorities. This multiplicity of responses can indeed enhance resilience as social support can continue through alliances and exchanges, strengthening social bonds that can help buffer catastrophes. The results can help shed light on the range of adaptation strategies to change encompassed within the manifestations of social resilience or vulnerability

Bunker Cave stalagmites: an archive for central European Holocene climate variability

Holocene climate was characterised by variability on multi-centennial to multi-decadal time scales. In central Europe, these fluctuations were most pronounced during winter. Here we present a record of past winter climate variability for the last 10.8 ka based on four speleothems from Bunker Cave, western Germany. Due to its central European location, the cave site is particularly well suited to record changes in precipitation and temperature in response to changes in the North Atlantic realm. We present high-resolution records of δ18O, δ13C values and Mg/Ca ratios. Changes in the Mg/Ca ratio are attributed to past meteoric precipitation variability. The stable C isotope composition of the speleothems most likely reflects changes in vegetation and precipitation, and variations in the δ18O signal are interpreted as variations in meteoric precipitation and temperature. We found cold and dry periods between 8 and 7 ka, 6.5 and 5.5 ka, 4 and 3 ka as well as between 0.7 and 0.2 ka. The proxy signals in the Bunker Cave stalagmites compare well with other isotope records and, thus, seem representative for central European Holocene climate variability. The prominent 8.2 ka event and the Little Ice Age cold events are both recorded in the Bunker Cave record. However, these events show a contrasting relationship between climate and δ18O, which is explained by different causes underlying the two climate anomalies. Whereas the Little Ice Age is attributed to a pronounced negative phase of the North Atlantic Oscillation, the 8.2 ka event was triggered by cooler conditions in the North Atlantic due to a slowdown of the thermohaline circulation

Arctic Ocean evidence for late Quaternary initiation of northern Eurasian ice sheets

A high-resolution multiparameter stratigraphy allows the identification of late Quaternary glacial and interglacial cycles in a central Arctic Ocean sediment core. Distinct sandy layers in the upper part of the otherwise fine-grained sediment core from the Lomonosov Ridge (lat 87.5°N) correlate to four major glacials since ca. 0.7 Ma. The composition of these ice-rafted terrigenous sediments points to a glaciated northern Siberia as the main source. In contrast, lithic carbonates derived from North America are also present in older sediments and indicate a northern North American glaciation since at least 2.8 Ma. We conclude that large-scale northern Siberian glaciation began much later than other Northern Hemisphere ice sheets

Arctic Ocean evidence for late Quaternary initiation of northern Eurasian ice sheets

A high-resolution multiparameter stratigraphy allows the identification of late Quaternary glacial and interglacial cycles in a central Arctic Ocean sediment core. Distinct sandy layers in the upper part of the otherwise fine-grained sediment core from the Lomonosov Ridge (lat 87.5°N) correlate to four major glacials since ca. 0.7 Ma. The composition of these ice-rafted terrigenous sediments points to a glaciated northern Siberia as the main source. In contrast, lithic carbonates derived from North America are also present in older sediments and indicate a northern North American glaciation since at least 2.8 Ma. We conclude that large-scale northern Siberian glaciation began much later than other Northern Hemisphere ice sheets